# Monazite – Safety Data Sheet

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- **Document title:** Monazite – Safety Data Sheet
- **Publisher:** RZ Resources Ltd
- **Material:** Monazite
- **CAS number:** 1306\-41\-8
- **Product code / grade:** 
- **Document type:** SDS
- **Original language:** English
- **Region:** Australia
- **Revision date:** October 4, 2022
- **Page count:** 5
- **Original filename:** rz\-monazite\.pdf
- **RESDS page:** https://resds\.com/document/monazite\-en\-21bd9fa19a
- **Original PDF:** https://resds\.com/pdf/monazite\-en\-21bd9fa19a\.pdf
- **Source URL:** https://rzresources\.com/wp\-content/uploads/2022/12/SDS\-RZ\-Monazite\-02\-Oct\-22\.pdf
- **Description:** Collected by RESDS\. Original publisher PDF retained\. Mineral sands concentrate used as raw material for rare\-earth compounds\. Section 3 is a multi\-mineral mixture; CAS numbers and composition are retained only as stated by the original SDS\. Revision 4 October 2022\. Source: RZ Resources Ltd\. Publication authorization confirmed by the RESDS site owner on 14 September 2026\.

## Page 1

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SAFETY DATA SHEET
Monazite


  1.  IDENTIFICATION MATERIAL SUPPLIER

  Product Names:       Monazite

  Other Names:          Mineral Sands Concentrate

  Uses:             Raw material to produce rare earth compounds

  Company:         RZ Resources Ltd

                  ABN 23 160 863 892

  Address:              Level 7, 10 Eagle Street,

                          Brisbane, Qld 4000

                            Australia

  Telephone:          +61 1300 735 386

  Email:                product@rzresources.com

  Web:                   https://rzresources.com/


  Emergency Contract:   +61 408 907 889 (24 hours)


  2.  HAZARDS IDENTIFICATION

   Classified as hazardous according to SafeWork Australia and the Global Harmonised System of classification and

   labelling of chemicals (GHS).

  GHS Classifications:
                     Acute Toxicity: Oral: Category 5
                         Carcinogenicity: Category 1B

  Hazard Statements:

  H302             Harmful if swallowed

  H332             Harmful if inhaled

  Precautionary Statements:

  P261             Avoid breathing dust/fume/gas/mist/vapors/spray.

  P264          Wash thoroughly after handling.

  P270          Do not eat, drink or smoke when using this product.

  P271           Use only outdoors or in a well-ventilated area.


  Other Hazards:    Radioactive





Date of Issue: October 4, 2022                                                                                Page 1 of 5
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## Page 2

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SAFETY DATA SHEET
Monazite


  3.  COMPOSITION / INFORMATION ON INGREDIENTS

     Ingredients (typical)               CAS Number           EC Number         Concentration

   Monazite                              1306-41-8                                 65-70%

   Cerium Phosphate                      13454-71-2                236-637-8          18-22%

    Yttrium Phosphate                      13990-54-0                237-790-3          10-14%

   Lanthanum Phosphate                  14913-14-5                237-419-5           8-12%

   Neodymium Phosphate                  14298-32-9                238-232-1           8-12%

   Thorium Phosphate                     14485-31-5                               -               4-6%

   Praseodymium Phosphate               14298-31-8                238-231-6           1-3%

   Samarium Phosphate                   13465-57-1                236-698-0           1-3%

   Dysprosium Phosphate                  13863-49-5                237-605-6           1-3%

    Gadolinium Phosphate                  13628-51-8                237-112-6           1-3%

    Ytterbium Phosphate                    13759-80-3                237-346-9           0.5-1.5%

   Uranium Phosphate                     18433-48-2                242-306-9            0.3 -0.4%



   Non monazite Components

    Zircon                                 14940-68-2                239-019-6          22-26%

    Rutile                                  1317-80-2                 215-282-2           2-4%

    Iron Oxide                              1309-37-1                 215-168-2           1-2%

    Quartz                                14808-60-7                238-878-4           1-2%




  4.  FIRST AID MEASURES

  Swallowed:               First aid is unlikely to be required but, if necessary, wash mouth out with water ensuring the
                     mouthwash is not swallowed. Give one or two glasses of water to drink. Seek medical
                            attention if a large quantity has been swallowed.

   Inhaled:             Blow nose to remove particulates from nose. Move to area with fresh air. Seek medical
                            attention if adverse reaction develops.

   Skin:              Remove contaminated clothing gently to avoid creating dust. Wash skin. If skin becomes
                                 irritated, seek medical attention. Launder affected clothing before re-use

   Eye:                 Hold eyelid open and flush with clean water. Continue until grit is removed. Seek medical
                            attention if irritation or soreness persists.

  Acute
  Swallowed:             Non-toxic. No known detrimental effect from accident ingestion as may occur during normal
                           handling. Ingestion of large amounts may cause irritation to the gastro-intestinal system due
                             to abrasiveness.





Date of Issue: October 4, 2022                                                                                Page 2 of 5
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## Page 3

```text
SAFETY DATA SHEET
Monazite


   Inhaled:               Mainly regarded as nuisance dust but may be irritating if inhaled at high concentrations. May
                      cause coughing and/or sneezing.

   Skin:              Low hazard.

  Eye:                    Solid and dust can be moderately irritating due to abrasiveness.

  Chronic
   Radiation:            Monazite contains naturally occurring radioactive elements of the uranium and thorium
                            series. The Monazite produced by RZ Resources Ltd contains concentrations of these
                            impurities with a typical specific activity of approximately 200 Bq/g of combined uranium and
                           thorium.

                              •  170 Bq/g (thorium-232) and
                              •  30 Bq/g (uranium-238).

                       Daughter  products are  present,  usually  at  equilibrium  concentrations  but  the main
                             radiological hazard is internal dust. As a guide, continuous worker exposure to respirable dust
                            levels above 3.5mg/m3 could give rise to annual internal exposures above 1 mSv.

                          External exposure is from gamma radiation. Continuous exposure (2000 hours per year)
                            within 2 meters of bulk Monazite could give rise to an annual external dose above 1 mSv.

   Silica:                Monazite contains amounts of free quartz and precautions should be taken to avoid inhaling
                          the dust.

   First Aid Facilities:     Eye Wash Station

  Doctor Treatment:      Treat symptomatically

  5. FIRE FIGHTING MEASURES

  Non-flammable, non-combustible. Use suitable firefighting measures for the surrounding fire.

  6. ACCIDENTAL RELEASE MEASURES

  Emergency Procedures:       Not relevant

  Containment and Clean-up:   Wear safety equipment for normal handling. Avoid generating dust. Vacuum up, if
                                   possible, otherwise sweep up and recycle. If the spilled product is not suitable for
                                   re-use, dispose of as radioactive waste.

  7. HANDLING AND STORAGE

  Handling:                     Dust generation should be minimised when handling. Wash thoroughly after handling.

  Storage:                     Storage areas should be ventilated.





Date of Issue: October 4, 2022                                                                                Page 3 of 5
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## Page 4

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SAFETY DATA SHEET
Monazite


  8. EXPOSURE CONTROLS / PERSONAL PROTECTION

 National Exposure Standards (Source: Safe Work Australia):

      Ingredient                                          TWA (mg/m3)    STEL (mg/m3)
    Titanium dioxide                                                        10                        -

    Iron Oxide                                                             5                        -

    Respirable silica (quartz)                                                       0.05                      -

    Zirconium compounds (as Zr)                                              5              10

   Uranium                                                                          0.2                0.6


   Biological Limit Values:       No information

  Engineering Controls:           Ventilation requirements will depend on handling methods and the amounts in use,
                                  but should be sufficient to maintain dust levels below exposure limits.

   Personal Protective Equipment:  Safety glasses or goggles. If there is a risk of inhaling dust, wear an approved P2, or
                                       better, respirator.

  9. PHYSICAL CHEMICAL PROPERTIES

  Appearance:                 Brownish free running sand

  Odour:                      Odourless

  pH:                       5 - 7

  Vapour Pressure:             Not applicable

   Boiling Point/Range:          Not applicable

   Melting Point:                 Monazite 1900°C -2100°C, Rutile 1840°C, Quartz 1700°C, Zirconia 2200°C

   Solubility:                       Insoluble

  Bulk Density:                2900 kg/m3

  Flash Point:                  Not applicable

  Flammability Limits:           Not applicable


  10. STABILITY AND REACTIVITY

   Reactivity:                         Inert

  Chemical Stability:             Stable

  Incompatible Materials:       None in normal or expected use

  Decomposition Products:       Decomposition will not occur


  11. TOXICOLOGICAL INFORMATION

  Acute Toxicity:      Harmful if swallowed or inhaled





Date of Issue: October 4, 2022                                                                                Page 4 of 5
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## Page 5

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SAFETY DATA SHEET
Monazite


  12. ECOLOGICAL INFORMATION

  No information available.

  13. DISPOSAL CONSIDERATION

    If not reusable, dispose in accordance with Commonwealth, State and local government and regulations for
   radioactive waste.

  14. TRANSPORT INFORMATION

  UN Code 2912 - Classified as a Class 7 Dangerous Goods according to the Australian Code for the Transport of
  Dangerous Goods by road and rail (ADG) and international codes, IATA and IMDG.





                  LAND TRANSPORT        SEA TRANSPORT          AIR TRANSPORT
                          (CNDG)                 (IMDG / IMO)               (IATA / ICAO)
  UN Number                 2912                      2912                     2912
  Proper Shipping    RADIOACTIVE MATERIAL,    RADIOACTIVE MATERIAL,   RADIOACTIVE MATERIAL,
  Name          LOW SPECIFIC ACTIVITY   LOW SPECIFIC ACTIVITY   LOW SPECIFIC ACTIVITY
                                  (LSA-I), non                     (LSA-I), non                    (LSA-I), non
                                 fissile or fissile-excepted          fissile or fissile-excepted         fissile or fissile-excepted
  Transport hazard              7                         7                        7
  class

  Packing Group         None allocated.             None allocated.            None allocated.


  Transport of Class 7 by road or rail in Australia is subject to separate state and territory legislation and the ARPANZA
  Code of Practice for the Safe Transport of Radioactive Substances (2008).

  Transport may be regulated in some countries.

   Material should be transported in sealed containers to prevent spillage and leakage. All spillages should be cleaned
  up immediately.

  15. REGULATORY INFORMATON

  Poisons Schedule:    None allocated

  16. OTHER INFORMATION

  Date of Issue:                October 4, 2022

  Replaces Issue:              August 8, 2022

  Review Date:                 October 4, 2027


  End of Safety Data Sheet





Date of Issue: October 4, 2022                                                                                Page 5 of 5
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