Cadmium-106 SDS

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 1/11

Section 1: Identification of the Substance/混合物 and of the Company/Undertaking

Product Identifier: Identification as on the label/商品名： Cadmium Oxide, Enriched Cadmium Oxide 分子量: 128.41 化学式: CdO 別名: Cadmium (II) oxide, cadmium monoxide. 詳細 of the supplier of the 安全データシート: Neonest AB Storgatan 70C, Solna SE-17152 Sweden Contact details: +46-76-219-9731 24-hour Emergency Contact: Swedish Poisons Centre 電話番号: 112 - Ask for Poisons Information, 112 – begär Giftinformation . Other International Contacts: CHEMTREC 24-hour: +1-703-741-5500 (US + Worldwide) NHS: 111 (UK) Charite: +49 30 450 531 000 (Netherlands) INTCF: +34 917689800 (Spain) CapTv: +33 1 40 05 48 48 (フランス)

Section 2: Hazards Identification

Classification of the substances or mixture: The mixture is classified according to: Regulation EC 1272/2008 [EU-GHS/CLP] Hazard classes/Hazard categories: Hazard statement: Acute Toxicity, Inhalation (Category 2) H330 Mutagenicity (Category 2) H341 Carcinogenicity (Category 1B) H350 Reproductive Toxicity (Category 2) H361 STOT RE (Category 1) H372 Aquatic Acute (Category 1) H400 Aquatic Chronic (Category 1) H410 Label elements: Hazard pictograms:

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 2/11 Signal Words: Danger. Hazard Statements: H330 Fatal if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Precautionary Statements: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local and national regulations. Other hazards: None known.

Section 3: 組成/Information on Ingredients

Substance/混合物: Substance. Ingredients: Substance name (IUPAC/EC) CAS - No. Molecular weight Concentration % by weight Classification EC1272/2008 EC - No. Cadmium oxide 1306-19-0 128.41 >99% Acute Tox. 2 H330 Muta. 1B H341 Carc. 1B H350 H350 Repr. 1B H360 H361 STOT RE 1 H372 Aquatic Acute 1 H400 215-146-2

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 3/11 Aquatic Chronic 1H410 For explanation of abbreviations see Section 16.

Section 4: First - Aid Measures

説明 of first aid measures: In case of inhalation: Move to fresh air. If not breathing, give artificial respiration. Seek immediate medical attention. In case of skin contact: If on skin, rinse well with running water for a minimum of 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate the eyes. Seek immediate medical attention if any adverse effects occur. In case of eye contact: Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. Seek immediate medical attention. In case of ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Most important symptoms and effects, both acute and delayed: Inhalation: Cadmium absorption is most efficient via respiratory tract. Inhalation of dust may produce irritation, headache, metallic taste and/or cough. Severe exposures may produce shortness of breath, chest pain and flulike symptoms: weakness, fever, headache, chills, sweating, nausea and muscular pain. Can cause pulmonary edema, liver and kidney damage, death. Symptoms from inhalation may be delayed for as long as 24 hours. Eyes: May cause irritation, redness, and pain. Skin contact: May cause irritation, redness, and pain. Ingestion: Toxic. Ingested cadmium salts may cause severe and sometimes fatal poisonings. Symptoms can include severe nausea, vomiting, diarrhoea, abdominal pain, choking, dizziness and salivation. Kidney and liver dysfunction may occur. Although as little as 10-20 mg of soluble cadmium salts have produced severe toxic symptoms when ingested, death probably requires several hundred mg by oral route. Indication of any immediate medical attention and special treatment needed: Treat symptomatically. Show this safety data sheet to a physician or emergency room.

Section 5: Fire - Fighting Measures

Extinguisher media: Suitable extinguisher media: Use any means suitable for extinguishing surrounding fire. Unsuitable extinguishing media: None known. Special hazards arising from the mixture: May emit toxic cadmium fumes during a fire. Advice for fire-fighters: Wear self-contained breathing apparatus and protective clothing for firefighting. Further information: Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Section 6: Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Personal precautions: Wear appropriate personal protective equipment as specified in Section 8. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 4/11 end of the day. Avoid cross-contamination of street clothes. Wash hands before eating. Do not eat, drink, or smoke in the workplace. Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. Methods for containment and cleaning up: Methods for cleaning up: Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Isolate personnel from spills at a 25-meter distance, or from fire at 800 meters. Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. Do not flush to the sewer. Bioaccumulation may occur in plants and seafood. Reference to other sections: Treat recovered material as described in the section "Disposal considerations".

Section 7: Handling and Storage

Precautions for safe handling: Advice on safe handling: Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Hygiene measures: Do not eat, drink or smoke when using this product. Conditions for safe storage, including incompatibilities: Requirements for storage areas and containers: Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Wear special protective equipment (Section 8) for maintenance break-in or where exposures may exceed established exposure levels.

Section 8: Exposure Controls/ Personal Protection

Control parameters: Occupational exposure limits: OSHA Threshold Limit Value (PEL) 5 ug/m 3 of Cadmium (TWA), 2.5 ug/m 3 (Action Level) ACGIH Threshold Limit Value (TLV) 0.01 mg/m 3 total dust, 0.002 mg/m 3 respirable fraction for cadmium and compounds, as Cd; listed as A2, suspected human carcinogen. Exposure controls: Appropriate engineering controls: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion into the general work area. Individual protection measures, such as personal protective equipment: Eye/face protection: Use safety glasses. If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles. Hand protection: Use chemical resistant gloves. Examples of preferred glove barrier materials include: Butyl rubber, Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate, polyvinyl alcohol, Polyvinyl chloride. Body protection: Wear protective clothing as appropriate.

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 5/11 Respiratory protection: If the exposure limit is exceeded and engineering controls are not feasible, a half-face high- efficiency particulate respirator (NIOSH type N100 filter) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece high efficiency particulate respirator (NIOSH type N100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive- pressure, air-supplied respirator.

Section 9: Physical and Chemical Properties

Information on basic physical and chemical properties Appearance (form): Solid (crystals or powder). Colour: Brown. Density: 8.15 g/ cm 3 Odour: Odourless. Odour threshold: No data available. Molecular Weight: 128.41 pH (concentration): No data available. Melting point/range (° C): 950 °C crystals, < 1426 ° C powder. Boiling point/range (° C): 1559 ° C Freezing point (°C): No data available. Flash point (° C): No data available. Evaporation rate: No data available. Flammability (solid, gas): No data available. Ignition temperature (° C): No data available. Upper/lower flammability/explosive limits: No data available. Vapour pressure (20 ° C): 1.3 mbar @ 1000 ºC Vapour density: No data available. Relative densi ty (25 ° C): No data available. Water solubility (g/L ) at 20 ° C: Insoluble. n-Octanol/Water partition coefficient : No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity, dynamic (mPa s): No data available. Explosive properties: The substance or mixture is not classified as explosive. Oxidising properties: The substance or mixture is not classified as oxidizing.

Section 10: Stability and Reactivity

Reactivity: No dangerous reaction known under conditions of normal use. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use. Conditions to avoid: Fire and other elevated temperature conditions . Incompatible materials: Explodes when heated with magnesium. Cadmium dust presents a fire/explosion hazard if reacted with oxidizing agents, metals, hydrogen azide, zinc, selenium or tellurium. Hazardous decomposition products: Toxic cadmium oxide fumes may be formed at high temperatures (> 900 ° C).

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 6/11

Section 11: Toxicological Information

Information on toxicological effects: Acute Toxicity: LD 50 Oral, Rat - 72 mg/kg; Inhalation - Mouse LC 50 : 250 mg/m 3 /2-hour - Investigated as a tumorigen, mutagen, reproductive effector. Classification according to GHS (1272/2008/EG, CLP) Skin corrosion/irritation: Not classified based on available information. Serious eye damage/eye irritation: Not classified based on available information. Respiratory or skin sensitisation: Not classified based on available information. Germ cell mutagenicity: Suspected of causing genetic defects. Carcinogenicity: IARC: Yes NTP: Yes OSHA: Yes Reproductive toxicity: Suspected of damaging fertility or the unborn child. Specific target organ toxicity – single exposure (STOT): Not classified based on available information. Specific target organ toxicity (STOT) – repeated exposure: Causes damage to organs through prolonged or repeated exposure. Aspiration toxicity: Not classified based on available information.

Section 12: Ecological Information

Toxicity: Toxicity to fish: LC 50 Pimephales promelas, 7.029 mg/l, 96 hours. Persistence and degradability: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. 検索結果 of PBT&amp; vPvB assessment: Not relevant. Other adverse effects: Very toxic to aquatic life.

Section 13: Disposal Considerations

Waste treatment methods: Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of closed container and unused contents in accordance with local and national regulations.

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 7/11 Sec tion 14: Transport Information DOT: Proper Shipping Name: CADMIUM COMPOUND, N.O.S. (CADMIUM OXIDE). Hazard Class : 6.1 UN Number: 2570 Packing Group: III Hazard Labels: International (Water, IMO): Proper Shipping Name: CADMIUM COMPOUND, N.O.S. (CADMIUM OXIDE). Hazard Class : 6.1 UN Number: 2570 Packing Group: III International (Air, ICAO): Proper Shipping Name: CADMIUM COMPOUND, N.O.S. (CADMIUM OXIDE). Hazard Class : 6.1 UN Number: 2570 Packing Group: III IATA: Proper Shipping Name: CADMIUM COMPOUND, N.O.S. (CADMIUM OXIDE). Hazard Class : 6.1 UN Number: 2570 Packing Group: III

Section 15: Regulatory Information

EU regulations: Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed. Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed.

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 8/11 Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed. Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Not listed. Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed. Authorisations: Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed. Restrictions on use: Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Not listed. Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding. Not regulated. Other EU regulations: Directive 2012/18/EU on major accident hazards involving dangerous substances Not listed. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Always applicable. Directive 94/33/EC on the protection of young people at work Not listed. Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. This 安全データシート complies with the requirements of Regulation (EC) No 1907/2006, as amended. OSHA Hazards: Carcinogen, Target Organ Effect, Highly toxic by inhalation, Toxic by ingestion, Teratogen, Mutagen. SARA 302 Components: The following components are subject to reporting levels established by SARA Title III, Section 302: Cadmium oxide non-pyrophoric / CAS No. 1306-19-0 / 改訂版 Date 1993-04-24 SARA 313 Components: The following components are subject to reporting levels established by SARA Title III, Section 313: Cadmium oxide non-pyrophoric / CAS No. 1306-19-0 / 改訂版 Date 1993-04-24. SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard. Massachusetts Right To Know Components: Cadmium oxide non-pyrophoric / CAS No. 1306-19-0 / 改訂版 Date 1993-04-24. Pennsylvania Right To Know Components: Cadmium oxide non-pyrophoric / CAS No. 1306-19-0 / 改訂版 Date

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 9/11 1993-04-24. New Jersey Right To Know Components: Cadmium oxide non-pyrophoric / CAS No. 1306-19-0 / 改訂版 Date 1993-04-24. California Prop. 65 Components: WARNING! This product contains a chemical known to the State of California to cause cancer: Cadmium oxide non-pyrophoric / CAS No. 1306-19-0 / 改訂版 Date 1987-10-01. California Prop. 65 Components: WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm: Cadmium oxide non-pyrophoric / CAS-No. 1306-19-0 / 改訂版 Date 1987-10-01. National regulations: Follow national regulation for work with chemical agents. Chemical safety assessment: No Chemical Safety Assessment has been carried out.

Section 16: Other Information

List of abbreviations: ACGIH American Conference of Governmental Industrial Hygienists ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road ALARA As Low As Is Reasonably Achievable AMU Atomic Mass Unit ANSI American National Standards Institute BLS Basic Life Support CAM Continuous Air Monitor CAS Chemical Abstracts Service (division of the American Chemical Society) CEN European Committee for Standardization CERCLA Comprehensive Environmental Response Compensation and Liability Act CLP Classification, Labelling and Packaging (European Union) CPR Controlled Products Regulations (Canada) CWA Clean Water Act (USA) DAC Derived Air Concentration (USA) DOE 米国 Department of Energy (USA) DOT 米国 Department of Transportation (USA) DSL Domestic Substances List (Canada) EC50 Half Maximal Effective Concentration EINECS European Inventory of Existing Commercial Chemical Substances EHS Environmentally Hazardous Substance ELINCS European List of Notified Chemical Substances EMS Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency (USA) EPCRA Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 GHS Globally Harmonized System HMIS Hazardous 材料 Identification System (USA) IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Containers ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life or Health IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 10/11 LD50 Lethal dose, 50 percent LDLO Lethal Dose Low LOEC Lowest-Observed-Effective Concentration MARPOL International Convention for the Prevention of Pollution from Ships MSHA Mine Safety and Health Administration (USA) NCRP National Council on Radiation Protection &amp; Measurements (USA) NDSL Non-Domestic Substances List (Canada) NFPA National Fire Protection Association (USA) NIOSH National Institute for Occupational Safety and Health (USA) NOEC No Observed Effect Concentration N.O.S. Not Otherwise Specified NRC Nuclear Regulatory Commission (USA) NTP National Toxicology Program (USA) OSHA Occupational Safety and Health Administration (USA) PBT Persistent Bioaccumulative and Toxic Chemical PEL Permissible Exposure Limit PIH Poisonous by Inhalation Hazard RCRA Resource Conservation and Recovery Act (USA) RCT Radiation Control Technician REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (Europe) RID Regulations Concerning the International Transport of Dangerous Goods by Rail RTECS Registry of Toxic Effects of Chemical Substances SARA Superfund Amendments and Reauthorization Act (USA) TDG Transportation of Dangerous Goods (Canada) TIH Toxic by Inhalation Hazard TLV Threshold Limit Value TPQ Threshold Planning Quantity TSCA Toxic Substances Control Act TWA Time Weighted Average UN United Nations (Number) VOC Volatile Organic 化合物 vPvB Very Persistent Very Bioaccumulative Chemical WGK Wassergefährdungsklassen (ドイツ: Water H azard Classes) WHMIS Workplace Hazardous 材料 Information System References: 情報なし. 全文 of any H-statements not written out in full under Sections 2 to 15: H330 Fatal if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. 改訂版 information: None. Training information:

安全データシート for Cadmium Oxide, Enriched Cadmium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 9-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Cadmium Oxide, Enriched Cadmium Oxide https://www.buyisotope.com ページ 11/11 Follow training instructions when handling this material. Further Information: The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.