Yttrium (III) Oxalate Nonahydrate – ProChem SDS PAGE 1 SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Yttrium (III) Oxalate Nonahydrate PRODUCT NUMBER: 3859 CAS NUMBER: 13266-82-5 SYNONYMS: Ethanedioic acid, yttrium salt; oxalic acid, yttrium salt. MANUFACTURER: Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Signal Word Warning Hazard Statements H302+H312 Harmful if swallowed or in contact with skin. Precautionary Phrases P280 Wear protective gloves/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. HMIS CLASSIFICATION: Health: 3 Fire: 0 Reactivity Hazard: 1 NFPA RATING: Health: 1 Flammability: 1 Reactivity Hazard: 0 EYE CONTACT: May cause moderate to severe irritation of the eyes. SKIN CONTACT: May cause moderate to severe irritation of the skin. INHALATION: Dust may be severely irritating to the nose, mucous membranes, and respiratory tract. INGESTION: May be harmful if swallowed. YTTRIUM (III) OXALATE PAGE 1 PAGE 2 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: Y2(C2O4)3 Ÿ 9H2O Molecular Weight: 604.01 CHEMICAL NAME CAS# % Yttrium (III) Oxalate 13266-82-5 100 SECTION 4 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Not available AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Carbon dioxide, extinguishing powder, or water spray. Fight large fires with water spray. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Carbon oxides and yttrium oxides SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Keep unprotected persons away. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Use with adequate ventilation. Keep away from heat and moisture. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Store in a rightly sealed container. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EXPOSURE CONTROLS Component Exposure Limits Basis Entity Yttrium 1 mg/m3 TLV ACGIH 1 mg/m3 PEL OSHA TLV: Threshold Limit Value over 8 hours of work. PEL: Permissible Exposure Limit EYE PROTECTION: Wear chemical safety glasses or goggles. SKIN PROTECTION: Wear nitrile or rubber gloves, apron, or lab coat. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. YTTRIUM (III) OXALATE PAGE 2 PAGE 3 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: White powder ODOR: None MOLECULAR WEIGHT: 604.01 BOILING POINT: Not available MELTING POINT: Not available (dec.) SPECIFIC GRAVITY: Not available SOLUBILITY: Slightly soluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Exposure to air or moisture over prolonged periods of time. INCOMPATIBILITY: Strong oxidizing agents and strong sulfuric acid. DECOMPOSITION PRODUCTS: Carbon oxides and yttrium oxide SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: may cause long-term adverse effects in the aquatic environment. Harmful in contact with skin and if swallowed. CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available CHRONIC TOXICITY: Yttrium is similar to the lanthanons and may have an anticoagulant effect on blood. Exposure to lanthanons may also lead to sensitivity to heat, itching, increased awareness of odor and taste, and liver damage. Oxalates are powerful irritants and corrosive to tissue. They have a caustic effect on mouth, esophagus, and stomach. Readily absorbed, they can cause severe kidney damage. To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA No data available. SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. SECTION 14 TRANSPORTATION DATA Not a dangerous good SECTION 15 REGULATORY INFORMATION TSCA: Not listed in the TSCA inventory SARA 302/304: Not Listed SARA 311/312: Not Listed SARA (TITLE 313): Not Listed CALIFORNIA PROP. 65: Not Listed WHMIS CANADA: Not Listed YTTRIUM (III) OXALATE PAGE 3 PAGE 4 SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 09/14 YTTRIUM (III) OXALATE PAGE 4