# Gadolinium \(III\) Nitrate Hexahydrate — Safety Data Sheet — ProChem 原本PDFから抽出したテキストです。表、画像、記号、OCR結果は原本と異なる場合があります。安全情報は原本PDFで確認してください。 - **文書名:** Gadolinium \(III\) Nitrate Hexahydrate — Safety Data Sheet — ProChem - **発行元:** ProChem - **材料:** Gadolinium \(III\) Nitrate Hexahydrate - **CAS番号:** 19598\-90\-4 - **製品番号・グレード:** 1835 - **文書種類:** SDS - **原文の言語:** English - **地域:** - **改訂日:** - **ページ数:** 4 - **原本ファイル名:** 044\_Gadolinium\_III\_Nitrate\_Hexahydrate\_ProChem\_EN\.pdf - **RESDSページ:** https://resds\.com/document/gadolinium\-iii\-nitrate\-hexahydrate\-sds\-en\-6f1e9964af - **原本PDF:** https://resds\.com/pdf/gadolinium\-iii\-nitrate\-hexahydrate\-sds\-en\-6f1e9964af\.pdf - **情報源URL:** https://prochemonline\.com/wp\-content/uploads/2021/06/1835\.GadoliniumIIINitrateHexahydrate\.pdf - **説明:** Original ProChem safety data sheet for Gadolinium \(III\) Nitrate Hexahydrate\. Original PDF retained without modification\. Source collected on 2026\-09\-13\. ## ページ 1 ```text SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Gadolinium (III) Nitrate Hexahydrate PRODUCT NUMBER: 1835 CAS NUMBER: 19598-90-4 SYNONYMS: Nitric acid, gadolinium(3+) salt, hexahydrate MANUFACTURER: Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Signal Word Danger Hazard Statements H272 May intensify fire; oxidizer. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary Phrases P210 Keep away from heat/sparks/open flames/hot surfaces. P220 Keep/store away from clothing/combustible material. P221 Take any precaution to avoid mixing with combustibles. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with waster for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse. P370+P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction P403+P233 Store in a well-ventilated place. Keep container tightly closed GADOLINIUM (III) NITRATE HEXAHYDRATE PAGE 1 ``` ## ページ 2 ```text SECTION 2 HAZARDS IDENTIFICATION (Cont.) HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 2 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 2 Specific Hazard: OX EYE CONTACT: May cause slight to mild irritation of the eyes. SKIN CONTACT: May cause slight to mild irritation of the skin. INHALATION: May be irritating to the nose, mucous membranes, and respiratory tract. INGESTION: Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: Gd(NO3)3 Ÿ 6H2O Molecular Weight: 451.36 CHEMICAL NAME CAS# % Gadolinium (III) nitrate hexahydrate 19598-90-4 100 SECTION 4 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water. Induce vomiting only if directed by medical personnel. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Not available AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Carbon dioxide, dry powder, or foam. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Nitrogen oxides and gadolinium oxides SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the formation of dust. Avoid breathing vapors, mist, gas, or dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Pick up and arrange disposal without creating dust. Sweep up and keep in suitable, closed containers for disposal. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Avoid formation of dusts and aerosols. Keep away from heat and sources of ignition. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Keep away from heat and direct sunlight. GADOLINIUM (III) NITRATE HEXAHYDRATE PAGE 2 ``` ## ページ 3 ```text SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: White crystal with lumps ODOR: No data available MOLECULAR WEIGHT: 451.36 BOILING POINT: No data available MELTING POINT: No data available SPECIFIC GRAVITY: 2.406 gm/ml VAPOR DENSITY: No data available SOLUBILITY: Very soluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Avoid moisture. Avoid contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high temperatures. INCOMPATIBILITY: Strong reducing agents, strong acids, organic materials, powdered metals, phosphorous, and sulfur. DECOMPOSITION PRODUCTS: Nitrogen oxides and gadolinium oxides. SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: LD50 Oral – rat – >5gm/kg. LD50 Intraperitoneal – rat – 230mg/kg. LD50 Intravenous – rat – 30mg/kg. LD50 Intraperitoneal – mouse – 300mg/kg. CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available RTECS: LW4725000 Rare earth compounds may cause delayed blood clotting leading to hemorrhages. Inhalation of rare earths may cause sensitivity to heat, itching, and increased awareness of odor and taste. To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA No data available. SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. GADOLINIUM (III) NITRATE HEXAHYDRATE PAGE 3 ``` ## ページ 4 ```text SECTION 14 TRANSPORTATION DATA UN1477 Nitrates, inorganic, n.o.s. (Gadolinium Nitrate) CLASS 5.1 PG II Marine Pollutant: No SECTION 15 REGULATORY INFORMATION TSCA: Listed in the TSCA inventory SARA 302/304: Not Listed SARA 311/312: Reactivity hazard, Acute Health Hazard SARA (TITLE 313): Not Listed CALIFORNIA PROP. 65: Not Listed WHMIS CANADA: Not Listed MASSACHUSETTS RIGHT TO KNOW COMPONENTS: No components are subject to the Massachusetts Right to Know Act. NEW JERSEY RIGHT TO KNOW COMPONENTS: Gadolinium (III) nitrate hexahydrate PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Gadolinium (III) nitrate hexahydrate SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 12/14 GADOLINIUM (III) NITRATE HEXAHYDRATE PAGE 4 ```