# Gadolinium\(III\) bromide hydrate — Safety Data Sheet — Apollo 原本PDFから抽出したテキストです。表、画像、記号、OCR結果は原本と異なる場合があります。安全情報は原本PDFで確認してください。 - **文書名:** Gadolinium\(III\) bromide hydrate — Safety Data Sheet — Apollo - **発行元:** Apollo - **材料:** Gadolinium\(III\) bromide hydrate - **CAS番号:** 30010\-20\-9 - **製品番号・グレード:** Gadolinium\(III\) bromide hydrate - **文書種類:** SDS - **原文の言語:** English - **地域:** European Union · REACH / CLP - **改訂日:** 10/07/2023 · Version 2\.2 - **ページ数:** 11 - **原本ファイル名:** 064\_Gadolinium\_III\_bromide\_hydrate\_Apollo\_via\_CymitQuimica\_EN\.pdf - **RESDSページ:** https://resds\.com/document/gadolinium\-iii\-bromide\-hydrate\-sds\-en\-9c7701c264 - **原本PDF:** https://resds\.com/pdf/gadolinium\-iii\-bromide\-hydrate\-sds\-en\-9c7701c264\.pdf - **情報源URL:** https://static\.cymitquimica\.com/products/54/pdf/sds\-IN1813\.pdf - **説明:** Original Apollo safety data sheet for Gadolinium\(III\) bromide hydrate\. Original PDF retained without modification\. Source collected on 2026\-09\-13\. ## ページ 1 ```text Gadolinium(III) bromide hydrate Apollo Scientific Chemwatch Hazard Alert Code: 2 Part Number: IN1813 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Safety Data Sheet S.GHS.GB-NIR.EN SECTION 1 Identification of the substance / mixture and of the company / undertaking Product Identifier Product name Gadolinium(III) bromide hydrate Chemical Name Gadolinium (III) bromide Synonyms Not Available Other means of Not Available identification CAS number 30010-20-9* Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Not Available Details of the manufacturer or supplier of the safety data sheet Registered company name Apollo Scientific Apollo Scientific ltd Whitefield Road, Bredbury Cheshire SK6 2QR United Address Whitefield Road, Bredbury SK62QR United Kingdom Kingdom (NI) Telephone 01614060505 +44(0) 161 406 0505 Fax 0161 406 0506 Not Available Website http://www.apolloscientific.co.uk/ apolloscientific.co.uk Email sales@apolloscientific.co.uk sales@apolloscientific.co.uk Emergency telephone number Association / Organisation Not Available Emergency telephone Not Available numbers Other emergency Not Available telephone numbers SECTION 2 Hazards identification Classification of the substance or mixture Classification according to regulation (EC) No H335 - Specific Target Organ Toxicity - Single Exposure (Respiratory Tract Irritation) Category 3, H315 - Skin Corrosion/Irritation 1272/2008 [CLP] and Category 2, H319 - Serious Eye Damage/Eye Irritation Category 2 amendments [1] Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI ``` ## ページ 2 ```text Part Number: IN1813 Page 2 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate Label elements Hazard pictogram(s) Signal word Warning Hazard statement(s) H335 May cause respiratory irritation. H315 Causes skin irritation. H319 Causes serious eye irritation. Precautionary statement(s) Prevention P271 Use only outdoors or in a well-ventilated area. P261 Avoid breathing dust/fumes. P280 Wear protective gloves, protective clothing, eye protection and face protection. P264 Wash all exposed external body areas thoroughly after handling. Precautionary statement(s) Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. Precautionary statement(s) Storage P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation. SECTION 3 Composition / information on ingredients Substances Classification according to regulation (EC) No 1272/2008 [CLP] and SCL / CAS No %[weight] Name amendments M-Factor Specific Target Organ Toxicity - Single Exposure (Respiratory Tract Gadolinium(III) Not 30010-20-9* 100 Irritation) Category 3 , Skin Corrosion/Irritation Category 2, Serious Eye bromide hydrate Available Damage/Eye Irritation Category 2; H335, H315, H319 [1] Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties Mixtures See section above for composition of Substances SECTION 4 First aid measures Description of first aid measures If this product comes in contact with the eyes: Eye Contact Wash out immediately with fresh running water. ``` ## ページ 3 ```text Part Number: IN1813 Page 3 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. Fire Fighting DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use. Non combustible. Fire/Explosion Hazard Not considered a significant fire risk, however containers may burn. May emit corrosive fumes. SECTION 6 Accidental release measures Personal precautions, protective equipment and emergency procedures See section 8 Environmental precautions See section 12 Methods and material for containment and cleaning up Clean up all spills immediately. Avoid breathing dust and contact with skin and eyes. Wear protective clothing, gloves, safety glasses and dust respirator. Use dry clean up procedures and avoid generating dust. Minor Spills Sweep up, shovel up or Vacuum up (consider explosion-proof machines designed to be grounded during storage and use). Place spilled material in clean, dry, sealable, labelled container. Moderate hazard. Major Spills CAUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. ``` ## ページ 4 ```text Part Number: IN1813 Page 4 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate Control personal contact by wearing protective clothing. Prevent, by any means available, spillage from entering drains or water courses. Recover product wherever possible. IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plastic bags or other containers for disposal. IF WET: Vacuum/shovel up and place in labelled containers for disposal. ALWAYS: Wash area down with large amounts of water and prevent runoff into drains. If contamination of drains or waterways occurs, advise Emergency Services. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 Handling and storage Precautions for safe handling Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. DO NOT allow material to contact humans, exposed food or food utensils. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Safe handling Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this SDS. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Other information Observe manufacturer's storage and handling recommendations contained within this SDS. For major quantities: Consider storage in bunded areas - ensure storage areas are isolated from sources of community water (including stormwater, ground water, lakes and streams}. Ensure that accidental discharge to air or water is the subject of a contingency disaster management plan; this may require consultation with local authorities. Conditions for safe storage, including any incompatibilities Lined metal can, lined metal pail/ can. Plastic pail. Suitable container Polyliner drum. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks. None known Storage incompatibility Hygroscopic Store under argon SECTION 8 Exposure controls / personal protection Control parameters Occupational Exposure Limits (OEL) INGREDIENT DATA Not Available Emergency Limits Ingredient TEEL-1 TEEL-2 TEEL-3 Gadolinium(III) bromide Not Available Not Available Not Available hydrate ``` ## ページ 5 ```text Part Number: IN1813 Page 5 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate Ingredient Original IDLH Revised IDLH Gadolinium(III) bromide Not Available Not Available hydrate Occupational Exposure Banding Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit Gadolinium(III) bromide E ≤ 0.01 mg/m³ hydrate Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and the adverse health outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds to a range of exposure concentrations that are expected to protect worker health. Exposure controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure. Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively large, a certain proportion will be powdered by mutual friction. If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory protection should be considered. Such protection might consist of: (a): particle dust respirators, if necessary, combined with an absorption cartridge; (b): filter respirators with absorption cartridge or canister of the right type; (c): fresh-air hoods or masks. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant. Appropriate engineering Type of Contaminant: Air Speed: controls direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas 1-2.5 m/s (200-500 discharge (active generation into zone of rapid air motion) f/min.) grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial 2.5-10 m/s (500-2000 velocity into zone of very high rapid air motion). f/min.) Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1: Room air currents minimal or favourable to capture 1: Disturbing room air currents 2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in motion 4: Small hood-local control only Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 4-10 m/s (800-2000 f/min) for extraction of crusher dusts generated 2 metres distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used. Individual protection measures, such as personal protective equipment Safety glasses with side shields. Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent] Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy Eye and face protection document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the ``` ## ページ 6 ```text Part Number: IN1813 Page 6 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]. Skin protection See Hand protection below The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when making a final choice. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: · frequency and duration of contact, · chemical resistance of glove material, · glove thickness and · dexterity Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent). · When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. · When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended. · Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term use. · Contaminated gloves should be replaced. As defined in ASTM F-739-96 in any application, gloves are rated as: · Excellent when breakthrough time > 480 min · Good when breakthrough time > 20 min Hands/feet protection · Fair when breakthrough time < 20 min · Poor when glove material degrades For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended. It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based on consideration of the task requirements and knowledge of breakthrough times. Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers technical data should always be taken into account to ensure selection of the most appropriate glove for the task. Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example: · Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are only likely to give short duration protection and would normally be just for single use applications, then disposed of. · Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or puncture potential Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended. Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive particles are not present. polychloroprene. nitrile rubber. butyl rubber. fluorocaoutchouc. polyvinyl chloride. Gloves should be examined for wear and/ or degradation constantly. Body protection See Other protection below Overalls. P.V.C apron. Other protection Barrier cream. Skin cleansing cream. Eye wash unit. Respiratory protection Type -P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator P1 - PAPR-P1 up to 10 x ES Air-line* - - up to 50 x ES Air-line** P2 PAPR-P2 up to 100 x ES - P3 - Air-line* - ``` ## ページ 7 ```text Part Number: IN1813 Page 7 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate 100+ x ES - Air-line** PAPR-P3 * - Negative pressure demand ** - Continuous flow A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC) · Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures. · The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure measurement data, and frequency and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in heat stress or distress due to personal protective equipment (powered, positive flow, full face apparatus may be an option). · Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory protection. These may be government mandated or vendor recommended. · Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratory protection program. · Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU) · Use approved positive flow mask if significant quantities of dust becomes airborne. · Try to avoid creating dust conditions. SECTION 9 Physical and chemical properties Information on basic physical and chemical properties Appearance Not Available Relative density (Water = Physical state Solid Not Available 1) Partition coefficient Odour Not Available Not Available n-octanol / water Auto-ignition temperature Odour threshold Not Available Not Available (°C) Decomposition pH (as supplied) Not Available Not Available temperature (°C) Melting point / freezing 186 Viscosity (cSt) Not Available point (°C) Initial boiling point and Not Available Molecular weight (g/mol) Not Available boiling range (°C) Flash point (°C) Not Available Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Not Available Oxidising properties Not Available Surface Tension (dyn/cm Upper Explosive Limit (%) Not Available Not Applicable or mN/m) Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water Not Available pH as a solution (1%) Not Available Vapour density (Air = 1) Not Available VOC g/L Not Available SECTION 10 Stability and reactivity Reactivity See section 7 Chemical stability Product is considered stable and hazardous polymerisation will not occur. Possibility of hazardous See section 7 reactions Conditions to avoid See section 7 Incompatible materials See section 7 ``` ## ページ 8 ```text Part Number: IN1813 Page 8 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate Hazardous decomposition See section 5 products SECTION 11 Toxicological information Information on toxicological effects The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives Inhaled using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because Ingestion of the lack of corroborating animal or human evidence. The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives Skin Contact using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Eye This material can cause eye irritation and damage in some persons. Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives Chronic using animal models); nevertheless exposure by all routes should be minimised as a matter of course. Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye STOT - Single Exposure Damage/Irritation Respiratory or Skin STOT - Repeated Exposure sensitisation Mutagenicity Aspiration Hazard Legend: – Data either not available or does not fill the criteria for classification – Data available to make classification SECTION 12 Ecological information Toxicity Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air No Data available for all ingredients No Data available for all ingredients Bioaccumulative potential Ingredient Bioaccumulation No Data available for all ingredients Mobility in soil Ingredient Mobility No Data available for all ingredients SECTION 13 Disposal considerations ``` ## ページ 9 ```text Part Number: IN1813 Page 9 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate Waste treatment methods Recycle wherever possible or consult manufacturer for recycling options. Product / Packaging Consult State Land Waste Management Authority for disposal. disposal Bury residue in an authorised landfill. Recycle containers if possible, or dispose of in an authorised landfill. SECTION 14 Transport information Labels Required Marine Pollutant NO Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code Product name Group Gadolinium(III) bromide Not Available hydrate Transport in bulk in accordance with the IGC Code Product name Ship Type Gadolinium(III) bromide Not Available hydrate SECTION 15 Regulatory information Safety, health and environmental regulations / legislation specific for the substance or mixture Gadolinium(III) bromide hydrate is found on the following regulatory lists Not Applicable National Inventory Status National Inventory Status Australia - AIIC / Australia No (Gadolinium(III) bromide hydrate) Non-Industrial Use Canada - DSL No (Gadolinium(III) bromide hydrate) Canada - NDSL No (Gadolinium(III) bromide hydrate) China - IECSC No (Gadolinium(III) bromide hydrate) Europe - EINEC / ELINCS / No (Gadolinium(III) bromide hydrate) NLP Japan - ENCS No (Gadolinium(III) bromide hydrate) Korea - KECI No (Gadolinium(III) bromide hydrate) New Zealand - NZIoC No (Gadolinium(III) bromide hydrate) Philippines - PICCS No (Gadolinium(III) bromide hydrate) USA - TSCA No (Gadolinium(III) bromide hydrate) Taiwan - TCSI No (Gadolinium(III) bromide hydrate) Mexico - INSQ No (Gadolinium(III) bromide hydrate) Vietnam - NCI No (Gadolinium(III) bromide hydrate) Russia - FBEPH No (Gadolinium(III) bromide hydrate) ``` ## ページ 10 ```text Part Number: IN1813 Page 10 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate National Inventory Status Yes = All CAS declared ingredients are on the inventory Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration. SECTION 16 Other information Revision Date 10/07/2023 Initial Date 11/07/2023 SDS Version Summary Date of Version Sections Updated Update CAS Number, Hazards identification - Classification, Composition / information on ingredients - Ingredients, 1.2 10/07/2023 Korean MSDS Number, Identification of the substance / mixture and of the company / undertaking - Supplier Information, Identification of the substance / mixture and of the company / undertaking - Synonyms Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards: EN 166 Personal eye-protection EN 340 Protective clothing EN 374 Protective gloves against chemicals and micro-organisms EN 13832 Footwear protecting against chemicals EN 133 Respiratory protective devices Definitions and abbreviations PC－TWA: Permissible Concentration-Time Weighted Average PC－STEL: Permissible Concentration-Short Term Exposure Limit IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit。 IDLH: Immediately Dangerous to Life or Health Concentrations ES: Exposure Standard OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BCF: BioConcentration Factors BEI: Biological Exposure Index AIIC: Australian Inventory of Industrial Chemicals DSL: Domestic Substances List NDSL: Non-Domestic Substances List IECSC: Inventory of Existing Chemical Substance in China EINECS: European INventory of Existing Commercial chemical Substances ELINCS: European List of Notified Chemical Substances NLP: No-Longer Polymers ENCS: Existing and New Chemical Substances Inventory KECI: Korea Existing Chemicals Inventory NZIoC: New Zealand Inventory of Chemicals PICCS: Philippine Inventory of Chemicals and Chemical Substances TSCA: Toxic Substances Control Act TCSI: Taiwan Chemical Substance Inventory INSQ: Inventario Nacional de Sustancias Químicas NCI: National Chemical Inventory FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP] ``` ## ページ 11 ```text Part Number: IN1813 Page 11 of 11 Issue Date: 10/07/2023 Version No: 2.2 Print Date: 10/07/2023 Gadolinium(III) bromide hydrate Classification according to regulation (EC) No Classification Procedure 1272/2008 [CLP] and amendments Specific Target Organ Toxicity - Single Exposure Expert judgement (Respiratory Tract Irritation) Category 3 , H335 Skin Corrosion/Irritation Expert judgement Category 2, H315 Serious Eye Damage/Eye Expert judgement Irritation Category 2, H319 Powered by AuthorITe, from Chemwatch. ```