サマリウム foil ALFAA43217 SDS

ページ 1 / 8 SAFETY DATA SHEET Creation Date 15-Feb-2011 改訂版 Date 27-Jul-2026 Version 6

ALFAA43217

Samarium foil

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 钐箔,钐箔,钐箔,钐箔,1.0mm1.0mm1.0mm1.0mm (0.04in)厚(0.04in)厚(0.04in)厚(0.04in)厚 Product 説明: Samarium foil

Cat No. : 43217 CAS No 7440-19-9 Molecular Formula Sm

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Solid Grey No information available

Emergency 概要 Flammable solid. In contact with water releases flammable gases which may ignite spontaneously. Causes damage to organs through prolonged or repeated exposure. Air sensitive.

Classification of the substance or mixture

Flammable solids. Category 2 Substances/mixtures which, in contact with water, emit flammable gases Category 1 Specific target organ toxicity - (repeated exposure) Category 1

Label 元素s

Signal Word Danger ______________________________________________________________________________________________ ページ 1

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Hazard Statements H228 - Flammable solid H260 - In contact with water releases flammable gases which may ignite spontaneously H372 - Causes damage to organs through prolonged or repeated exposure

Precautionary Statements Prevention P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P231 + P232 - Handle and store contents under inert gas. Protect from moisture P240 - Ground and bond container and receiving equipment P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P314 - Get medical advice/attention if you feel unwell P302 + P335 + P334 - IF ON SKIN: Brush off loose particles from skin. Immerse in cool water or wrap in wet bandages P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish Storage P402 + P404 - Store in a dry place. Store in a closed container Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Combustible material. Reacts violently with water, liberating extremely flammable gases. Water reactive. Health Hazards Causes damage to organs through prolonged or repeated exposure. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Is not likely mobile in the environment. Reacts with water.

Other Hazards Radioactive This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Samarium 7440-19-9 >95

SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Most important symptoms and effects None reasonably foreseeable.

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Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Produce flammable gases on contact with water.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation.

Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological Information.

Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Avoid dust formation. Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Handle under an inert atmosphere.

Storage Keep from any possible contact with water. Store under an inert atmosphere. Keep container tightly closed in a dry and well-ventilated place. Air sensitive.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of

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ALFAA43217 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026ページ 4 / 8 Samarium foil ______________________________________________________________________________________________ exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Disposable gloves See manufacturers - EN 374 (minimum requirement) recommendations Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly

Large scale/emergency use In case of insufficient ventilation, wear suitable respiratory equipment

Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. When RPE is used a face piece Fit Test should be conducted

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Grey Physical State Solid

Odor No information available Odor Threshold No data available pH No data available Melting Point/Range 1072 °C / 1961.6 °F Softening Point No data available Boiling Point/Range 1778 °C / 3232.4 °F @ 760 mmHg Flash Point Not applicable Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No data available Vapor Density Not applicable Solid ______________________________________________________________________________________________ ページ 4

ALFAA43217 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026ページ 5 / 8 Samarium foil ______________________________________________________________________________________________ Specific Gravity / Density No data available Bulk Density No data available Water Solubility Water reactive Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature 150 °C / 302 °F Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

Molecular Formula Sm Molecular Weight 150.36

SECTION 10. STABILITY AND REACTIVITY

Stability Water reactive. Air sensitive.

Hazardous Reactions None under normal processing. Hazardous Polymerization No information available.

Conditions to Avoid Avoid dust formation. Protect from water. Exposure to moist air or water.

材料 to avoid Water.

Hazardous Decomposition Products Hydrogen.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity; Component LD50 Oral LD50 Dermal LC50 Inhalation Samarium LD50 > 2000 mg/kg ( Rat )

(b) skin corrosion/irritation; No data available

(c) serious eye damage/irritation; No data available

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

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(i) STOT-repeated exposure; Category 1

Target Organs None known.

(j) aspiration hazard; Not applicable Solid

Symptoms / effects,both acute and No information available delayed

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Reacts with water so no ecotoxicity data for the substance is available.

Persistence and Degradability No information available Persistence Persistence is unlikely, based on information available. Degradability Reacts with water. Degradation in sewage Water reactive. treatment plant

Bioaccumulative Potential Product does not bioaccumulate due to reaction with water

Mobility in soil Reacts with water Is not likely mobile in the environment

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep product and empty container away from heat and sources of ignition.

Other Information Waste codes should be assigned by the user based on the application for which the product was used. Do not flush to sewer. Can be landfilled or incinerated, when in compliance with local regulations.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN3208 Proper Shipping Name METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. Technical Shipping Name Samarium Hazard Class 4.3 Packing Group III

IMDG/IMO

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ALFAA43217 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026ページ 7 / 8 Samarium foil ______________________________________________________________________________________________ UN-No UN3208 Proper Shipping Name METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. Technical Shipping Name Samarium Hazard Class 4.3 Packing Group III

IATA

UN-No UN3208 Proper Shipping Name METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.* Technical Shipping Name Samarium Hazard Class 4.3 Packing Group III

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Samarium - - X 231-128-7 X X X X X KE-30854

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Creation Date 15-Feb-2011 改訂版 Date 27-Jul-2026 改訂版 Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene.

Legend

CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% ______________________________________________________________________________________________ ページ 7

ALFAA43217 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026ページ 8 / 8 Samarium foil ______________________________________________________________________________________________ LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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