# Cerium \(IV\) Ammonium Nitrate – ProChem SDS

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- **Document title:** Cerium \(IV\) Ammonium Nitrate – ProChem SDS
- **Publisher:** ProChem, Inc\.
- **Material:** Cerium \(IV\) Ammonium Nitrate
- **CAS number:** 16774\-21\-3
- **Product code / grade:** 1404\-1
- **Document type:** SDS
- **Original language:** English
- **Region:** United States
- **Revision date:** Not stated
- **Page count:** 4
- **Original filename:** prochem\-cerium\-iv\-ammonium\-nitrate\-1\.pdf
- **RESDS page:** https://resds\.com/document/cerium\-iv\-ammonium\-nitrate\-prochem\-en\-74ee0bf251
- **Original PDF:** https://resds\.com/pdf/cerium\-iv\-ammonium\-nitrate\-prochem\-en\-74ee0bf251\.pdf
- **Source URL:** https://prochemonline\.com/wp\-content/uploads/2023/09/1404\-1\.CeriumIVAmmoniumNitrate\.pdf
- **Description:** Collected by RESDS\. Original publisher PDF retained\. Original ProChem SDS for Cerium \(IV\) Ammonium Nitrate\. Product number 1404\-1; revision not stated\. Publication authorized by the user on 2026\-09\-14\.

## Page 1

```text
 SECTION 1     PRODUCT AND COMPANY INFORMATION

PRODUCT NAME:    Cerium (IV) Ammonium Nitrate

PRODUCT NUMBER:  1404-1

CAS NUMBER:        16774-21-3

SYNONYMS:        Ammonium cerium (IV) nitrate, Ammonium hexanitratocerate (IV), Ceric ammonium nitrate,
                   diammonium cerium nitrate

MANUFACTURER:


ProChem, Inc.                                        PHONE:        815-398-1788
826 Roosevelt Road                                          FAX:           815-398-1810
Rockford, IL  61109                                    TOLL FREE:    800-795-8788

                  IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2    HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram


Signal Word         Danger

Hazard Statements

 H272             May intensify fire, oxidizer.
 H290             May be corrosive to metals.
 H302                Harmful if swallowed.
 H314              Causes severe skin burns and eye damage.
 H317             May cause an allergic skin reaction.
 H335             May cause respiratory irritation.

Precautionary Phrases

 P210              Keep away from heat.
 P220                Keep/Store away from clothing/combustible materials.
 P221               Take any precaution to avoid mixing with combustibles.
 P261                Avoid breathing dust/fume/gas/mist/vapors/spray.
 P264             Wash skin thoroughly after handling.
 P270             Do not eat, drink, or smoke when using this product.
 P280              Wear protective gloves/protective clothing/eye protection/face protection.
 P301+P312            IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
 P303+P361+P330     IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
 P304+P340            IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.


CERIUM (IV) AMMONIUM NITRATE                                                          PAGE 1
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## Page 2

```text
SECTION 2    HAZARDS IDENTIFICATION (Cont.)

 P305+P351+P338     IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
                        do. Continue rinsing.
 P370+P378             In case of fire: Use dry sand, dry chemical, or alcohol-resistant foam for extinction.

HMIS CLASSIFICATION:
Health: 2              Fire: 0                  Reactivity Hazard: 2
NFPA RATING:
Health: 3            Flammability: 3         Reactivity Hazard: 3       Special: OX

EYE CONTACT: Causes serious eye irritation.
SKIN CONTACT: Causes skin irritation.
INHALATION: May cause respiratory irritation.
INGESTION: Harmful if swallowed.


SECTION 3      COMPOSITION / INFORMATION ON INGREDIENTS

Formula: (NH4)2Ce(NO3)6

Molecular Weight: 548.22


CHEMICAL NAME                                           CAS#                               %


Cerium (IV) Ammonium Nitrate                                            16774-21-3                                             100

SECTION 4   FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under
eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention.
SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
irritation persists.
INHALATION: Remove to fresh air and keep at rest. Closely monitor the victim for signs of respiratory problems, such as
difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance.
INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
vomiting only if directed by medical personnel.

SECTION 5   FIREFIGHTING MEASURES

FLASH POINT: Not available
AUTO IGNITION TEMPERATURE: Not available
EXPLOSION LIMITS: Not available
EXTINGUISHING MEDIUM: Carbon dioxide, extinguishing powder, or water spray. Fight large fires with water spray or alcohol
resistant foam. This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing,
including eye protection and boots.
HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Nitrogen oxides, ammonia, and cerium oxide fume.

SECTION 6   ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the
formation of dust. Avoid breathing vapors, mist, gas, or dust.
ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Pick up and arrange disposal without creating dust. Sweep
up and keep in suitable, closed containers for disposal.

SECTION 7   HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Use with adequate ventilation. Avoid
contact with skin and eyes. Avoid formation of dust. Keep away from heat and sources of ignition.



CERIUM (IV) AMMONIUM NITRATE                                                          PAGE 2
```

## Page 3

```text
SECTION 7   HANDLING AND STORAGE (Cont.)

CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Store under inert gas. Store away from flammable
substances, reducing agents, strong bases, metal powders. Do not store with organic materials and acids.

SECTION 8  EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values.
EYE PROTECTION: Wear chemical safety glasses or goggles and face shield.
SKIN PROTECTION: Wear nitrile or rubber gloves, apron, or lab coat.
VENTILATION: Provide local exhaust, preferably mechanical.
RESPIRATOR: Use an approved respirator.
ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and
handling.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: Orange red solid
ODOR: Pungent
MOLECULAR WEIGHT: 548.22
BOILING POINT: No data available
MELTING POINT: 107° C
SPECIFIC GRAVITY: No data available
VAPOR DENSITY: No data available
SOLUBILITY: Soluble

SECTION 10  STABILITY AND REACTIVITY

STABILITY: Stable
HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID: Avoid moisture
INCOMPATIBILITY: Strong reducing agents, organic materials, and powdered metals.
DECOMPOSITION PRODUCTS: Nitrogen oxides, ammonia, and cerium oxide fume.


SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: LD50 Oral – rat - > 300 – 2,000 mg/kg (OECD Test Guideline 401)
CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen.
MUTAGENIC EFFECTS: Not available
TETRATOGENIC EFFECTS: Not available
RTECS: CQ9800000

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12  ECOLOGICAL DATA

No data available

SECTION 13  DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.





CERIUM (IV) AMMONIUM NITRATE                                                          PAGE 3
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## Page 4

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SECTION 14  TRANSPORTATION DATA

UN3085                                        Marine Pollutant: No
Oxidizing solid, corrosive, n.o.s.
(Cerium (IV) Ammonium Nitrate)
Class 5.1 (8)
PG II



SECTION 15  REGULATORY INFORMATION

TSCA: Listed in the TSCA inventory

SARA 302/304: Not listed
SARA 311/312: Reactivity Hazard, Acute Health Hazard
SARA (TITLE 313): Not listed

PENNSYLVANIA RIGHT TO KNOW: Cerium (IV) Ammonium Nitrate
NEW JERSEY RIGHT TO KNOW: Cerium (IV) Ammonium Nitrate

CALIFORNIA PROP. 65: Not Listed


SECTION 16  OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, ProChem, Inc. makes
no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based
on the information.
DATE CREATED: 09/23
SDS DEPT.





CERIUM (IV) AMMONIUM NITRATE                                                          PAGE 4
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