Praseodymium (III, IV) Oxide – ProChem SDS PAGE 1 SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Praseodymium (III, IV) Oxide PRODUCT NUMBER: 2981 CAS NUMBER: 12037-29-5 SYNONYMS: Hexapraseodymium undecaoxide MANUFACTURER: Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Not a dangerous substance according to the GHS HMIS CLASSIFICATION: Health: 1 Flammability: 0 Reactivity: 0 NFPA RATING: Health: 1 Fire: 0 Reactivity Hazard: 0 EYE CONTACT: May cause slight to mild irritation of the eyes. SKIN CONTACT: May cause slight to mild irritation of the skin. INHALATION: May be irritating to the nose, mucous membranes, and respiratory tract. INGESTION: May be harmful if swallowed. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: Pr6O11 Molecular Weight: 1021.43 CHEMICAL NAME CAS# % ACGIH (TWA) OSHA (PEL) Praseodymium (III, IV) Oxide 12037-29-5 100 No data No data SECTION 4 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. PRASEODYMIUM (III, IV) OXIDE PAGE 1 PAGE 2 SECTION 4 FIRST AID MEASURES (Cont.) INHALATION: Remove victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Product is not flammable AUTO IGNITION TEMPERATURE: Not applicable EXPLOSION LIMITS: Not applicable EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive self-contained breathing apparatus, flame and chemical resistant clothing, hats, boots, and gloves. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: None available. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear protective equipment. Ensure adequate ventilation. Avoid breathing vapors, mist, or gas. ENVIRONMENTAL PRECAUTIONS: Do not let enter drains. Do not allow to be released into environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Provide appropriate exhaust ventilation at places where dust is formed. CONDITIONS FOR SAFE STORAGE: Store material in a tightly sealed container. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EYE PROTECTION: Always wear approved safety glasses with side shields, safety goggles, or face shield when handling a chemical substance in the laboratory. SKIN PROTECTION: Chemical resistant gloves. VENTILATION: Handle in an efficient chemical fume hood. RESPIRATOR: If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 19-10.134. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: Black powder MOLECULAR WEIGHT: 1021.43 BOILING POINT: 4200° C MELTING POINT: 2500° C SPECIFIC GRAVITY: 7.07 gm/ml ODOR: Odorless SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES (Cont.) VAPOR PRESSURE: Not applicable SOLUBILITY: Insoluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Air and moisture stable HAZARDOUS POLYMERIZATION: No hazardous polymerization CONDITIONS TO AVOID: None INCOMPATIBILITY: Strong oxidizing agents DECOMPOSITION PRODUCTS: None PRASEODYMIUM (III, IV) OXIDE PAGE 2 PAGE 3 SECTION 11 TOXICOLOGICAL DATA RTECS DATA: Oral (rat); LD50: >5 gm/kg. Intraperitoneal (mouse); Cytogenetic analysis: 77 mg/kg. CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified as a confirmed carcinogen by IARC, ACGIH, NTP, and OSHA. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not availabe To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA No information available SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. SECTION 14 TRANSPORTATION DATA Non-hazardous material SECTION 15 REGULATORY INFORMATION TSCA: Listed in the TSCA inventory SARA 313 COMPONENTS: This material does not contain any chemical components with know CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 302 COMPONENTS: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 311/312 HAZARDS: No SARA Hazards MASSACHUSETTS RIGHT TO KNOW COMPONENTS: No components are subject to the Massachusetts Right To Know Act. PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Dipraseodymium trioxide NEW JERSEY RIGHT TO KNOW COMPONENTS: Dipraseodymium trioxide CALIFORNIA PROP. 65 COMPONENTS: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 04/14 PRASEODYMIUM (III, IV) OXIDE PAGE 3