# Samarium \(III\) fluoride SDS – Avocado Research Chemicals Ltd\. \(Part of Thermo Fisher Scientific\) 原本PDFから抽出したテキストです。表、画像、記号、OCR結果は原本と異なる場合があります。安全情報は原本PDFで確認してください。 - **文書名:** Samarium \(III\) fluoride SDS – Avocado Research Chemicals Ltd\. \(Part of Thermo Fisher Scientific\) - **発行元:** Avocado Research Chemicals Ltd\. \(Part of Thermo Fisher Scientific\) - **材料:** Samarium \(III\) fluoride - **CAS番号:** 13765\-24\-7 - **製品番号・グレード:** ALFAA13660 - **文書種類:** SDS - **原文の言語:** English - **地域:** United Kingdom - **改訂日:** 27\-Jul\-2026 - **ページ数:** 8 - **原本ファイル名:** thermofisher\-ALFAA13660\-Samarium\-EN\.pdf - **RESDSページ:** https://resds\.com/document/samarium\-iii\-fluoride\-sds\-avocado\-research\-chemicals\-ltd\-part\-of\-thermo\-fisher\-en\-e7bea0d0fb - **原本PDF:** https://resds\.com/pdf/samarium\-iii\-fluoride\-sds\-avocado\-research\-chemicals\-ltd\-part\-of\-thermo\-fisher\-en\-e7bea0d0fb\.pdf - **情報源URL:** https://assets\.thermofisher\.com/DirectWebViewer/private/results\.aspx?LANGUAGE=d\_\_EN&PLANT=d\_\_ALF&SKU=ALFAA13660&SUBFORMAT=d\_\_CGV4&page=NewSearch - **説明:** Collected by RESDS\. Original publisher PDF retained\. Original manufacturer safety data sheet for Samarium \(III\) fluoride\. Product number: ALFAA13660\. Original revision: 27\-Jul\-2026\. Published under the file\-level authorization confirmed by the user for the frozen 1,125\-file manifest\. ## ページ 1 ```text Page 1 / 8 SAFETY DATA SHEET Creation Date 19-Oct-2010 Revision Date 27-Jul-2026 Version 5 ALFAA13660 Samarium (III) fluoride SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 产品说明:产品说明:产品说明:产品说明: 氟化钐氟化钐氟化钐氟化钐 Product Description: Samarium (III) fluoride Cat No. : 13660 CAS No 13765-24-7 Molecular Formula F3Sm Supplier Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887 E-mail address begel.sdsdesk@thermofisher.com Recommended Use Laboratory chemicals. Uses advised against No Information available SECTION 2. HAZARD IDENTIFICATION Physical State Appearance Odor Solid No information available No information available Emergency Overview Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Classification of the substance or mixture Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Specific target organ toxicity - (single exposure) Category 3 Label Elements Signal Word Warning Hazard Statements ______________________________________________________________________________________________ Page 1 ``` ## ページ 2 ```text ALFAA13660 SAFETY DATA SHEET Revision Date 27-Jul-2026Page 2 / 8 Samarium (III) fluoride ______________________________________________________________________________________________ H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation Precautionary Statements Prevention P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor if you feel unwell P362 + P364 - Take off contaminated clothing and wash it before reuse Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Physical and Chemical Hazards None identified. Health Hazards Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. This product does not contain any known or suspected endocrine disruptors. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No Weight % Samarium fluoride (SmF3) 13765-24-7 99.9 SECTION 4. FIRST AID MEASURES Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Inhalation Remove from exposure, lie down. Remove to fresh air. Get medical attention. Ingestion Clean mouth with water. Get medical attention. Most important symptoms and effects No information available. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Notes to Physician Treat symptomatically. ______________________________________________________________________________________________ Page 2 ``` ## ページ 3 ```text ALFAA13660 SAFETY DATA SHEET Revision Date 27-Jul-2026Page 3 / 8 Samarium (III) fluoride ______________________________________________________________________________________________ SECTION 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Extinguishing media which must not be used for safety reasons No information available. Specific Hazards Arising from the Chemical Non-combustible. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Ensure adequate ventilation. Environmental Precautions See Section 12 for additional Ecological Information. Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Refer to protective measures listed in Sections 8 and 13. SECTION 7. HANDLING AND STORAGE Handling Avoid contact with skin and eyes. Do not breathe dust. Handle product only in closed system or provide appropriate exhaust ventilation. Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Store contents under argon. Specific Use(s) Use in laboratories SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters Component China ACGIH TLV OSHA PEL NIOSH Samarium fluoride (SmF3) - TWA: 2.5 mg/m3 (Vacated) TWA: 2.5 mg/m3 IDLH: 250 mg/m3 Component Hong Kong Thailand European Union The United Kingdom Samarium fluoride (SmF3) - TWA: 2.5 mg/m3 - Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of ______________________________________________________________________________________________ Page 3 ``` ## ページ 4 ```text ALFAA13660 SAFETY DATA SHEET Revision Date 27-Jul-2026Page 4 / 8 Samarium (III) fluoride ______________________________________________________________________________________________ exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust Exposure Controls Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source. Personal protective equipment Eye Protection Goggles (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination. Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Respiratory Protection No protective equipment is needed under normal use conditions. Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Small scale/Laboratory use Maintain adequate ventilation Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Environmental exposure controls No information available. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Solid Odor No information available Odor Threshold No data available pH No information available Melting Point/Range 1306 °C / 2382.8 °F Softening Point No data available Boiling Point/Range 2323 °C / 4213.4 °F Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available Vapor Pressure No information available Vapor Density Not applicable Solid ______________________________________________________________________________________________ Page 4 ``` ## ページ 5 ```text ALFAA13660 SAFETY DATA SHEET Revision Date 27-Jul-2026Page 5 / 8 Samarium (III) fluoride ______________________________________________________________________________________________ Specific Gravity / Density No data available Bulk Density No data available Water Solubility No information available Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available Molecular Formula F3Sm Molecular Weight 207.35 SECTION 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Hazardous Reactions No information available. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Incompatible products. Materials to avoid Strong acids. Strong reducing agents. Hazardous Decomposition Products Gaseous hydrogen fluoride (HF). SECTION 11. TOXICOLOGICAL INFORMATION Product Information No acute toxicity information is available for this product (a) acute toxicity; (b) skin corrosion/irritation; Category 2 (c) serious eye damage/irritation; Category 2 (d) respiratory or skin sensitization; Respiratory No data available Skin No data available (e) germ cell mutagenicity; No data available (f) carcinogenicity; No data available There are no known carcinogenic chemicals in this product (g) reproductive toxicity; No data available (h) STOT-single exposure; Category 3 Results / Target organs Respiratory system (i) STOT-repeated exposure; No data available ______________________________________________________________________________________________ Page 5 ``` ## ページ 6 ```text ALFAA13660 SAFETY DATA SHEET Revision Date 27-Jul-2026Page 6 / 8 Samarium (III) fluoride ______________________________________________________________________________________________ Target Organs No information available. (j) aspiration hazard; Not applicable Solid Symptoms / effects,both acute and No information available delayed SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity effects Contains no substances known to be hazardous to the environment or that are not degradable in waste water treatment plants. Persistence and Degradability No information available Degradability Not relevant for inorganic substances. Bioaccumulative Potential No information available Mobility in soil No information available Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance SECTION 13. DISPOSAL CONSIDERATIONS Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations. Contaminated Packaging Dispose of this container to hazardous or special waste collection point. Other Information Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains. SECTION 14. TRANSPORT INFORMATION Road and Rail Transport Not Regulated IMDG/IMO Not regulated IATA Not regulated Special Precautions for User No special precautions required SECTION 15. REGULATORY INFORMATION ______________________________________________________________________________________________ Page 6 ``` ## ページ 7 ```text ALFAA13660 SAFETY DATA SHEET Revision Date 27-Jul-2026Page 7 / 8 Samarium (III) fluoride ______________________________________________________________________________________________ International Inventories X = listed, China (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), Korea (KECL). Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Samarium fluoride - - - 237-367-3 X - - X X - KE-30871 (SmF3) National Regulations SECTION 16. OTHER INFORMATION Prepared By Health, Safety and Environmental Department Creation Date 19-Oct-2010 Revision Date 27-Jul-2026 Revision Summary Not applicable. Training Advice Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers. Legend CAS - Chemical Abstracts Service TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japanese Existing and New Chemical Substances IECSC - Chinese Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic Compound) Key literature references and sources for data https://echa.europa.eu/information-on-chemicals Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS ______________________________________________________________________________________________ Page 7 ``` ## ページ 8 ```text ALFAA13660 SAFETY DATA SHEET Revision Date 27-Jul-2026Page 8 / 8 Samarium (III) fluoride ______________________________________________________________________________________________ Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet ______________________________________________________________________________________________ Page 8 ```