# · Trade name: Terbium\(III\) perchlorate, 50% aqueous solution \(99\.9%\-Tb\) \(REO\) — Safety Data Sheet — Strem Chemicals, Inc\.

原本PDFから抽出したテキストです。表、画像、記号、OCR結果は原本と異なる場合があります。安全情報は原本PDFで確認してください。

- **文書名:** · Trade name: Terbium\(III\) perchlorate, 50% aqueous solution \(99\.9%\-Tb\) \(REO\) — Safety Data Sheet — Strem Chemicals, Inc\.
- **発行元:** Strem Chemicals, Inc\.
- **材料:** · Trade name: Terbium\(III\) perchlorate, 50% aqueous solution \(99\.9%\-Tb\) \(REO\)
- **CAS番号:** 
- **製品番号・グレード:** 93\-6512
- **文書種類:** SDS
- **原文の言語:** English
- **地域:** United States · OSHA
- **改訂日:** 07/21/2021
- **ページ数:** 8
- **原本ファイル名:** sd93\-6512\_US\.pdf
- **RESDSページ:** https://resds\.com/document/trade\-name\-terbium\-iii\-perchlorate\-50\-aqueous\-solution\-99\-9\-tb\-reo\-sds\-strem\-chemicals\-en\-f0aaa82b3f
- **原本PDF:** https://resds\.com/pdf/trade\-name\-terbium\-iii\-perchlorate\-50\-aqueous\-solution\-99\-9\-tb\-reo\-sds\-strem\-chemicals\-en\-f0aaa82b3f\.pdf
- **情報源URL:** 
- **説明:** 

## ページ 1

```text
Page 1/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
1 Identification
· Product name
· Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
· Item number: 93-6512
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Strem Chemicals, Inc.
7 Mulliken Way
NEWBURYPORT, MA 01950
USA
info@strem.com
· Information department: Technical Department
· Emergency telephone number:
EMERGENCY: CHEMTREC: + 1 (800) 424-9300
During normal opening times: +1 (978) 499-1600
2 Hazard(s) identification
· Classification of the substance or mixture
GHS03 Flame over circle
d ~ 
Ox. Liq. 2 H272 May intensify fire; oxidizer.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
d ~ 
GHS03
· Signal word Danger
· Hazard statements
H272 May intensify fire; oxidizer.
· Precautionary statements
P210  Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P221  Take any precaution to avoid mixing with combustibles.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P403+P233  Store in a well-ventilated place. Keep container tightly closed.
P501  Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
3   Health = 0
Fire = 3
0  0
Reactivity = 0
OX
The substance possesses oxidizing properties.
(Contd. on page 2)
US
44.1.1
```

## ページ 2

```text
Page 2/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
(Contd. of page 1)
· HMIS-ratings (scale 0 - 4)
HEALTH 0
Health = 0
FIRE  3 Fire = 3
REACTIVITY 0 Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components: not applicable
4 First-aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately rinse with water.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions: No special measures required.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
(Contd. on page 3)
US
44.1.1
```

## ページ 3

```text
Page 3/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
(Contd. of page 2)
· Protective Action Criteria for Chemicals
· PAC-1:
None of the ingredients is listed.
· PAC-2:
None of the ingredients is listed.
· PAC-3:
None of the ingredients is listed.
7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
· Breathing equipment: A NIOSH approved respirator in accordance with 29 CFR 1910.134.
· Protection of hands:
Protective gloves
_ S
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
(Contd. on page 4)
US
44.1.1
```

## ページ 4

```text
Page 4/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
(Contd. of page 3)
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Goggles recommended during refilling.
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:  Liquid
Color:  Colorless
· Odor:  Odorless
· Odor threshold:  Not determined.
· pH-value:  Not determined.
· Change in condition
Melting point/Melting range:  Undetermined.
Boiling point/Boiling range:  Undetermined.
· Flash point:  Not applicable.
· Flammability (solid, gaseous):  Not determined.
· Ignition temperature:
Decomposition temperature:  Not determined.
· Auto igniting:  Product is not selfigniting.
· Danger of explosion:  Product does not present an explosion hazard.
· Explosion limits:
Lower:  Not determined.
Upper:  Not determined.
· Vapor pressure at 20 °C (68 °F):  23 hPa (17 mm Hg)
· Density:  Not determined.
· Relative density  Not determined.
· Vapor density  Not determined.
· Evaporation rate  Not determined.
· Solubility in / Miscibility with
Water:  Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:  Not determined.
Kinematic:  Not determined.
· Solvent content:
Organic solvents:  0.0 %
Water:  50.0 %
VOC content:  0.0 g/l / 0.00 lb/gl
(Contd. on page 5)
US
44.1.1
```

## ページ 5

```text
Page 5/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
(Contd. of page 4)
· Other information  No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes: Not known to be hazardous to water.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
US
(Contd. on page 6)
44.1.1
```

## ページ 6

```text
Page 6/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
(Contd. of page 5)
13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· DOT, IMDG, IATA  UN3211
· UN proper shipping name
· DOT  Perchlorates, inorganic, aqueous solution, n.o.s.
· IMDG, IATA  PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
· Transport hazard class(es)
· DOT
d c ` j z t
· Class  5.1 Oxidizing substances
· Label  5.1
· IMDG, IATA
d c ` j z
· Class  5.1 Oxidizing substances
· Label  5.1
· Packing group
· DOT, IMDG, IATA  II
· Environmental hazards:
· Marine pollutant:  No
· Special precautions for user  Warning: Oxidizing substances
· EMS Number:  F-H,S-Q
· Segregation groups  Perchlorates
· Stowage Category  B
· Segregation Code  SG38 Stow "separated from" ammonium compounds.
SG49 Stow "separated from" cyanides
SG62 Stow "separated from" sulphur
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code  Not applicable.
(Contd. on page 7)
US
44.1.1
```

## ページ 7

```text
Page 7/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
(Contd. of page 6)
· Transport/Additional information:
· DOT
· Quantity limitations  On passenger aircraft/rail: 1L
On cargo aircraft only: 5L
· IMDG
· Limited quantities (LQ)  1L
· Excepted quantities (EQ)  Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· UN "Model Regulation":  UN 3211 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION,
N.O.S., 5.1, II
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 8)
US
44.1.1
```

## ページ 8

```text
Page 8/8
Safety Data Sheet
according to OSHA HCS
Printing date 07/21/2021  Reviewed on 07/15/2021
Trade name: Terbium(III) perchlorate, 50% aqueous solution (99.9%-Tb) (REO)
(Contd. of page 7)
· Hazard pictograms
d ~ 
GHS03
· Signal word Danger
· Hazard statements
H272 May intensify fire; oxidizer.
· Precautionary statements
P210  Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P221  Take any precaution to avoid mixing with combustibles.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P403+P233  Store in a well-ventilated place. Keep container tightly closed.
P501  Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing SDS: Technical Department.
· Contact: Technical Director
· Date of preparation / last revision 07/21/2021 / -
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Ox. Liq. 2: Oxidizing liquids – Category 2
US
44.1.1
```