# Lanthanum, compound with nickel \(1:5\) SDS – Avocado Research Chemicals Ltd\. \(Part of Thermo Fisher Scientific\)

Text extracted from the original PDF. Tables, images, symbols and OCR may differ. Check the original PDF for safety information.

- **Document title:** Lanthanum, compound with nickel \(1:5\) SDS – Avocado Research Chemicals Ltd\. \(Part of Thermo Fisher Scientific\)
- **Publisher:** Avocado Research Chemicals Ltd\. \(Part of Thermo Fisher Scientific\)
- **Material:** Lanthanum, compound with nickel \(1:5\)
- **CAS number:** 12196\-72\-4
- **Product code / grade:** ALFAA11271
- **Document type:** SDS
- **Original language:** English
- **Region:** United Kingdom
- **Revision date:** 31\-Jul\-2026
- **Page count:** 8
- **Original filename:** thermofisher\-ALFAA11271\-Lanthanum\-EN\.pdf
- **RESDS page:** https://resds\.com/document/lanthanum\-compound\-with\-nickel\-1\-5\-sds\-avocado\-research\-chemicals\-ltd\-part\-of\-thermo\-fisher\-en\-5cb5e69e7f
- **Original PDF:** https://resds\.com/pdf/lanthanum\-compound\-with\-nickel\-1\-5\-sds\-avocado\-research\-chemicals\-ltd\-part\-of\-thermo\-fisher\-en\-5cb5e69e7f\.pdf
- **Source URL:** https://assets\.thermofisher\.com/DirectWebViewer/private/results\.aspx?LANGUAGE=d\_\_EN&PLANT=d\_\_ALF&SKU=ALFAA11271&SUBFORMAT=d\_\_CGV4&page=NewSearch
- **Description:** Collected by RESDS\. Original publisher PDF retained\. Original manufacturer safety data sheet for Lanthanum, compound with nickel \(1:5\)\. Product number: ALFAA11271\. Original revision: 31\-Jul\-2026\. Published under the file\-level authorization confirmed by the user for the frozen 1,125\-file manifest\.

## Page 1

```text
                                                                                                     Page 1 / 8             SAFETY DATA SHEET
                                                                                                     Revision Date 31-Jul-2026
                                                                                                                   Version 5


 ALFAA11271

                Lanthanum, compound with nickel (1:5)

   SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING


产品说明:产品说明:产品说明:产品说明:            镧镍合金镧镍合金镧镍合金镧镍合金
Product Description:             Lanthanum, compound with nickel (1:5)

Cat No. :                        11271
CAS No                           12196-72-4
Molecular Formula                LaNi5

Supplier                         Avocado Research Chemicals Ltd.
                                        (Part of Thermo Fisher Scientific)
                                 Shore Road, Heysham
                                     Lancashire, LA3 2XY,
                                    United Kingdom
                                        Office Tel: +44 (0) 1524 850506
                                        Office Fax: +44 (0) 1524 850608


Emergency Telephone Number     For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11
                               Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99
                         CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address                    begel.sdsdesk@thermofisher.com

Recommended Use                 Laboratory chemicals.
Uses advised against           No Information available

                           SECTION 2. HAZARD IDENTIFICATION


            Physical State                      Appearance                          Odor
               Solid Pieces                            Grey                                 Odorless

                                        Emergency Overview
May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing cancer. Flammable solid. Moisture
                     sensitive. Air sensitive. Causes damage to organs through prolonged or repeated exposure.


Classification of the substance or mixture

Flammable solids.                                                                Category 2
Respiratory Sensitization                                                          Category 1
Carcinogenicity                                                                   Category 2
Specific target organ toxicity - (repeated exposure)                                    Category 1

Label Elements





______________________________________________________________________________________________
                                              Page 1
```

## Page 2

```text
ALFAA11271               SAFETY DATA SHEET                     Revision Date 31-Jul-2026Page 2 / 8
                                   Lanthanum, compound with nickel (1:5)
______________________________________________________________________________________________
Signal Word                    Danger

Hazard Statements
H228 - Flammable solid
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H351 - Suspected of causing cancer
H372 - Causes damage to organs through prolonged or repeated exposure

Precautionary Statements
Prevention
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P240 - Ground and bond container and receiving equipment
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - In case of inadequate ventilation wear respiratory protection
Response
P304 + P341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish
Storage
P403 - Store in a well-ventilated place
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards
Combustible material.
Health Hazards
May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing cancer. Causes damage to organs
through prolonged or repeated exposure.
Environmental hazards
Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants.

This product does not contain any known or suspected endocrine disruptors.

                  SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS


                           Component                              CAS No                Weight %
                     Lanthanum, compound with nickel (1:5)                             12196-72-4                <=100



                            SECTION 4. FIRST AID MEASURES


General Advice
If symptoms persist, call a physician.

Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation
Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion
______________________________________________________________________________________________
                                              Page 2
```

## Page 3

```text
ALFAA11271               SAFETY DATA SHEET                     Revision Date 31-Jul-2026Page 3 / 8
                                   Lanthanum, compound with nickel (1:5)
______________________________________________________________________________________________
Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Most important symptoms and effects
May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms of allergic reaction may include rash, itching,
swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing


Self-Protection of the First Aider
Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of
contamination.

Notes to Physician
Treat symptomatically.

                          SECTION 5. FIRE-FIGHTING MEASURES


Suitable Extinguishing Media
approved class D extinguishers. Do not use water or foam.

Extinguishing media which must not be used for safety reasons
No information available.

Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapors.


Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

                       SECTION 6. ACCIDENTAL RELEASE MEASURES


Personal Precautions
Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation.


Environmental Precautions
Should not be released into the environment. See Section 12 for additional Ecological Information. Do not allow material to
contaminate ground water system. Do not flush into surface water or sanitary sewer system.


Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal.


Refer to protective measures listed in Sections 8 and 13.

                          SECTION 7. HANDLING AND STORAGE


Handling
Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid
ingestion and inhalation. Avoid dust formation.

Storage
Keep container tightly closed in a dry and well-ventilated place.

Specific Use(s)
Use in laboratories

                  SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION


______________________________________________________________________________________________
                                              Page 3
```

## Page 4

```text
ALFAA11271               SAFETY DATA SHEET                     Revision Date 31-Jul-2026Page 4 / 8
                                   Lanthanum, compound with nickel (1:5)
______________________________________________________________________________________________
Control Parameters

      Component                China              ACGIH TLV           OSHA PEL              NIOSH
 Lanthanum, compound with                    -               TWA: 0.2 mg/m3        (Vacated) TWA: 1 mg/m3        IDLH: 10 mg/m3
          nickel (1:5)                                                                    REL = 0.015 mg/m3 (TWA)

      Component            Hong Kong                Thailand            European Union       The United Kingdom
 Lanthanum, compound with                    -               TWA: 1 mg/m3                               STEL: 1.5 mg/m3 15 min
          nickel (1:5)                                                                        TWA: 0.5 mg/m3 8 hr
                                                                                                                       Skin

Legend

ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
NIOSH: NIOSH - National Institute for Occupational Safety and Health

Monitoring methods
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of
exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and
inhalable dust MDHS 91 Metals and metalloids in workplace air by X-ray fluorescence spectrometry MDHS 99 Metals in air by
ICP-AES

Exposure Controls

Engineering Measures
Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation
or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of
properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

   Eye Protection              Wear safety glasses with side shields (or goggles) (European standard - EN 166)

   Hand Protection                  Protective gloves

    Glove material     Breakthrough time  Glove thickness   EU standard             Glove comments
      Natural rubber     See manufacturers               -          EN 374             (minimum requirement)
        Nitrile rubber       recommendations
       Neoprene
       PVC
Inspect gloves before use.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
(Refer to manufacturer/supplier for information)
Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g.
sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger
of cuts, abrasion.
Remove gloves with care avoiding skin contamination.

   Skin and body protection       Long sleeved clothing

   Respiratory Protection       When workers are facing concentrations above the exposure limit they must use
                                      appropriate certified respirators.
                              To protect the wearer, respiratory protective equipment must be the correct fit and be used
                               and maintained properly

   Large scale/emergency use    Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits
                                    are exceeded or if irritation or other symptoms are experienced
                           Recommended Filter type: Particulates filter conforming to EN 143

   Small scale/Laboratory use     Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure
                                              limits are exceeded or if irritation or other symptoms are experienced.
                           Recommended half mask:- Particle filtering: EN149:2001
                           When RPE is used a face piece Fit Test should be conducted
______________________________________________________________________________________________
                                              Page 4
```

## Page 5

```text
ALFAA11271               SAFETY DATA SHEET                     Revision Date 31-Jul-2026Page 5 / 8
                                   Lanthanum, compound with nickel (1:5)
______________________________________________________________________________________________


Hygiene Measures                Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls  No information available.

                     SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance                      Grey
Physical State                        Solid Pieces

Odor                              Odorless
Odor Threshold               No data available
pH                         No information available
Melting Point/Range            No data available
Softening Point                No data available
Boiling Point/Range            No information available
Flash Point                   No information available           Method - No information available
Evaporation Rate                  Not applicable                         Solid
Flammability (solid,gas)         No information available
Explosion Limits               No data available

Vapor Pressure                No data available
Vapor Density                     Not applicable                         Solid
Specific Gravity  / Density           8.4 g/cm3            @ 20 °C
Bulk Density                  No data available
Water Solubility               No information available
Solubility in other solvents       No information available
Partition Coefficient (n-octanol/water)
Autoignition Temperature        No data available
Decomposition Temperature      No data available
Viscosity                         Not applicable                         Solid
Explosive Properties            No information available
Oxidizing Properties            No information available


Molecular Formula                LaNi5



                         SECTION 10. STABILITY AND REACTIVITY


Stability                                 Air sensitive. Moisture sensitive.

Hazardous Reactions            None under normal processing.
Hazardous Polymerization        No information available.

Conditions to Avoid             None known.

Materials to avoid                    Acids. Oxidizing agent.


Hazardous Decomposition Products Heavy metal oxides. Lanthanum oxide.

                        SECTION 11. TOXICOLOGICAL INFORMATION


Product Information

(a) acute toxicity;

(b) skin corrosion/irritation;       No data available

______________________________________________________________________________________________
                                              Page 5
```

## Page 6

```text
ALFAA11271               SAFETY DATA SHEET                     Revision Date 31-Jul-2026Page 6 / 8
                                   Lanthanum, compound with nickel (1:5)
______________________________________________________________________________________________

(c) serious eye damage/irritation;   No data available


(d) respiratory or skin sensitization;
   Respiratory                    Category 1
   Skin                     No data available

(e) germ cell mutagenicity;       No data available

(f) carcinogenicity;                 Category 2

                                 There are no known carcinogenic chemicals in this product



(g) reproductive toxicity;         No data available


(h) STOT-single exposure;        No data available



(i) STOT-repeated exposure;        Category 1

   Route of exposure                Inhalation
   Target Organs                   Respiratory system.


(j) aspiration hazard;               Not applicable
                                       Solid

Symptoms  / effects,both acute and Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
delayed                                 of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

                         SECTION 12. ECOLOGICAL INFORMATION


Ecotoxicity effects              May cause long-term adverse effects in the environment. Do not allow material to
                                   contaminate ground water system.




Persistence and Degradability      Product contains heavy metals. Discharge into the environment must be avoided. Special
                                      pre-treatment is necessary
   Persistence                May persist.
    Degradability                  Not relevant for inorganic substances.
   Degradation in sewage          Contains substances known to be hazardous to the environment or not degradable in waste
   treatment plant                 water treatment plants.


Bioaccumulative Potential          Product has a high potential to bioconcentrate



Mobility in soil                No information available


Endocrine Disruptor Information    This product does not contain any known or suspected endocrine disruptors
Persistent Organic Pollutant        This product does not contain any known or suspected substance
Ozone Depletion Potential           This product does not contain any known or suspected substance

                         SECTION 13. DISPOSAL CONSIDERATIONS


______________________________________________________________________________________________
                                              Page 6
```

## Page 7

```text
ALFAA11271               SAFETY DATA SHEET                     Revision Date 31-Jul-2026Page 7 / 8
                                   Lanthanum, compound with nickel (1:5)
______________________________________________________________________________________________
Waste from Residues/Unused      Waste is classified as hazardous. Dispose of in accordance with the European Directives
Products                        on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging           Dispose of this container to hazardous or special waste collection point. Empty containers
                                          retain product residue, (liquid and/or vapor), and can be dangerous. Keep product and
                                empty container away from heat and sources of ignition.

Other Information                Waste codes should be assigned by the user based on the application for which the product
                             was used. Do not flush to sewer. Can be landfilled or incinerated, when in compliance with
                                          local regulations.

                         SECTION 14. TRANSPORT INFORMATION


Road and Rail Transport

UN-No                       UN3178
Proper Shipping Name            Flammable solid, inorganic, n.o.s.
   Technical Shipping Name       (Lanthanum nickel)
Hazard Class                        4.1
Packing Group                                     III


IMDG/IMO

UN-No                       UN3178
Proper Shipping Name            Flammable solid, inorganic, n.o.s.
   Technical Shipping Name       (Lanthanum nickel)
Hazard Class                        4.1
Packing Group                                     III


IATA

UN-No                       UN3178
Proper Shipping Name            Flammable solid, inorganic, n.o.s.
   Technical Shipping Name       (Lanthanum nickel)
Hazard Class                        4.1
Packing Group                                     III


Special Precautions for User      No special precautions required

                         SECTION 15. REGULATORY INFORMATION



International Inventories
X = listed, China (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), Japan (ENCS), Japan
(ISHL), Australia (AICS), Korea (KECL).

    Component        The        List of    IECSC   EINECS   TSCA   DSL   PICCS  ENCS    ISHL    AICS    KECL
                     Inventory of dangerous
                   Hazardous  goods GB
                    Chemicals   12268 -
                        (2015      2012
                         Edition)
Lanthanum, compound         -                 -                -      235-372-5    X            -             -             -                          -     KE-21828
    with nickel (1:5)

        Component          Seveso III Directive (2012/18/EC) - Qualifying  Seveso III Directive (2012/18/EC) - Qualifying Quantities
                                  Quantities for Major Accident Notification                 for Safety Report Requirements
   Lanthanum, compound with                                                                 1 tonne
            nickel (1:5)

______________________________________________________________________________________________
                                              Page 7
```

## Page 8

```text
ALFAA11271               SAFETY DATA SHEET                     Revision Date 31-Jul-2026Page 8 / 8
                                   Lanthanum, compound with nickel (1:5)
______________________________________________________________________________________________

National Regulations


                            SECTION 16. OTHER INFORMATION


Prepared By                         Health, Safety and Environmental Department
Revision Date                      31-Jul-2026
Revision Summary                Not applicable.

Training Advice
Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and
hygiene.
Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit
and standards.
First aid for chemical exposure, including the use of eye wash and safety showers.

                                              Legend

CAS - Chemical Abstracts Service                          TSCA - United States Toxic Substances Control Act Section 8(b)
                                                                       Inventory
EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic
Substances/EU List of Notified Chemical Substances                  Substances List
PICCS - Philippines Inventory of Chemicals and Chemical Substances  ENCS - Japanese Existing and New Chemical Substances
IECSC - Chinese Inventory of Existing Chemical Substances          AICS - Australian Inventory of Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances         NZIoC - New Zealand Inventory of Chemicals


WEL - Workplace Exposure Limit                        TWA - Time Weighted Average
ACGIH - American Conference of Governmental Industrial Hygienists   IARC - International Agency for Research on Cancer
DNEL - Derived No Effect Level                           PNEC - Predicted No Effect Concentration
RPE - Respiratory Protective Equipment                        LD50 - Lethal Dose 50%
LC50 - Lethal Concentration 50%                            EC50 - Effective Concentration 50%
NOEC - No Observed Effect Concentration                 POW - Partition coefficient Octanol:Water
PBT - Persistent, Bioaccumulative, Toxic                       vPvB - very Persistent, very Bioaccumulative


ICAO/IATA - International Civil Aviation Organization/International Air   IMO/IMDG - International Maritime Organization/International Maritime
Transport Association                                          Dangerous Goods Code
ADR - European Agreement Concerning the International Carriage of   MARPOL - International Convention for the Prevention of Pollution from
Dangerous Goods by Road                                         Ships
OECD - Organisation for Economic Co-operation and Development    ATE - Acute Toxicity Estimate
BCF - Bioconcentration factor                           VOC - (Volatile Organic Compound)

Key literature references and sources for data
https://echa.europa.eu/information-on-chemicals
Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS




                                                    Disclaimer
 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
 date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
   transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
                                 materials or in any process, unless specified in the text

                    End of Safety Data Sheet





______________________________________________________________________________________________
                                              Page 8
```
