# GADOLINIUM\(III\) ACETYLACETONATE HYDRATE 99\.9% — Safety Data Sheet — Apollo 原本PDFから抽出したテキストです。表、画像、記号、OCR結果は原本と異なる場合があります。安全情報は原本PDFで確認してください。 - **文書名:** GADOLINIUM\(III\) ACETYLACETONATE HYDRATE 99\.9% — Safety Data Sheet — Apollo - **発行元:** Apollo - **材料:** GADOLINIUM\(III\) ACETYLACETONATE HYDRATE 99\.9% - **CAS番号:** 64438\-54\-6 - **製品番号・グレード:** IN1840 - **文書種類:** SDS - **原文の言語:** English - **地域:** - **改訂日:** 17/07/2015 - **ページ数:** 7 - **原本ファイル名:** 100\_GADOLINIUM\_III\_ACETYLACETONATE\_HYDRATE\_99\_9\_Apollo\_via\_chemBlink\_EN\.pdf - **RESDSページ:** https://resds\.com/document/gadolinium\-iii\-acetylacetonate\-hydrate\-99\-9\-sds\-en\-4517715d35 - **原本PDF:** https://resds\.com/pdf/gadolinium\-iii\-acetylacetonate\-hydrate\-99\-9\-sds\-en\-4517715d35\.pdf - **情報源URL:** https://www\.chemblink\.com/MSDSFiles/64438\-54\-6Apollo\.pdf - **説明:** Original Apollo safety data sheet for GADOLINIUM\(III\) ACETYLACETONATE HYDRATE 99\.9%\. Original PDF retained without modification\. Source collected on 2026\-09\-13\. ## ページ 1 ```text SAFETY DATA SHEET GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% Page: 1 Compilation date: 17/07/2015 Revision date: SAP Revision No: 1 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% CAS number: 64438-54-6 Product code: IN1840 Synonyms: GADOLINIUM(III) PENTANE-2,4-DIONATE HYDRATE 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Company name: Apollo Scientific Ltd Units 3 & 4 Parkway Denton Manchester M34 3SG UK Tel: 0161 337 9971 Fax: 0161 336 6932 Email: david.tideswell@apolloscientific.co.uk 1.4. Emergency telephone number Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CLP: STOT SE 3: H335; Eye Irrit. 2: H319; Skin Irrit. 2: H315 Classification under CHIP: Xi: R36/37/38 Most important adverse effects: Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. 2.2. Label elements Label elements: Hazard statements: H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. Signal words: Warning Hazard pictograms: GHS07: Exclamation mark [cont...] ``` ## ページ 2 ```text SAFETY DATA SHEET GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% Page: 2 Precautionary statements: P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust. P280: Wear protective gloves/protective clothing/eye protection/face protection. 2.3. Other hazards PBT: This product is not identified as a PBT/vPvB substance. Section 3: Composition/information on ingredients 3.1. Substances Chemical identity: GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% CAS number: 64438-54-6 Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor. Ingestion: Wash out mouth with water. Consult a doctor. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. 4.3. Indication of any immediate medical attention and special treatment needed Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Carbon dioxide, dry chemical powder, foam. Suitable extinguishing media for the surrounding fire should be used. 5.2. Special hazards arising from the substance or mixture Exposure hazards: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Gadolinium Oxides 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. [cont...] ``` ## ページ 3 ```text SAFETY DATA SHEET GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% Page: 3 Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not create dust. 6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Transfer to a closable, labelled salvage container for disposal by an appropriate method. 6.4. Reference to other sections Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of dust in the air. Only use in fume hood. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. Product is hygroscopic. Take precautions to avoid contact with atmospheric moisture. Store under Argon. Suitable packaging: Must only be kept in original packaging. 7.3. Specific end use(s) Specific end use(s): No data available. Section 8: Exposure controls/personal protection 8.1. Control parameters Workplace exposure limits: No data available. DNEL/PNEC Values DNEL / PNEC No data available. 8.2. Exposure controls Engineering measures: Ensure there is sufficient ventilation of the area. Respiratory protection: Self-contained breathing apparatus must be available in case of emergency. Respiratory protective device with particle filter. [cont...] ``` ## ページ 4 ```text SAFETY DATA SHEET GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% Page: 4 Hand protection: Protective gloves. Eye protection: Safety glasses. Ensure eye bath is to hand. Skin protection: Protective clothing. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Solid Melting point/range°C: 143 9.2. Other information Other information: No data available. Section 10: Stability and reactivity 10.1. Reactivity Reactivity: Stable under recommended transport or storage conditions. 10.2. Chemical stability Chemical stability: Stable under normal conditions. 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. 10.4. Conditions to avoid Conditions to avoid: Heat. Humidity. Moist air. 10.5. Incompatible materials Materials to avoid: Strong oxidising agents. Strong acids. 10.6. Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Gadolinium oxides Section 11: Toxicological information 11.1. Information on toxicological effects Relevant hazards for substance: Hazard Route Basis Skin corrosion/irritation DRM Based on test data Serious eye damage/irritation OPT Based on test data STOT-single exposure INH Based on test data Symptoms / routes of exposure Skin contact: There may be irritation and redness at the site of contact. [cont...] ``` ## ページ 5 ```text SAFETY DATA SHEET GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% Page: 5 Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Section 12: Ecological information 12.1. Toxicity Ecotoxicity values: No data available. 12.2. Persistence and degradability Persistence and degradability: No data available. 12.3. Bioaccumulative potential Bioaccumulative potential: No data available. 12.4. Mobility in soil Mobility: No data available. 12.5. Results of PBT and vPvB assessment PBT identification: This product is not identified as a PBT/vPvB substance. 12.6. Other adverse effects Other adverse effects: No data available. Section 13: Disposal considerations 13.1. Waste treatment methods Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company. MATERIAL SHOULD BE DISPOSED OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS Disposal of packaging: Dispose of as special waste in compliance with local and national regulations Observe all federal, state and local environmental regulations. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. Section 14: Transport information Transport class: This product does not require a classification for transport. Section 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. [cont...] ``` ## ページ 6 ```text SAFETY DATA SHEET GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% Page: 6 Section 16: Other information Other information Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * Data predicted using computational software. Toxtree - Toxic Hazard Estimation by decision tree approach. http://ecb.jrc.ec.europa.eu/qsar/qsar-tools/index.php? c=TOXTREE ~ Data predicted using computational software ACD/ToxSuite v 2.95.1 Copyright 1994- 2009 ACD/labs, Copyright 2001-2009 Pharma Algorithms, Inc, Advanced Chemistry Development, Inc (ACD/Labs). http://www.acdlabs.com/products/pc_admet/tox/tox/ Phrases used in s.2 and s.3: H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. R36/37/38: Irritating to eyes, respiratory system and skin. Legend to abbreviations: PNEC = predicted no effect level DNEL = derived no effect level LD50 = median lethal dose LC50 = median lethal concentration EC50 = median effective concentration IC50 = median inhibitory concentration dw = dry weight bw = body weight cc = closed cup oc = open cup MUS = mouse GPG = guinea pig RBT = rabbit HAM = hamster HMN = human MAM = mammal PGN = pigeon IVN = intravenous SCU = subcutaneous SKN = skin DRM = dermal OCC = ocular/corneal PCP = phycico-chemical properties Legal disclaimer: The material is intended for research purposes only and should be handled exclusively [cont...] ``` ## ページ 7 ```text SAFETY DATA SHEET GADOLINIUM(III) ACETYLACETONATE HYDRATE 99.9% Page: 7 by those who have been fully trained in safety, laboratory and chemical handling procedures. The above information is believed to be correct to the best of our knowledge. The above information is believed to be correct to the best of our knowledge at the date of its publication, but should not be considered to be all inclusive. It should be used only as a guide for safe handling, storage, transportation and disposal. We cannot guarantee that the hazards detailed in this document are the only hazards that exist for this product. This is not a warranty and Apollo Scientific Ltd shall not be held liable for any damage resulting from handling or from contact with the above product. [final page] ```