Palladium-102 SDS (Pd-102 / 102Pd) — Palladium Metal Powder, Enriched Palladium Metal Powder PAGE 1 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. Section 1: Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier: Identification as on the label/Trade name: Palladium, Enriched Palladium. Molecular weight: 106.42 Chemical formula: Pd Synonyms: Palladium (powder), Palladium black, Palladium element. Details of the supplier of the Safety Data Sheet: Neonest AB Storgatan 70C, Solna SE-17152 Sweden Contact details: +46-76-219-9731 24-hour Emergency Contact: Swedish Poisons Centre Phone: 112 - Ask for Poisons Information, 112 – begär Giftinformation. Other International Contacts: CHEMTREC 24-hour: +1-703-741-5500 (US + Worldwide) NHS: 111 (UK) Charite: +49 30 450 531 000 (Netherlands) INTCF: +34 917689800 (Spain) CapTv: +33 1 40 05 48 48 (France) Section 2: Hazards Identification Classification of the substances or mixture: The mixture is classified according to: Regulation EC 1272/2008 [EU-GHS/CLP] Hazard classes/Hazard categories: Hazard statement: Flammable solids (Category 1) H228 Skin irritation (Category 2) H315 Eye irritation (Category 2) H319 Specific target organ toxicity - single exposure (Category 3), Respiratory system H335 Label elements: Hazard pictograms: Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 1/10 PAGE 2 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. Signal Words: Danger. Hazard Statements: H228 Flammable solid. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary Statements: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P302 + P352 IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Other hazards: None known. Section 3: Composition/Information on Ingredients Substance/Mixture: Substance. Ingredients: CAS-No. Molecular Concentration Classification Substance name (IUPAC/EC) EC-No. weight % by weight EC1272/2008 7440-05-3 106.42 Flam. Sol. 1; Skin Irrit. 2; Palladium <= 100 % 231-115-6 Eye Irrit. 2; STOT SE 3; H228, H315, H319, H335. For explanation of abbreviations see Section 16. Section 4: First-Aid Measures Description of first aid measures: In case of inhalation: If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact: Wash off with soap and plenty of water. In case of eye contact: Flush eyes with water for at least 15 minutes as a precaution. In case of ingestion: Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Rinse mouth with water. Most important symptoms and effects, both acute and delayed: Inhalation: May be harmful if inhaled. May cause respiratory tract irritation. Eyes: May cause eye irritation. Skin contact: May be harmful if absorbed through skin. May cause skin irritation. Ingestion: May be harmful if swallowed. Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 2/10 PAGE 3 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. Indication of any immediate medical attention and special treatment needed: Treat symptomatically. Show this safety data sheet to a physician or emergency room. Section 5: Fire-Fighting Measures Extinguisher media: Suitable extinguisher media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media: None known. Special hazards arising from the mixture: Hafnium oxide. Advice for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Further information: Standard procedure for chemical fires. Use water spray to cool unopened containers. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures: Personal precautions: Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Local authorities should be advised if significant spillages cannot be contained. Methods for containment and cleaning up: Methods for cleaning up: Sweep up and shovel. Keep in suitable, closed containers for disposal. Contain spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local regulations. Reference to other sections: Treat recovered material as described in the section "Disposal considerations". Section 7: Handling and Storage Precautions for safe handling: Advice on safe handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Hygiene measures: Do not eat, drink or smoke when using this product. Take measures to prevent the build up of electrostatic charge. Conditions for safe storage, including incompatibilities: Requirements for storage areas and containers: Keep container tightly closed in a dry and well-ventilated place. Store in cool place. Section 8: Exposure Controls/Personal Protection Control parameters: Occupational exposure limits: Contains no substances with occupational exposure limit values Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 3/10 PAGE 4 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. Exposure controls: Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. A system of local or mechanical exhaust is recommended to keep dust levels low. Individual protection measures, such as personal protective equipment: Eye/face protection: Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body protection: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific workplace. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection: Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N100 (US) or type P3 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section 9: Physical and Chemical Properties Information on basic physical and chemical properties Appearance (form): Solid (powder). Colour: Grey. Odour: No data available. Odour threshold: No data available. Molecular Weight: 106.42 pH (concentration): No data available. Melting point/range (°C): 1554 °C Boiling point/range (°C): 2970 °C Freezing point (°C): No data available. Flash point (°C): No data available. Evaporation rate: No data available. Flammability (solid, gas): No data available. Ignition temperature (°C): No data available. Upper/lower flammability/explosive limits: No data available. Vapour pressure (20 °C): No data available Vapour density: No data available. Relative density (25 °C): 12.02 g/cm3 Water solubility (g/L) at 20 °C: Insoluble. n-Octanol/Water partition coefficient: No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity, dynamic (mPa s): No data available. Explosive properties: The substance or mixture is not classified as explosive. Oxidising properties: The substance or mixture is not classified as oxidizing. Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 4/10 PAGE 5 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. Section 10: Stability and Reactivity Reactivity: No data available. Chemical stability: Stable under recommended storage conditions. Possibility of hazardous reactions: No data available. Conditions to avoid: Heat, flames and sparks. Incompatible materials: Strong acids, Halogens, Bases, Palladium undergoes a violent reaction with arsenic, Methanol, Ethanol, AlcoholsStrong oxidizing agents. Hazardous decomposition products: No data available. Section 11: Toxicological Information Information on toxicological effects: Not classified based on available information. Classification according to GHS (1272/2008/EG, CLP) Skin corrosion/irritation: Not classified based on available information. Serious eye damage/eye irritation: Not classified based on available information. Respiratory or skin sensitisation: Not classified based on available information. Germ cell mutagenicity: Not classified based on available information. Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as a probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Reproductive toxicity: Not classified based on available information. Specific target organ toxicity – single exposure (STOT): Not classified based on available information. Specific target organ toxicity (STOT) – repeated exposure: Not classified based on available information. Aspiration toxicity: Not classified based on available information. Section 12: Ecological Information Toxicity: No data available. Persistence and degradability: No data available. Bioaccumulative potential: No data available. Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 5/10 PAGE 6 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. Mobility in soil: No data available. Results of PBT& vPvB assessment: Not relevant. Other adverse effects: No data available. Section 13: Disposal Considerations Waste treatment methods: Offer surplus and non-recyclable solutions to a licensed disposal company. Recycle products when possible (RCRA 40 CFR 261). Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Ensure proper disposal compliance with federal state and local laws before disposal. Section 14: Transport Information DOT (US): Proper shipping Name: METAL POWDER, FLAMMABLE, N.O.S Hazard Class: 4.1 UN Number: 3089 Packing Group: III Hazard Label: IMO: Proper shipping Name: METAL POWDER, FLAMMABLE, N.O.S Hazard Class: 4.1 UN Number: 3089 Packing Group: III IATA: Proper shipping Name: Metal powder, flammable, n.o.s. Hazard Class: 4.1 UN Number: 3089 Packing Group: III Special precautions for user: No data available. Section 15: Regulatory Information EU regulations: Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed. Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I Not listed. Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 6/10 PAGE 7 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed. Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Not listed. Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed. Authorisations: Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed. Restrictions on use: Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Not listed. Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding. Not regulated. Other EU regulations: Directive 2012/18/EU on major accident hazards involving dangerous substances Not listed. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Always applicable. Directive 94/33/EC on the protection of young people at work Not listed. Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended. OSHA Hazards: No known OSHA hazards. DSL Status: All components of this product are on the Canadian DSL list. Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 7/10 PAGE 8 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Powders: Fire hazard, Acute health hazard. RCRA: No TSCA: Palladium metal powder is listed TSCA inventory 8(b). CERCLA: None listed. Massachusetts Right to Know Components: No components are subject to the Massachusetts Right to Know Act. Pennsylvania Right to Know Components: Palladium / CAS No. 7440-05-3 / Revision Date: None New Jersey Right to Know Components: Palladium / CAS No. 7440-05-3 / Revision Date: None California Prop. 65 Components: This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm. International Regulations Canada WHMIS: Palladium powder: CLASS B-4: Flammable solid Europe EINECS Nos.: 231-115-6 National regulations: Follow national regulation for work with chemical agents. Chemical safety assessment: No Chemical Safety Assessment has been carried out. Section 16: Other Information List of abbreviations: ACGIH American Conference of Governmental Industrial Hygienists ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road ALARA As Low As Is Reasonably Achievable AMU Atomic Mass Unit ANSI American National Standards Institute BLS Basic Life Support CAM Continuous Air Monitor CAS Chemical Abstracts Service (division of the American Chemical Society) CEN European Committee for Standardization CERCLA Comprehensive Environmental Response Compensation and Liability Act CLP Classification, Labelling and Packaging (European Union) CPR Controlled Products Regulations (Canada) CWA Clean Water Act (USA) DAC Derived Air Concentration (USA) DOE United States Department of Energy (USA) DOT United States Department of Transportation (USA) DSL Domestic Substances List (Canada) EC50 Half Maximal Effective Concentration EINECS European Inventory of Existing Commercial Chemical Substances EHS Environmentally Hazardous Substance ELINCS European List of Notified Chemical Substances EMS Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency (USA) EPCRA Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 GHS Globally Harmonized System Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 8/10 PAGE 9 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. HMIS Hazardous Materials Identification System (USA) IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Containers ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life or Health IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent LDLO Lethal Dose Low LOEC Lowest-Observed-Effective Concentration MARPOL International Convention for the Prevention of Pollution from Ships MSHA Mine Safety and Health Administration (USA) NCRP National Council on Radiation Protection & Measurements (USA) NDSL Non-Domestic Substances List (Canada) NFPA National Fire Protection Association (USA) NIOSH National Institute for Occupational Safety and Health (USA) NOEC No Observed Effect Concentration N.O.S. Not Otherwise Specified NRC Nuclear Regulatory Commission (USA) NTP National Toxicology Program (USA) OSHA Occupational Safety and Health Administration (USA) PBT Persistent Bioaccumulative and Toxic Chemical PEL Permissible Exposure Limit PIH Poisonous by Inhalation Hazard RCRA Resource Conservation and Recovery Act (USA) RCT Radiation Control Technician REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (Europe) RID Regulations Concerning the International Transport of Dangerous Goods by Rail RTECS Registry of Toxic Effects of Chemical Substances SARA Superfund Amendments and Reauthorization Act (USA) TDG Transportation of Dangerous Goods (Canada) TIH Toxic by Inhalation Hazard TLV Threshold Limit Value TPQ Threshold Planning Quantity TSCA Toxic Substances Control Act TWA Time Weighted Average UN United Nations (Number) VOC Volatile Organic Compound vPvB Very Persistent Very Bioaccumulative Chemical WGK Wassergefährdungsklassen (Germany: Water Hazard Classes) WHMIS Workplace Hazardous Materials Information System References: Not available. Full text of any H-statements not written out in full under Sections 2 to 15: None. Revision information: Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 9/10 PAGE 10 Safety Data Sheet for Palladium Metal Powder, Enriched Palladium Metal Powder According to ISO 11014:2010 First Print Date: 5-March-2015 Revision Date: 10-May-2020 Version: 1.1.1. None. Training information: Follow training instructions when handling this material. Further Information: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Safety Data Sheet (SDS) for Palladium Metal Powder, Enriched Palladium https://www.buyisotope.com Page 10/10