Gadolinium (III) Fluoride — Safety Data Sheet — ProChem PAGE 1 SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Gadolinium (III) Fluoride PRODUCT NUMBER: 1828 CAS NUMBER: 13765-26-9 MANUFACTURER: Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Signal Word Warning Hazard Statements H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary Phrases P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P280 Wear protective gloves/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse. HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 0 EYE CONTACT: May cause irritation of the eyes. SKIN CONTACT: may cause mild irritation and redness. INHALATION: May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath. INGESTION: Toxicity reduced to the extent that this compound is relatively insoluble. In large amounts may cause vomiting, abdominal pain, and diarrhea. GADOLINIUM (III) FLUORIDE PAGE 1 PAGE 2 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: GdF3 Molecular Weight: 214.25 CHEMICAL NAME CAS# % Gadolinium (III) Fluoride 13765-26-9 100 SECTION 4 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Product is not flammable. AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: This product does not present an explosion hazard. EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen fluoride and gadolinium oxide. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the formation of dust. Avoid breathing vapors, mist, gas, or dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Mix spills with powdered sodium bicarbonate, lime, or calcium carbonate. Sweep up and place in suitable container for proper disposal. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid formation of dust. CONDITIONS FOR SAFE STORAGE: Store in a cool, dry, and well-ventilated area. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EXPOSURE CONTROLS: Component Exposure Limits Basis Entity Gadolinium (III) Fluoride 2.5 mg/m3 TWA OSHA TWA: Time Weighted Average over 8 hours of work. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, apron, or lab coat. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. GADOLINIUM (III) FLUORIDE PAGE 2 PAGE 3 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: White powder ODOR: None MOLECULAR WEIGHT: 214.25 BOILING POINT: No data available MELTING POINT: 1231° C SPECIFIC GRAVITY: 7.047 gm/ml SOLUBILITY: Insoluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None INCOMPATIBILITY: Strong reducing agents DECOMPOSITION PRODUCTS: Hydrogen fluoride and gadolinium oxide SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available RTECS: Not available To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA No data available SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. SECTION 14 TRANSPORTATION DATA Not a dangerous good SECTION 15 REGULATORY INFORMATION TSCA: Listed in the TSCA inventory SARA 302/304: Not listed SARA (TITLE 313): Not listed SARA 311/312 HAZARD: Acute Health Hazard PENNSYLVANIA RIGHT TO KNOW: Gadolinium (III) Fluoride NEW JERSEY RIGHT TO KNOW: Gadolinium (III) Fluoride CALIFORNIA PROP. 65: Not Listed GADOLINIUM (III) FLUORIDE PAGE 3 PAGE 4 SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 05/15 SDS DEPT. GADOLINIUM (III) FLUORIDE PAGE 4