ランタン(III) oxide ALFAA11272 SDS

ページ 1 / 7 SAFETY DATA SHEET Creation Date 21-Dec-2012 改訂版 Date 25-Jul-2026 Version 6

ALFAA11272

Lanthanum(III) oxide

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 氧化镧(III),氧化镧(III),氧化镧(III),氧化镧(III),REactonREactonREactonREacton Product 説明: Lanthanum(III) oxide

Cat No. : 11272 別名 Lanthanum Sesquioxide; Lanthanum Trioxide. CAS No 1312-81-8 Molecular Formula La2 O3

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Powder Solid White Odorless

Emergency 概要 Air sensitive. Hygroscopic.

Classification of the substance or mixture Based on available data, the classification criteria are not met

Label 元素s

None required

Physical and Chemical Hazards Hygroscopic. Health Hazards The product contains no substances which at their given concentration are considered to be hazardous to health. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Is not likely mobile in the environment due its low water solubility. Spillage unlikely to penetrate soil.

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ALFAA11272 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 2 / 7 Lanthanum(III) oxide ______________________________________________________________________________________________

Other Hazards

This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Lanthanum oxide (La2O3) 1312-81-8 <=100

SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Most important symptoms and effects None reasonably foreseeable.

Self-Protection of the First Aider No special precautions required.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust formation.

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ALFAA11272 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 3 / 7 Lanthanum(III) oxide ______________________________________________________________________________________________ Environmental Precautions Should not be released into the environment.

Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid ingestion and inhalation. Avoid dust formation. Do not get in eyes, on skin, or on clothing.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store under an inert atmosphere. Air sensitive.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures None under normal use conditions. .

Personal protective equipment

Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection No protective equipment is needed under normal use conditions.

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ALFAA11272 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 4 / 7 Lanthanum(III) oxide ______________________________________________________________________________________________ Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced おすすめ 絞り込み type: Particle filter

Small scale/Laboratory use Maintain adequate ventilation

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance White Physical State Powder Solid

Odor Odorless Odor Threshold No data available pH Not applicable Melting Point/Range 2315 °C / 4199 °F Softening Point No data available Boiling Point/Range 4200 °C / 7592 °F Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No data available Vapor Density Not applicable Solid Specific Gravity / Density No data available Bulk Density No data available Water Solubility Insoluble Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

Molecular Formula La2 O3 Molecular Weight 325.82

SECTION 10. STABILITY AND REACTIVITY

Stability Hygroscopic. Air sensitive.

Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur.

Conditions to Avoid Incompatible products. Excess heat. Avoid dust formation. Exposure to air. Exposure to moist air or water.

材料 to avoid Strong oxidizing agents. Strong acids. Carbon dioxide (CO2).

Hazardous Decomposition Products None under normal use conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

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ALFAA11272 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 5 / 7 Lanthanum(III) oxide ______________________________________________________________________________________________

Product Information

(a) acute toxicity;

(b) skin corrosion/irritation; Based on available data, the classification criteria are not met

(c) serious eye damage/irritation; Based on available data, the classification criteria are not met

(d) respiratory or skin sensitization; Respiratory Based on available data, the classification criteria are not met Skin Based on available data, the classification criteria are not met

(e) germ cell mutagenicity; Based on available data, the classification criteria are not met

(f) carcinogenicity; Based on available data, the classification criteria are not met

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; Based on available data, the classification criteria are not met

(h) STOT-single exposure; Based on available data, the classification criteria are not met

(i) STOT-repeated exposure; Based on available data, the classification criteria are not met

Target Organs None known.

(j) aspiration hazard; Not applicable Solid

Other Adverse Effects The toxicological properties have not been fully investigated.

Symptoms / effects,both acute and No information available delayed

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Do not empty into drains. .

Persistence and Degradability Persistence Insoluble in water. Degradability Not relevant for inorganic substances.

Bioaccumulative Potential May have some potential to bioaccumulate

Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water solubility

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors

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ALFAA11272 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 6 / 7 Lanthanum(III) oxide ______________________________________________________________________________________________ Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Chemical waste generators must determine whether a discarded chemical is classified as a Products hazardous waste. Consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Contaminated Packaging Empty remaining contents. Dispose of in accordance with local regulations. Do not re-use empty containers.

Other Information Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport Not Regulated

IMDG/IMO Not regulated

IATA Not regulated

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Lanthanum oxide - - X 215-200-5 X X X X X X KE-21836 (La2O3)

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Creation Date 21-Dec-2012 改訂版 Date 25-Jul-2026 改訂版 Summary SDS sections updated.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and

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ALFAA11272 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 7 / 7 Lanthanum(III) oxide ______________________________________________________________________________________________ hygiene.

Legend

CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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