# Tris\(2,2,6,6\-tetramethyl\-3,5\-heptanedionato\)lutetium\(III\), 99% \(99\.9\+%\-Lu\) \(REO\) \[Lu\(TMHD\) SDS – Strem Chemicals, Inc\. Text extracted from the original PDF. Tables, images, symbols and OCR may differ. Check the original PDF for safety information. - **Document title:** Tris\(2,2,6,6\-tetramethyl\-3,5\-heptanedionato\)lutetium\(III\), 99% \(99\.9\+%\-Lu\) \(REO\) \[Lu\(TMHD\) SDS – Strem Chemicals, Inc\. - **Publisher:** Strem Chemicals, Inc\. - **Material:** Tris\(2,2,6,6\-tetramethyl\-3,5\-heptanedionato\)lutetium\(III\), 99% \(99\.9\+%\-Lu\) \(REO\) \[Lu\(TMHD\) - **CAS number:** 15492\-45\-2 - **Product code / grade:** 71\-1080 - **Document type:** SDS - **Original language:** English - **Region:** United Kingdom - **Revision date:** 30\.07\.2016 - **Page count:** 6 - **Original filename:** sd71\-1080\_GB\.pdf - **RESDS page:** https://resds\.com/document/tris\-2\-2\-6\-6\-tetramethyl\-3\-5\-heptanedionato\-lutetium\-iii\-99\-99\-9\-lu\-reo\-lu\-tmhd\-sds\-strem\-chemicals\-en\-4e791063a5 - **Original PDF:** https://resds\.com/pdf/tris\-2\-2\-6\-6\-tetramethyl\-3\-5\-heptanedionato\-lutetium\-iii\-99\-99\-9\-lu\-reo\-lu\-tmhd\-sds\-strem\-chemicals\-en\-4e791063a5\.pdf - **Source URL:** https://sds\.strem\.com/sd71\-1080\_GB\.pdf - **Description:** Collected by RESDS\. Original publisher PDF retained\. Original manufacturer safety data sheet for Tris\(2,2,6,6\-tetramethyl\-3,5\-heptanedionato\)lutetium\(III\), 99% \(99\.9\+%\-Lu\) \(REO\) \[Lu\(TMHD\)\. Product number: 71\-1080\. Original revision: 30\.07\.2016\. Published under the file\-level authorization confirmed by the user for the frozen 1,125\-file manifest\. ## Page 1 ```text Page 1/6 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.07.2016 Revision: 30.07.2016 SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III), 99% (99.9+%-Lu) (REO) [Lu(TMHD) 3] · Item number: 71-1080 · CAS Number: 15492-45-2 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: Strem Chemicals, Inc. 7 Mulliken Way NEWBURYPORT, MA 01950 USA info@strem.com · Further information obtainable from: Technical Department · 1.4 Emergency telephone number: EMERGENCY: CHEMTREC: + 1 (800) 424-9300 During normal opening times: +1 (978) 499-1600 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS07 d~ Skin Irrit. 2 H315 Causes skin irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. · Hazard pictograms d~ GHS07 · Signal word Warning · Hazard statements H315 Causes skin irritation. · Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. (Contd. on page 2) GB 42.0 ``` ## Page 2 ```text Page 2/6 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.07.2016 Revision: 30.07.2016 Trade name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III), 99% (99.9+%-Lu) (REO) [Lu(TMHD)3] (Contd. of page 1) P312 Call a POISON CENTER or doctor/physician if you feel unwell. P403+P233 Store in a well-ventilated place. Keep container tightly closed. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.1 Chemical characterisation: Substances · CAS No. Description 15492-45-2 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III), 99% (99.9+%-Lu) (REO) [Lu(TMHD)3] SECTION 4: First aid measures · 4.1 Description of first aid measures · After inhalation: In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: If symptoms persist consult doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: No special measures required. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Not required. · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. · Information about fire - and explosion protection: No special measures required. (Contd. on page 3) GB 42.0 ``` ## Page 3 ```text Page 3/6 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.07.2016 Revision: 30.07.2016 Trade name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III), 99% (99.9+%-Lu) (REO) [Lu(TMHD)3] (Contd. of page 2) · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: Not required. · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. · Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. · Protection of hands: Protective gloves _S The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Crystalline Colour: Whitish · Odour: Odourless · Odour threshold: Not determined. · pH-value: Not applicable. · Change in condition Melting point/Melting range: Undetermined. (Contd. on page 4) GB 42.0 ``` ## Page 4 ```text Page 4/6 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.07.2016 Revision: 30.07.2016 Trade name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III), 99% (99.9+%-Lu) (REO) [Lu(TMHD)3] (Contd. of page 3) Boiling point/Boiling range: Undetermined. · Flash point: Not applicable. · Flammability (solid, gaseous): Not determined. · Ignition temperature: Decomposition temperature: Not determined. · Self-igniting: Not determined. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapour pressure: Not applicable. · Density: Not determined. · Relative density Not determined. · Vapour density Not applicable. · Evaporation rate Not applicable. · Solubility in / Miscibility with water: Insoluble. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. · Solvent content: Organic solvents: 0.0 % VOC (EC) 0.00 % Solids content: 100.0 % · 9.2 Other information No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known. · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known. SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. (Contd. on page 5) GB 42.0 ``` ## Page 5 ```text Page 5/6 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.07.2016 Revision: 30.07.2016 Trade name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III), 99% (99.9+%-Lu) (REO) [Lu(TMHD)3] (Contd. of page 4) · Serious eye damage/irritation Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN-Number · ADR, ADN, IMDG, IATA not regulated · 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA not regulated · 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class not regulated · 14.4 Packing group · ADR, IMDG, IATA not regulated · 14.5 Environmental hazards: · Marine pollutant: No (Contd. on page 6) GB 42.0 ``` ## Page 6 ```text Page 6/6 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 30.07.2016 Revision: 30.07.2016 Trade name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lutetium(III), 99% (99.9+%-Lu) (REO) [Lu(TMHD)3] (Contd. of page 5) · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation": not regulated SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I Substance is not listed. · National regulations: · Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Technical Department. · Contact: Technical Director · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 GB 42.0 ```