Hafnium-180 SDS

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 1/9

Section 1: Identification of the Substance/混合物 and of the Company/Undertaking

Product Identifier: Identification as on the label/商品名： Hafnium Oxide, Enriched Hafnium. 分子量: 210.49 化学式: HfO 2 別名: None. 詳細 of the supplier of the 安全データシート: Neonest AB Storgatan 70C, Solna SE-17152 Sweden Contact details: +46-76-219-9731 24-hour Emergency Contact: Swedish Poisons Centre 電話番号: 112 - Ask for Poisons Information, 112 – begär Giftinformation . Other International Contacts: CHEMTREC 24-hour: +1-703-741-5500 (US + Worldwide) NHS: 111 (UK) Charite: +49 30 450 531 000 (Netherlands) INTCF: +34 917689800 (Spain) CapTv: +33 1 40 05 48 48 (フランス)

Section 2: Hazards Identification

Classification of the substances or mixture: The mixture is classified according to: Regulation EC 1272/2008 [EU-GHS/CLP] Hazard classes/Hazard categories: Hazard statement: Not classified as hazardous. None required. Label elements: Hazard pictograms: Not required. Signal Words: Not required. Hazard Statements: Not required. Precautionary Statements: None. Other hazards: None known.

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 2/9

Section 3: 組成/Information on Ingredients

Substance/混合物: Substance. Ingredients: Substance name (IUPAC/EC) CAS - No. Molecular weight Concentration % by weight Classification EC1272/2008 EC - No. Hafnium dioxide 12055-23-1 210.49 >99% Not Classified. 235-013-2 For explanation of abbreviations see Section 16.

Section 4: First - Aid Measures

説明 of first aid measures: In case of inhalation: Remove victim to fresh air, keep warm and quiet, give oxygen if breathing is difficult, and seek medical attention. In case of skin contact: Remove contaminated clothing, brush material off skin, wash affected area with mild soap and water. Seek medical attention if symptoms persist. In case of eye contact: Flush with warm water, lifting upper and lower eyelids. In case of ingestion: Give 1-2 glasses of water and induce vomiting, seek medical attention. Never give anything by mouth to unconscious person. Rinse mouth with water. Most important symptoms and effects, both acute and delayed: Inhalation: May be harmful if inhaled. May cause respiratory tract irritation. Eyes: May cause eye irritation. Skin contact: May be harmful if absorbed through skin. May cause skin irritation. Ingestion: May be harmful if swallowed. Indication of any immediate medical attention and special treatment needed: Treat symptomatically. Show this safety data sheet to a physician or emergency room.

Section 5: Fire - Fighting Measures

Extinguisher media: Suitable extinguisher media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: None known. Special hazards arising from the mixture: Hafnium oxide. Advice for fire-fighters: Use NIOSH-approved self-contained breathing apparatus and full protective equipment. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution. Further information: Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 3/9

Section 6: Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Personal precautions: Notify safety personnel of leaks or spills. Remove spills by vacuuming or wet sweeping in order to keep airborne dust at a minimum. Avoid dust formation. Avoid breathing vapours, mist or gas. Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. Methods for containment and cleaning up: Methods for cleaning up: Sweep up spilled material and store in a suitable container for disposal. Reference to other sections: Treat recovered material as described in the section "Disposal considerations".

Section 7: Handling and Storage

Precautions for safe handling: Advice on safe handling: Avoid breathing dust. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. Hygiene measures: Do not eat, drink or smoke when using this product. Conditions for safe storage, including incompatibilities: Requirements for storage areas and containers: Store in closed container in a cool, dry, well-ventilated, low-fire-risk area. Protect container from physical damage.

Section 8: Exposure Controls/ Personal Protection

Control parameters: Occupational exposure limits: Contains no substances with occupational exposure limit values Exposure controls: Appropriate engineering controls: A system of local or mechanical exhaust is recommended to keep dust levels low. Individual protection measures, such as personal protective equipment: Eye/face protection: Use safety glasses. If there is a potential for exposure to particles which could cause eye discomfort, wear ANSI-approved chemical goggles. Maintain eye wash fountain and quick-drench facilities in work area. Hand protection: Use chemical resistant gloves. Examples of preferred glove barrier materials include: Butyl rubber, Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate, polyvinyl alcohol, Polyvinyl chloride. Body protection: Not necessary under normal conditions of use. Respiratory protection: Use a NIOSH-approved dust respirator.

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 4/9

Section 9: Physical and Chemical Properties

Information on basic physical and chemical properties Appearance (form): Solid. Colour: White. Odour: No data available. Odour threshold: No data available. Molecular Weight: 210.49 pH (concentration): No data available. Melting point/range (° C): 2758° +/ - 25 °C Boiling point/range (° C): 5400 °C Freezing point (°C): No data available. Flash point (° C): No data available. Evaporation rate: No data available. Flammability (solid, gas): No data available. Ignition temperature (° C): No data available. Upper/lower flammability/explosive limits: No data available. Vapour pressure (20 ° C): No data available Vapour density: No data available. Relative densi ty (25 ° C): 9.687 Water solubility (g/L ) at 20 ° C: Insoluble. n-Octanol/Water partition coefficient : No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity, dynamic (mPa s): No data available. Explosive properties: The substance or mixture is not classified as explosive. Oxidising properties: The substance or mixture is not classified as oxidizing.

Section 10: Stability and Reactivity

Reactivity: No dangerous reaction known under conditions of normal use. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use. Conditions to avoid: None known . Incompatible materials: None known. Hazardous decomposition products: None known.

Section 11: Toxicological Information

Information on toxicological effects: Not classified based on available information. Classification according to GHS (1272/2008/EG, CLP) Skin corrosion/irritation: Not classified based on available information. Serious eye damage/eye irritation: Not classified based on available information.

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 5/9 Respiratory or skin sensitisation: Not classified based on available information. Germ cell mutagenicity: Not classified based on available information. Carcinogenicity: NTP: No IARC: No OSHA: No Reproductive toxicity: Not classified based on available information. Specific target organ toxicity – single exposure (STOT): Not classified based on available information. Specific target organ toxicity (STOT) – repeated exposure: Not classified based on available information. Aspiration toxicity: Not classified based on available information.

Section 12: Ecological Information

Toxicity: No data available. Persistence and degradability: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. 検索結果 of PBT& vPvB assessment: Not relevant. Other adverse effects: No data available.

Section 13: Disposal Considerations

Waste treatment methods: Offer surplus and non-recyclable solutions to a licensed disposal company.

Section 14: Transport Information

UN number: Not regulated as a dangerous good. UN proper shipping name: Not regulated as a dangerous good. Transport hazard class(es): Not regulated as a dangerous good. Packing group: Not regulated as a dangerous good. Environmental hazards: Not regulated as a dangerous good. Special precautions for user: Not dangerous goods in the meaning of ADR/RID, ADN, IMDG-Code, ICAO/IATA-DGR. Transport in bulk according to Annex II of Marpol and the IBC Code: Not applicable.

Section 15: Regulatory Information

EU regulations: Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed. Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I Not listed.

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 6/9 Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed. Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Not listed. Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed. Authorisations: Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed. Restrictions on use: Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Not listed. Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding. Not regulated. Other EU regulations: Directive 2012/18/EU on major accident hazards involving dangerous substances Not listed. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Always applicable. Directive 94/33/EC on the protection of young people at work Not listed. Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. This 安全データシート complies with the requirements of Regulation (EC) No 1907/2006, as amended. US Federal TSCA: CAS# 12055-23-1 is listed on the TSCA inventory. Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 7/9 Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.

Section 12b: None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and Corresponding RQs: None of the chemicals in this material have an RQ. SARA Section 302 Extremely Hazardous Substances: None of the chemicals in this product have a TPQ.

Section 313: No chemicals are reportable under Section 313.

Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. US States: CAS# 12055-23-1 is not present on state lists from CA, PA, MN, MA, FL or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives: Hazard Symbols: 情報なし Risk Phrases: 情報なし Safety Phrases: S 24/25 Avoid contact with skin and eyes S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 28A After contact with skin, wash immediately with plenty of water. WGK (Water Danger/Protection): CAS# 12055-23-1: No information available. Canada - DSL/NDSL: CAS# 12055-23-1 is listed on Canada's DSL List. Canada – WHMIS: 情報なし. National regulations: Follow national regulation for work with chemical agents. Chemical safety assessment: No Chemical Safety Assessment has been carried out.

Section 16: Other Information

List of abbreviations: ACGIH American Conference of Governmental Industrial Hygienists ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road ALARA As Low As Is Reasonably Achievable AMU Atomic Mass Unit ANSI American National Standards Institute BLS Basic Life Support CAM Continuous Air Monitor CAS Chemical Abstracts Service (division of the American Chemical Society) CEN European Committee for Standardization CERCLA Comprehensive Environmental Response Compensation and Liability Act CLP Classification, Labelling and Packaging (European Union) CPR Controlled Products Regulations (Canada) CWA Clean Water Act (USA) DAC Derived Air Concentration (USA) DOE 米国 Department of Energy (USA)

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 8/9 DOT 米国 Department of Transportation (USA) DSL Domestic Substances List (Canada) EC50 Half Maximal Effective Concentration EINECS European Inventory of Existing Commercial Chemical Substances EHS Environmentally Hazardous Substance ELINCS European List of Notified Chemical Substances EMS Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency (USA) EPCRA Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 GHS Globally Harmonized System HMIS Hazardous 材料 Identification System (USA) IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Containers ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life or Health IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent LDLO Lethal Dose Low LOEC Lowest-Observed-Effective Concentration MARPOL International Convention for the Prevention of Pollution from Ships MSHA Mine Safety and Health Administration (USA) NCRP National Council on Radiation Protection & Measurements (USA) NDSL Non-Domestic Substances List (Canada) NFPA National Fire Protection Association (USA) NIOSH National Institute for Occupational Safety and Health (USA) NOEC No Observed Effect Concentration N.O.S. Not Otherwise Specified NRC Nuclear Regulatory Commission (USA) NTP National Toxicology Program (USA) OSHA Occupational Safety and Health Administration (USA) PBT Persistent Bioaccumulative and Toxic Chemical PEL Permissible Exposure Limit PIH Poisonous by Inhalation Hazard RCRA Resource Conservation and Recovery Act (USA) RCT Radiation Control Technician REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (Europe) RID Regulations Concerning the International Transport of Dangerous Goods by Rail RTECS Registry of Toxic Effects of Chemical Substances SARA Superfund Amendments and Reauthorization Act (USA) TDG Transportation of Dangerous Goods (Canada) TIH Toxic by Inhalation Hazard TLV Threshold Limit Value TPQ Threshold Planning Quantity TSCA Toxic Substances Control Act TWA Time Weighted Average

安全データシート for Hafnium Oxide, Enriched Hafnium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 14-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Hafnium Oxide, Enriched Hafnium https://www.buyisotope.com ページ 9/9 UN United Nations (Number) VOC Volatile Organic 化合物 vPvB Very Persistent Very Bioaccumulative Chemical WGK Wassergefährdungsklassen (ドイツ: Water Hazard Classes) WHMIS Workplace Hazardous 材料 Information System References: 情報なし. 全文 of any H-statements not written out in full under Sections 2 to 15: None. 改訂版 information: None. Training information: Follow training instructions when handling this material. Further Information: The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.