サマリウム (II) iodide, 0.1M in THF ALFAA22360 SDS

ページ 1 / 9 SAFETY DATA SHEET Creation Date 20-Aug-2009 改訂版 Date 03-Aug-2026 Version 5

ALFAA22360

Samarium (II) iodide, 0.1M in THF

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 碘化钐(II)碘化钐(II)碘化钐(II)碘化钐(II) Product 説明: Samarium (II) iodide, 0.1M in THF

Cat No. : 22360 Molecular Formula I2 Sm

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Liquid Clear Colorless No information available

Emergency 概要 Highly flammable liquid and vapor. Causes serious eye irritation. Suspected of causing cancer. May cause respiratory irritation. Harmful if swallowed. May cause drowsiness and dizziness. May form explosive peroxides. Moisture sensitive. Air sensitive.

Classification of the substance or mixture

Flammable liquids. Category 2 Acute Oral Toxicity Category 4 Serious Eye Damage/Eye Irritation Category 2 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3

Label 元素s

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ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 2 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________ Signal Word Danger

Hazard Statements H225 - Highly flammable liquid and vapor H319 - Causes serious eye irritation H351 - Suspected of causing cancer H335 - May cause respiratory irritation H302 - Harmful if swallowed H336 - May cause drowsiness or dizziness

Precautionary Statements Prevention P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection/ face protection Response P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308 + P313 - IF exposed or concerned: Get medical advice/attention P330 - Rinse mouth P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Vapors may cause flash fire or explosion. Highly flammable. May form explosive peroxides. Health Hazards Causes serious eye irritation. Suspected of causing cancer. May cause respiratory irritation. Harmful if swallowed. May cause drowsiness or dizziness. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. . Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems.

Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Tetrahydrofuran 109-99-9 96 Samarium iodide (SmI2) 32248-43-4 4

SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.

Eye Contact ______________________________________________________________________________________________ ページ 2

ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 3 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________ Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Most important symptoms and effects None reasonably foreseeable. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting: Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting: Causes central nervous system depression

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician Treat symptomatically. Symptoms may be delayed.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam. Water mist may be used to cool closed containers.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. May form explosive peroxides.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Remove all sources of ignition. Take precautionary measures against static discharges.

Environmental Precautions Should not be released into the environment.

Methods for Containment and Clean Up Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling ______________________________________________________________________________________________ ページ 3

ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 4 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________ Ensure adequate ventilation. Wear personal protective equipment/face protection. Avoid ingestion and inhalation. Do not get in eyes, on skin, or on clothing. If peroxide formation is suspected, do not open or move container. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame. Shelf life 12 months. May form explosive peroxides on prolonged storage. Containers should be dated when opened and tested periodically for the presence of peroxides. Should crystals form in a peroxidizable liquid, peroxidation may have occurred and the product should be considered extremely dangerous. In this instance, the container should only be opened remotely by professionals.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Component 中国 ACGIH TLV OSHA PEL NIOSH Tetrahydrofuran TWA: 300 mg/m3 TWA: 50 ppm (Vacated) TWA: 200 ppm IDLH: 2000 ppm STEL: 100 ppm (Vacated) TWA: 590 mg/m3 TWA: 200 ppm Skin (Vacated) STEL: 250 ppm TWA: 590 mg/m3 (Vacated) STEL: 735 mg/m3 STEL: 250 ppm TWA: 200 ppm STEL: 735 mg/m3 TWA: 590 mg/m3

Component Hong Kong Thailand European Union The 英国 Tetrahydrofuran TWA: 200 ppm TWA: 200 ppm TWA: 50 ppm (8h) STEL: 100 ppm 15 min TWA: 590 mg/m3 TWA: 150 mg/m3 (8h) STEL: 300 mg/m3 15 min STEL: 250 ppm STEL: 100 ppm (15min) TWA: 50 ppm 8 hr STEL: 737 mg/m3 STEL: 300 mg/m3 (15min) TWA: 150 mg/m3 8 hr Skin Skin

Legend

ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH: NIOSH - National Institute for Occupational Safety and Health

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS70 General methods for sampling airborne gases and vapours MDHS 88 Volatile organic compounds in air. Laboratory method using diffusive samplers, solvent desorption and gas chromatography MDHS 96 Volatile organic compounds in air - Laboratory method using pumped solid sorbent tubes, solvent desorption and gas chromatography

Exposure Controls

Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting equipment. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection Goggles (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Butyl rubber See manufacturers - EN 374 (minimum requirement) recommendations Neoprene gloves Inspect gloves before use. ______________________________________________________________________________________________ ページ 4

ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 5 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________ Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced おすすめ 絞り込み type: low boiling organic solvent 種類 AX Brown conforming to EN371 or Organic gases and vapours filter 種類 A Brown conforming to EN14387

Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. おすすめ half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141 When RPE is used a face piece Fit Test should be conducted

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear Colorless Physical State Liquid

Odor No information available Odor Threshold No data available pH No information available Melting Point/Range No data available Softening Point No data available Boiling Point/Range No information available Flash Point -17 °C / 1.4 °F Method - No information available Evaporation Rate No data available Flammability (solid,gas) Not applicable Liquid Explosion Limits No data available

Vapor Pressure No data available Vapor Density No data available (Air = 1.0) Specific Gravity / Density 0.9222 Bulk Density Not applicable Liquid Water Solubility Miscible Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Component log Pow Tetrahydrofuran 0.45 Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties Vapors may form explosive mixtures with air Oxidizing Properties No information available

Molecular Formula I2 Sm ______________________________________________________________________________________________ ページ 5

ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 6 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________ Molecular Weight 404.17

SECTION 10. STABILITY AND REACTIVITY

Stability May form explosive peroxides. Moisture sensitive. Air sensitive.

Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization may occur.

Conditions to Avoid Incompatible products. Excess heat. Keep away from open flames, hot surfaces and sources of ignition. Exposure to moist air or water. Exposure to air.

材料 to avoid Strong oxidizing agents.

Hazardous Decomposition Products Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity; Toxicology data for the components

Component LD50 Oral LD50 Dermal LC50 Inhalation Tetrahydrofuran 1650 mg/kg ( Rat ) > 2000 mg/kg (Rabbit) 180 mg/L ( Rat ) 1 h 53.9 mg/L ( Rat ) 4 h

(b) skin corrosion/irritation; Based on available data, the classification criteria are not met

(c) serious eye damage/irritation; Category 2

(d) respiratory or skin sensitization; Respiratory Based on available data, the classification criteria are not met Skin Based on available data, the classification criteria are not met

Component Test method Test species Study result Tetrahydrofuran Local Lymph Node Assay mouse non-sensitising 109-99-9 ( 96 ) OECD Test Guideline 429

No information available

(e) germ cell mutagenicity; Based on available data, the classification criteria are not met

Component Test method Test species Study result Tetrahydrofuran OECD Test Guideline 476 in vivo negative 109-99-9 ( 96 ) Gene cell mutation Mammalian ------------------------------------------ OECD Test Guideline 473 ------------------------------------------ ------------------------------------------ Chromosomal aberration assay in vitro negative Mammalian

Mutagenic effects have occured in microorganisms

(f) carcinogenicity; Category 2

Limited evidence of a carcinogenic effect The table below indicates whether each agency has listed any ingredient as a carcinogen

Component EU UK ドイツ IARC Tetrahydrofuran Group 2B ______________________________________________________________________________________________ ページ 6

ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 7 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________

(g) reproductive toxicity; Based on available data, the classification criteria are not met Component Test method Test species / Duration Study result Tetrahydrofuran OECD Test Guideline 416 Rat 2 Generation NOAEL = 3,000 ppm 109-99-9 ( 96 )

(h) STOT-single exposure; Category 3

検索結果 / Target organs Respiratory system Central nervous system (CNS)

(i) STOT-repeated exposure; Based on available data, the classification criteria are not met

Target Organs None known.

(j) aspiration hazard; Based on available data, the classification criteria are not met

Symptoms / effects,both acute and Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting: delayed Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting: Causes central nervous system depression

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Do not empty into drains. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system.

Component Freshwater Fish Water Flea Freshwater Algae Microtox Tetrahydrofuran 2160 mg/l LC50 = 96 h EC50 48 h 3485 mg/l Pimephales promelas EC50: >10000 mg/L/24h Leuciscus idus: LC50: 2820 mg/L/48h

Persistence and Degradability Persistence Persistence is unlikely, Miscible with water, based on information available.

Bioaccumulative Potential Bioaccumulation is unlikely

Component log Pow Bioconcentration factor (BCF) Tetrahydrofuran 0.45 No data available

Mobility in soil The product is water soluble, and may spread in water systems Will likely be mobile in the environment due to its water solubility Highly mobile in soils

Endocrine Disruptor Information Component EU - Endocrine Disrupters EU - Endocrine Disruptors - 日本 - Endocrine Disruptor Candidate List Evaluated Substances Information Tetrahydrofuran Group III Chemical Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations.

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ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 8 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________

Contaminated Packaging Dispose of this container to hazardous or special waste collection point. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep product and empty container away from heat and sources of ignition.

Other Information Do not flush to sewer. Waste codes should be assigned by the user based on the application for which the product was used. Can be landfilled or incinerated, when in compliance with local regulations.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN2056 Proper Shipping Name TETRAHYDROFURAN Hazard Class 3 Packing Group II

IMDG/IMO

UN-No UN2056 Proper Shipping Name TETRAHYDROFURAN Hazard Class 3 Packing Group II

IATA

UN-No UN2056 Proper Shipping Name TETRAHYDROFURAN Hazard Class 3 Packing Group II

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Tetrahydrofuran X X X 203-726-8 X X X X X X KE-33454

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Creation Date 20-Aug-2009 改訂版 Date 03-Aug-2026

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ALFAA22360 SAFETY DATA SHEET 改訂版 Date 03-Aug-2026ページ 9 / 9 Samarium (II) iodide, 0.1M in THF ______________________________________________________________________________________________ 改訂版 Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers. Fire prevention and fighting, identifying hazards and risks, static electricity, explosive atmospheres posed by vapours and dusts. Chemical incident response training.

Legend

CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Physical hazards On basis of test data Health Hazards Calculation method Environmental hazards Calculation method

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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