# Zirconium\-96 SDS \(Zr\-96 / 96Zr\) — Zirconium Metal Powder, Enriched Zirconium Metal Powder

原本PDFから抽出したテキストです。表、画像、記号、OCR結果は原本と異なる場合があります。安全情報は原本PDFで確認してください。

- **文書名:** Zirconium\-96 SDS \(Zr\-96 / 96Zr\) — Zirconium Metal Powder, Enriched Zirconium Metal Powder
- **発行元:** Neonest AB
- **材料:** Zirconium Metal Powder, Enriched Zirconium Metal Powder
- **CAS番号:** 7440\-67\-7
- **製品番号・グレード:** Enriched isotope · Zirconium\-96 · Zr\-96 · 96Zr
- **文書種類:** SDS
- **原文の言語:** English
- **地域:** Sweden
- **改訂日:** 31\-Aug\-2019
- **ページ数:** 9
- **原本ファイル名:** 96zr\-metal\-powder\-safety\-data\-sheet\-96zr\-sds\-96zr\-isotope\-96zr\-enriched\-96zr\.pdf
- **RESDSページ:** https://resds\.com/document/zirconium\-96\-isotope\-sds\-zr\-96\-96zr\-zirconium\-metal\-powder\-enriched\-zirconium\-metal\-powder\-3b4598b93d
- **原本PDF:** https://resds\.com/pdf/zirconium\-96\-isotope\-sds\-zr\-96\-96zr\-zirconium\-metal\-powder\-enriched\-zirconium\-metal\-powder\-3b4598b93d\.pdf
- **情報源URL:** https://www\.buyisotope\.com/sds/96zr\-metal\-powder\-safety\-data\-sheet\-96zr\-sds\-96zr\-isotope\-96zr\-enriched\-96zr\.pdf
- **説明:** Safety Data Sheet for Zirconium Metal Powder, Enriched Zirconium Metal Powder, published by Neonest AB\. Supplier file designation: Zirconium\-96 / Zr\-96 / 96Zr\.

## ページ 1

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 1/9 
Section 1:   Identification of the Substance/Mixture and of the Company/Undertaking 
Product Identifier: 
Identification as on the label/Trade name:   Zirconium, Enriched Zirconium. 
Molecular weight:   91.22 
Chemical formula:   Zr 
Synonyms:   Zircat, Zirconium metal. 
Details of the supplier of the Safety Data Sheet: 
Neonest AB 
Storgatan 70C, Solna 
SE-17152 
Sweden 
Contact details: 
+46-76-219-9731 
24-hour Emergency Contact: 
Swedish Poisons Centre 
Phone: 112 - Ask for Poisons Information, 112   –   begär Giftinformation . 
Other International Contacts: 
CHEMTREC 24-hour: +1-703-741-5500 (US + Worldwide) 
NHS: 111 (UK) 
Charite: +49 30 450 531 000 (Netherlands) 
INTCF: +34 917689800 (Spain) 
CapTv: +33 1 40 05 48 48 (France) 
Section 2: Hazards Identification 
Classification of the substances or mixture: 
The mixture is classified according to:   Regulation EC 1272/2008 [EU-GHS/CLP] 
Hazard classes/Hazard categories:   Hazard statement: 
Pyrophoric Solid (Category 1)   H250 
Water-reactive (Category 1)   H260 
Label elements: 
Hazard pictograms: 
Signal Words:   Danger. 
Hazard Statements:
```

## ページ 2

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 2/9 
H250 Catches fire spontaneously if exposed to air. 
H260 In contact with water releases flammable gases which may ignite spontaneously. 
Precautionary Statements: 
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 
P222 Do not allow contact with air. 
P223 Do not allow contact with water. 
P231 + P232 Handle and store contents under inert gas. Protect from moisture. 
P233 Keep container tightly closed. 
P280 Wear protective gloves/protective clothing. 
P302 + P334 IF ON SKIN: Immerse in cool water or wrap in wet bandages. 
Other hazards:   None known. 
Section 3: Composition/Information on Ingredients 
Substance/Mixture:   Substance. 
Ingredients: 
Substance name   (IUPAC/EC)   CAS - No.   Molecular 
weight 
Concentration 
% by weight 
Classification 
EC1272/2008 EC - No. 
Zirconium 
7440-67-7 
91.22   >99%   Pyr. Sol. 1   H250 
Water-react. 1   H260 231-176-9 
For explanation of abbreviations see Section 16. 
Section 4: First - Aid Measures 
Description of first aid measures: 
In case of inhalation:   If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult,
give oxygen. 
In case of skin contact:   In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove
contaminated clothing and shoes. Call a physician. 
In case of eye contact:   In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.
Assure adequate flushing by separating the eyelids with fingers. Call a physician. 
In case of ingestion:   If swallowed, wash out mouth with water provided person is conscious. Call a physician. 
Most important symptoms and effects, both acute and delayed: 
Inhalation:   May be harmful if inhaled; material is irritating to mucous membranes and upper respiratory tract. 
Eyes:   Causes eye irritation. 
Skin contact:   Causes skin irritation. 
Ingestion:   May be harmful if swallowed. 
Indication of any immediate medical attention and special treatment needed:   Treat symptomatically. Show this
safety data sheet to a physician or emergency room. 
Section 5: Fire - Fighting Measures 
Extinguisher media:
```

## ページ 3

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 3/9 
Suitable extinguisher media:   Use approved class D extinguishers or smother with dry sand, dry ground limestone, or
dry clay. 
Unsuitable extinguishing media:   Do not use water or carbon dioxide extinguisher on this material. 
Special hazards arising from the mixture:   Pyrophoric material. Emits toxic fumes under fire conditions. 
Advice for fire-fighters:   Wear self-contained breathing apparatus and protective clothing to prevent contact with skin
and eyes. 
Further information:   None. 
Section 6: Accidental Release Measures 
Personal precautions, protective equipment and emergency procedures: 
Personal precautions:   Evacuate area. Shut off all sources of ignition. Use non-sparking tools. Wear self-contained
breathing apparatus, rubber boots, and heavy rubber gloves. Avoid dust formation. Avoid breathing vapours, mist or
gas. 
Environmental precautions:   Prevent product from entering drains. Prevent further leakage or spillage if safe to do so.
Local authorities should be advised if significant spillages cannot be contained. 
Methods for containment and cleaning up: 
Methods for cleaning up:   Avoid raising dust. Cover with dry-lime, sand, or soda ash. Place in covered containers using
non-sparking tools and transport outdoors. Ventilate area and wash spill site after material pickup is complete. 
Reference to other sections: 
Treat recovered material as described in the section "Disposal considerations". 
Section 7: Handling and Storage 
Precautions for safe handling: 
Advice on safe handling:   Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or
repeated exposure. 
Hygiene measures:   Do not eat, drink or smoke when using this product. 
Conditions for safe storage, including incompatibilities: 
Requirements for storage areas and containers:   Keep container closed. Keep away from heat, sparks, and open
flame. Handle and store under nitrogen. Handle and store under inert gas. 
Section 8: Exposure Controls/ Personal Protection 
Control parameters: 
Occupational exposure limits: 
Country   Source   Type   Value 
USA   ACGIH   STEL   10 mg/m 3 
USA   ACGIH   TWA   5 mg/m 3 
USA   MSHA Standard-air   TWA   5 mg/m 3 
USA   OSHA   PEL   8H TWA 5 mg(Zr)/m 3 
New Zealand   OEL 
USA   NIOSH   TWA   5 mg/m 3
```

## ページ 4

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 4/9 
STEL   10 mg/m 3 
Exposure controls: 
Appropriate engineering controls:   Safety shower and eye bath. Use non-sparking tools. Use only in a chemical fume
hood. 
Individual protection measures, such as personal protective equipment: 
Eye/face protection:   Chemical safety goggles. 
Hand protection:   Compatible chemical-resistant gloves. 
Respiratory protection:   Government approved respirator. 
Section 9: Physical and Chemical Properties 
Information on basic physical and chemical properties 
Appearance (form):   Solid. 
Colour:   Grey. 
Odour:   No data available. 
Odour threshold:   No data available. 
Molecular Weight:   91.22 
pH (concentration):   No data available. 
Melting point/range (° C):   No data available. 
Boiling point/range (° C):   No data available. 
Freezing point   (°C):   No data available. 
Flash point (° C):   No data available. 
Evaporation rate:   No data available. 
Flammability (solid, gas):   The substance is a flammable solid. 
Ignition temperature (° C):   No data available. 
Upper/lower flammability/explosive limits:   No data available. 
Vapour   pressure (20 ° C):   No data available 
Vapour density:   No data available. 
Relative densi ty (25 ° C):   6.49 g/cm 3 
Water solubility (g/L ) at 20 ° C:   No data available. 
n-Octanol/Water partition coefficient : No data available. 
Auto-ignition temperature:   No data available. 
Decomposition temperature:   No data available. 
Viscosity, dynamic (mPa s):   No data available. 
Explosive properties:   The substance or mixture is not classified as explosive. 
Oxidising properties:   The substance or mixture is not classified as oxidizing. 
Section 10: Stability and Reactivity 
Reactivity:   No dangerous reaction known under conditions of normal use. 
Chemical stability:   Stable under normal conditions. 
Possibility of hazardous reactions:   Reacts violently with water. 
Conditions to avoid:   Air, moisture . 
Incompatible materials:   Water, strong acids, strong oxidizing agents, hydrogen fluoride, phosphorus, oxygen. 
Hazardous decomposition products:   None known.
```

## ページ 5

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 5/9 
Section 11: Toxicological Information 
Information on toxicological effects: 
Not classified based on available information. 
Classification according to GHS (1272/2008/EG, CLP) 
Skin corrosion/irritation: 
Not classified based on available information. 
Serious eye damage/eye irritation: 
Not classified based on available information. 
Respiratory or skin sensitisation: 
Not classified based on available information. 
Germ cell mutagenicity: 
Not classified based on available information. 
Carcinogenicity: 
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, NTP, or EPA
classification. 
ACGIH: Carcinogen List: Rating: A4 
Reproductive toxicity: 
Not classified based on available information. 
Specific target organ toxicity   –   single exposure (STOT): 
Not classified based on available information. 
Specific target organ toxicity (STOT)   –   repeated exposure: 
Not classified based on available information. 
Aspiration toxicity: 
Not classified based on available information. 
Section 12: Ecological Information 
Toxicity:   No data available. 
Persistence and degradability:   No data available. 
Bioaccumulative potential:   No data available. 
Mobility in soil:   No data available. 
Results of PBT& vPvB assessment:   Not relevant. 
Other adverse effects:   No data available. 
Sect ion 13: Disposal Considerations 
Waste treatment methods:   Catalysts and expensive metals should be recovered for reuse or recycling. Contact a
licensed professional waste disposal service to dispose of this material. Observe all local and national environmental
regulations. 
Section 14: Transport Information 
DOT: 
Proper Shipping Name:   ZIRCONIUM POWDER, DRY.
```

## ページ 6

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 6/9 
Hazard Class : 4.2 
UN Number:   2008 
Packing Group:   II 
Hazard Label: 
IATA: 
Proper Shipping Name:   ZIRCONIUM POWDER, DRY. 
Hazard Class : 4.2 
UN Number:   2008 
Packing Group:   II 
Section 15: Regulatory Information 
EU regulations: 
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended 
Not listed. 
Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I 
Not listed. 
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as
amended 
Not listed. 
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as
amended 
Not listed. 
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as
amended 
Not listed. 
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended 
Not listed. 
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry 
Not listed. 
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA 
Not listed. 
Authorisations: 
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended 
Not listed. 
Restrictions on use: 
Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use 
Not regulated.
```

## ページ 7

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 7/9 
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as
amended 
Not listed. 
Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens
at work 
Not regulated. 
Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or
are breastfeeding. 
Not regulated. 
Other EU regulations: 
Directive 2012/18/EU on major accident hazards involving dangerous substances 
Not listed. 
Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work. 
Always applicable. 
Directive 94/33/EC on the protection of young people at work 
Not listed. 
Other regulations:   The product is classified and labelled in accordance with EC directives or respective national laws.
This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended. 
OSHA Hazards:   Flammable solid. 
SARA 302 Components:   No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302. 
SARA 313 Components : This material does not contain any chemical components with known CAS numbers that
exceed the threshold (de minimis) reporting levels established by SARA Title III, Section 313. 
SARA 311/312 Hazards:   Reactivity Hazard, Chronic Health Hazard. 
Massachusetts Right to Know Components:   Zirconium Pyrophoric / CAS No. 7440-67-7 / Revision Date 1991-07-01 
Pennsylvania Right to Know Components:   Zirconium Pyrophoric / CAS No. 7440-67-7 / Revision Date 1991-07-01 
New Jersey Right to Know Components:   Zirconium Pyrophoric / CAS No. 7440-67-7 / Revision Date 1991-07-01 
California Prop. 65 Components:   This product does not contain any chemicals known to the State of California to
cause cancer, birth defects, or any other reproductive harm. 
National regulations:   Follow national regulation for work with chemical agents. 
Chemical safety assessment:   No Chemical Safety Assessment has been carried out. 
Section 16: Other Information 
List of abbreviations: 
ACGIH American Conference of Governmental Industrial Hygienists 
ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road 
ALARA As Low As Is Reasonably Achievable 
AMU Atomic Mass Unit 
ANSI American National Standards Institute 
BLS Basic Life Support 
CAM Continuous Air Monitor 
CAS Chemical Abstracts Service (division of the American Chemical Society) 
CEN European Committee for Standardization
```

## ページ 8

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 8/9 
CERCLA Comprehensive Environmental Response Compensation and Liability Act 
CLP Classification, Labelling and Packaging (European Union) 
CPR Controlled Products Regulations (Canada) 
CWA Clean Water Act (USA) 
DAC Derived Air Concentration (USA) 
DOE United States Department of Energy (USA) 
DOT United States Department of Transportation (USA) 
DSL Domestic Substances List (Canada) 
EC50 Half Maximal Effective Concentration 
EINECS European Inventory of Existing Commercial Chemical Substances 
EHS Environmentally Hazardous Substance 
ELINCS European List of Notified Chemical Substances 
EMS Emergency Response Procedures for Ships Carrying Dangerous Goods 
EPA Environmental Protection Agency (USA) 
EPCRA Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 
GHS Globally Harmonized System 
HMIS Hazardous Materials Identification System (USA) 
IARC International Agency for Research on Cancer 
IATA International Air Transport Association 
IBC Intermediate Bulk Containers 
ICAO International Civil Aviation Organization 
IDLH Immediately Dangerous to Life or Health 
IMDG International Maritime Code for Dangerous Goods 
LC50 Lethal concentration, 50 percent 
LD50 Lethal dose, 50 percent 
LDLO Lethal Dose Low 
LOEC Lowest-Observed-Effective Concentration 
MARPOL International Convention for the Prevention of Pollution from Ships 
MSHA Mine Safety and Health Administration (USA) 
NCRP National Council on Radiation Protection & Measurements (USA) 
NDSL Non-Domestic Substances List (Canada) 
NFPA National Fire Protection Association (USA) 
NIOSH National Institute for Occupational Safety and Health (USA) 
NOEC No Observed Effect Concentration 
N.O.S. Not Otherwise Specified 
NRC Nuclear Regulatory Commission (USA) 
NTP National Toxicology Program (USA) 
OSHA Occupational Safety and Health Administration (USA) 
PBT Persistent Bioaccumulative and Toxic Chemical 
PEL Permissible Exposure Limit 
PIH Poisonous by Inhalation Hazard 
RCRA Resource Conservation and Recovery Act (USA) 
RCT Radiation Control Technician 
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (Europe) 
RID Regulations Concerning the International Transport of Dangerous Goods by Rail 
RTECS Registry of Toxic Effects of Chemical Substances 
SARA Superfund Amendments and Reauthorization Act (USA)
```

## ページ 9

```text
Safety Data Sheet for Zirconium Metal
Powder, Enriched Zirconium Metal Powder 
According to ISO 11014:2010
First Print Date: 5-Mar-2015
Revision Date: 31-Aug-2019
Version: 1.1.1. 
Safety Data Sheet (SDS) for Zirconium, Enriched Zirconium   https://www.buyisotope.com   Page 9/9 
TDG Transportation of Dangerous Goods (Canada) 
TIH Toxic by Inhalation Hazard 
TLV Threshold Limit Value 
TPQ Threshold Planning Quantity 
TSCA Toxic Substances Control Act 
TWA Time Weighted Average 
UN United Nations (Number) 
VOC Volatile Organic Compound 
vPvB Very Persistent Very Bioaccumulative Chemical 
WGK Wassergefährdungsklassen (Germany: Water Hazard Classes) 
WHMIS Workplace Hazardous Materials Information System 
References: 
Not available. 
Full text of any H-statements not written out in full under Sections 2 to 15: 
H250 Catches fire spontaneously if exposed to air. 
H260 In contact with water releases flammable gases which may ignite spontaneously. 
Revision information: 
None. 
Training information: 
Follow training instructions when handling this material. 
Further Information: 
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
```