Gadolinium Vanadate — Safety Data Sheet — ProChem PAGE 1 SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Gadolinium Vanadate PRODUCT NUMBER: 1849 MANUFACTURER: Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Signal Word Danger Hazard Statements H301 Toxic if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary Phrases P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink, or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P312+P330 IF SWALLOWED: Call a POISON CENTER or doctor/physician. Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340+P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 0 GADOLINIUM VANADATE PAGE 1 PAGE 2 SECTION 2 HAZARDS IDENTIFICATION (Cont.) EYE CONTACT: Causes serious eye irritation. SKIN CONTACT: Causes skin irritation. INHALATION: May cause respiratory irritation. INGESTION: Toxic if swallowed. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: GdVO4 Molecular Weight: 272.19 CHEMICAL NAME CAS# % Gadolinium Vanadate - 100 SECTION 4 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. INGESTION: Seek medical attention. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Not applicable AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Gadolinium oxide and vanadium oxides SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the formation of dust. Avoid breathing vapors, mist, gas, or dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Sweep up and place in a suitable container for proper disposal. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Avoid formation of dusts and aerosols. Further processing of solid materials may result in the formation of combustible dusts. The potential for combustible dust formation should be taken into consideration before additional processing occurs. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Hygroscopic. Keep in a dry place. GADOLINIUM VANADATE PAGE 2 PAGE 3 SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EXPOSURE CONTROLS: Contains a substance with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: Brown powder ODOR: None MOLECULAR WEIGHT: 272.19 BOILING POINT: No data available MELTING POINT: No data available SPECIFIC GRAVITY: No data available VAPOR DENSITY: No data available SOLUBILITY: Insoluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: No data INCOMPATIBILITY: Strong oxidizing agents. DECOMPOSITION PRODUCTS: Gadolinium oxide and vanadium oxides SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: No data available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available CHRONIC TOXICITY: Not available RTECS: Not available To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA No information available SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. GADOLINIUM VANADATE PAGE 3 PAGE 4 SECTION 14 TRANSPORTATION DATA UN3285 Vanadium compound, n.o.s. (Gadolinium vanadate) CLASS 6.1 PG III Marine Pollutant: No SECTION 15 REGULATORY INFORMATION SARA 302/304: Not Listed SARA 311/312: Acute Health Hazard SARA (TITLE 313): Gadolinium vanadate CALIFORNIA PROP. 65: Not Listed WHMIS CANADA: Not Listed MASSACHUSETTS RIGHT TO KNOW COMPONENTS: No components are subject to the Massachusetts Right to Know Act. NEW JERSEY RIGHT TO KNOW COMPONENTS: Gadolinium vanadate PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Gadolinium vanadate SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 06/15 SDS DEPT. GADOLINIUM VANADATE PAGE 4