Terbium (III) Bromide Hydrate – ProChem SDS PAGE 1 SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Terbium (III) Bromide Hydrate PRODUCT NUMBER: 3466 CAS NUMBER: 15162-98-8 SYNONYMS: Terbium tribromide hydrate MANUFACTURER: Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Not a dangerous substance according to the GHS. HMIS CLASSIFICATION: Health: 1 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 1 Flammability: 0 Reactivity Hazard: 0 EYE CONTACT: Avoid contact with eyes. SKIN CONTACT: May cause allergic skin reaction. INHALATION: May cause irritation of respiratory tract. INGESTION: May be harmful if swallowed. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: TbBr3 Ÿ xH2O Molecular Weight: 398.64 (anhy.) CHEMICAL NAME CAS# % Terbium (III) Bromide Hydrate 15162-98-8 100 SECTION 4 FIRST AID MEASURES EYE EXPOSURE: In case of eye contact, rinse immediately with plenty of water and seek medical advice. SKIN EXPOSURE: Rinse with plenty of water and seek medical attention. INHALATION: Remove to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary. TERBIUM (III) BROMIDE PAGE 1 PAGE 2 SECTION 4 FIRST AID MEASURES (Cont.) INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention if necessary. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Not available AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Carbon dioxide, extinguishing powder, or water spray. Fight large fires with water spray of alcohol resistant foam. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen Bromide and terbium oxides. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Sweep up and place in suitable container for proper disposal. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Keep container tightly closed. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area in a tightly sealed container. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles. SKIN PROTECTION: Wear nitrile or rubber gloves, apron, or lab coat. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: White powder ODOR: Not available MOLECULAR WEIGHT: 398.64 (anhy.) BOILING POINT: 1490° C MELTING POINT: 827° C SPECIFIC GRAVITY: 4.67 gm/ml VAPOR DENSITY: No data available SOLUBILITY: Soluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Exposure to air/moisture over long periods of time. INCOMPATIBILITY: Strong oxidizing agents. DECOMPOSITION PRODUCTS: Hydrogen bromide and terbium oxides. TERBIUM (III) BROMIDE PAGE 2 PAGE 3 SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: No data available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available CHRONIC TOXICITY: Lanthanons can cause delayed blood clotting leading to hemorrhages. Exposure may also lead to sensitivity to heat, itching, increased awareness of odor and taste, and live damage. Inorganic bromides may produce depression, emaciation and in severe cases, psychosis and mental deterioration. Bromoderma, a bromide rash, often occurs when bromide inhalation or administration is prolonged. This rash is usually found on the face and resembles acne and furunculosis. RTECS: No data To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA No data available. SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. SECTION 14 TRANSPORTATION DATA Not a dangerous good. SECTION 15 REGULATORY INFORMATION TSCA: Listed in the TSCA inventory DSCL (EEC): Listed on the DSCL inventory SARA 302/304: Not Listed SARA 311/312: Not available SARA (TITLE 313): Not Listed CALIFORNIA PROP. 65: Not Listed WHMIS CANADA: Not Listed SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 09/14 TERBIUM (III) BROMIDE PAGE 3