Vanadium Oxide, Enriched Vanadium Oxide SDS

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 1/11

Section 1: Identification of the Substance/混合物 and of the Company/Undertaking

Product Identifier: Identification as on the label/商品名： Vanadium(V) oxide, Enriched Vanadium. 分子量: 181.88 化学式: V 2 O 5 別名: Divanadium pentoxide. 詳細 of the supplier of the 安全データシート: Neonest AB Storgatan 70C, Solna SE-17152 Sweden Contact details: +46-76-219-9731 24-hour Emergency Contact: Swedish Poisons Centre 電話番号: 112 - Ask for Poisons Information, 112 – begär Giftinformation . Other International Contacts: CHEMTREC 24-hour: +1-703-741-5500 (US + Worldwide) NHS: 111 (UK) Charite: +49 30 450 531 000 (Netherlands) INTCF: +34 917689800 (Spain) CapTv: +33 1 40 05 48 48 (フランス)

Section 2: Hazards Identification

Classification of the substances or mixture: The mixture is classified according to: Regulation EC 1272/2008 [EU-GHS/CLP] Hazard classes/Hazard categories: Hazard statement: Acute Toxicity, Oral (Category 4) H302 Acute Toxicity, Inhalation (Category 4) H332 STOT SE (Category 3) H335 Mutagenicity (Category 2) H341 Reproductive Toxicity (Category 2) H361 STOT RE (Category 1) H372 Aquatic Chronic (Category 2) H411 Label elements: Hazard pictograms:

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 2/11 Signal Words: Danger. Hazard Statements: H302 Harmful if swallowed. H332 Harmful if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Precautionary Statements: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing. P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P391 Collect spillage. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local and national regulations. Other hazards: None known.

Section 3: 組成/Information on Ingredients

Substance/混合物: Substance. Ingredients: Substance name (IUPAC/EC) CAS - No. Molecular weight Concentration % by weight Classification EC1272/2008 EC - No. Divanadium pentoxide 1314-62-1 181.88 >99% Acute Tox. 4 H302 Acute Tox. 4 H332 STOT SE 3 H335 Muta. 2 H341 H341 Repr. 2 H361 H361 STOT RE 1 H372 Aquatic Chronic 2H411 215-239-8

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 3/11 For explanation of abbreviations see Section 16.

Section 4: First - Aid Measures

説明 of first aid measures: In case of inhalation: If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact: Wash off with soap and plenty of water. Consult a physician. In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. In case of ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed: Inhalation: Harmful if inhaled; causes respiratory tract irritation. Eyes: Causes eye irritation. Skin contact: Causes skin irritation; may be fatal if absorbed through skin. Ingestion: Harmful if swallowed. Indication of any immediate medical attention and special treatment needed: Treat symptomatically. Show this safety data sheet to a physician or emergency room.

Section 5: Fire - Fighting Measures

Extinguisher media: Suitable extinguisher media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media: None known. Special hazards arising from the mixture: None known. Advice for fire-fighters: Wear self-contained breathing apparatus and protective clothing for firefighting. Further information: Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Section 6: Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Personal precautions: Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. Methods for containment and cleaning up: Methods for cleaning up: Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal. Reference to other sections: Treat recovered material as described in the section "Disposal considerations".

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 4/11

Section 7: Handling and Storage

Precautions for safe handling: Advice on safe handling: Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. Hygiene measures: Do not eat, drink or smoke when using this product. Conditions for safe storage, including incompatibilities: Requirements for storage areas and containers: Keep container tightly closed in a dry and well-ventilated place.

Section 8: Exposure Controls/ Personal Protection

Control parameters: Occupational exposure limits: Components CAS-No. Value Control Parameters Update Basis Vanadium pentoxide 1314-62-1 TWA 0.05 mg/m 3 2007-01-01 USA - ACGIH Threshold Limit Values (TLV ) Remarks Irritation Lung Adopted values or notations enclosed are those for which changes are proposed in the NIC See Notice of Intended Changes (NIC) Substances for which there is a Biological Exposure Index or Indices (see BEI® section) Not classifiable as a human carcinogen: Agents which cause concern that they could be carcinogenic for humans but which cannot be assessed conclusively because of a lack of data. In vitro or animal studies do not provide indications of carcinogenicity which are sufficient to classify the agent into one of the other categories. TWA 0.05 mg/m 3 1989-01-19 USA - OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 TWA 0.05 mg/m 3 2008-01-01 USA - ACGIH Threshold Limit Values (TLV) Irritation Lung Adopted values or notations enclosed are those for which changes are proposed in the NIC See Notice of Intended Changes (NIC) Substances for which there is a Biological Exposure Index or Indices (see BEI® section) Not classifiable as a human carcinogen: Agents which cause concern that they could be carcinogenic for humans but which cannot be assessed conclusively because of a lack of data. In vitro or animal studies do not provide indications of carcinogenicity which are sufficient to classify the agent into one of the other categories. C 0.1 mg/m 3 2007-01-01 USA - Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants Ceiling limit is to be determined from breathing-zone air samples. Exposure controls: Appropriate engineering controls: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion into the general work area. Individual protection measures, such as personal protective equipment:

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 5/11 Eye/face protection: Face shield and safety glasses. Hand protection: Use chemical resistant gloves. Examples of preferred glove barrier materials include: Butyl rubber, Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate, polyvinyl alcohol, Polyvinyl chloride. Body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place. Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Section 9: Physical and Chemical Properties

Information on basic physical and chemical properties Appearance (form): Solid. Colour: No data available. Odour: No data available. Odour threshold: No data available. Molecular Weight: 181.88 pH (concentration): No data available. Melting point/range (° C): 690 °C Boiling point/range (° C): No data available. Freezing point (°C): No data available. Flash point (° C): No data available. Evaporation rate: No data available. Flammability (solid, gas): No data available. Ignition temperature (° C): No data available. Upper/lower flammability/explosive limits: No data available. Vapour pressure (20 ° C): No data available. Vapour density: No data available. Relative densi ty (25 ° C): 3.35 g/mL at 25 °C Water solubility (g/L ) at 20 ° C: No data available. n-Octanol/Water partition coefficient : No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity, dynamic (mPa s): No data available. Explosive properties: The substance or mixture is not classified as explosive. Oxidising properties: The substance or mixture is not classified as oxidizing.

Section 10: Stability and Reactivity

Reactivity: No dangerous reaction known under conditions of normal use. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use. Conditions to avoid: None known . Incompatible materials: Strong acids. Hazardous decomposition products: Hazardous decomposition products formed under fire conditions: vanadium/vanadium oxides.

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 6/11

Section 11: Toxicological Information

Information on toxicological effects: Acute Toxicity: LD 50 Oral (rat) 10 mg/kg. Remarks: Behavioural: Coma. LC 50 Inhalation (rat) 6 h - 126 mg/m 3 Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste): Eye: Other. Behavioural: Ataxia. Lungs, Thorax, or Respiration: Dyspnoea. LD 50 Dermal (rabbit) 50 mg/kg Remarks: Liver: Other changes. Kidney, Ureter, Bladder: Other changes. Classification according to GHS (1272/2008/EG, CLP) Skin corrosion/irritation: Not classified based on available information. Serious eye damage/eye irritation: Not classified based on available information. Respiratory or skin sensitisation: May cause respiratory irritation. Germ cell mutagenicity: Laboratory experiments have shown mutagenic effects. In vitro tests showed mutagenic effects. Carcinogenicity: IARC: 2B - Group 2B: Possibly carcinogenic to humans (Vanadium pentoxide) ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Reproductive toxicity: Possible risk of congenital malformation in the foetus. Suspected human reproductive toxicant. Specific target organ toxicity – single exposure (STOT): Not classified based on available information. Specific target organ toxicity (STOT) – repeated exposure: Causes damage to organs through prolonged or repeated exposure. Aspiration toxicity: Not classified based on available information.

Section 12: Ecological Information

Toxicity: Toxic to aquatic life with long lasting effects. Toxicity to fish: LC 50 - Oncorhynchus mykiss (rainbow trout) - 5.2 mg/l - 96.0 h Toxicity to Daphnia and Other Aquatic Invertebrates: EC 50 - Daphnia magna (Water flea) - 0.94 mg/l - 48 h Persistence and degradability: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. 検索結果 of PBT& vPvB assessment: Not relevant.

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 7/11 Other adverse effects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

Section 13: Disposal Considerations

Waste treatment methods: Observe all local and national environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Section 14: Transport Information

DOT: Proper Shipping Name: VANADIUM PENTOXIDE. Hazard Class : 6.1 UN Number: 2862 Packing Group: III Hazard Labels: Reportable quantity: 1000 lbs Marine Pollutant: No IMDG: Proper Shipping Name: VANADIUM PENTOXIDE. Hazard Class : 6.1 UN Number: 2862 Packing Group: III EMS No.: F-A, S-A Marine Pollutant: No IATA: Proper Shipping Name: VANADIUM PENTOXIDE. Hazard Class : 6.1 UN Number: 2862 Packing Group: III

Section 15: Regulatory Information

EU regulations: Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed. Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I Not listed.

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 8/11 Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed. Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Not listed. Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed. Authorisations: Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed. Restrictions on use: Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Not listed. Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding. Not regulated. Other EU regulations: Directive 2012/18/EU on major accident hazards involving dangerous substances Not listed. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Always applicable. Directive 94/33/EC on the protection of young people at work Not listed. Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. This 安全データシート complies with the requirements of Regulation (EC) No 1907/2006, as amended. OSHA Hazards: Target Organ Effect, Highly toxic by inhalation, Highly toxic by ingestion, Highly toxic by skin absorption, Irritant, Carcinogen, Teratogen. DSL 状態: All components of this product are on the Canadian DSL list.

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 9/11 SARA 302 Components: Vanadium pentoxide / CAS No. 1314-62-1 / 改訂版 Date 2007-07-01 SARA 313 Components: Vanadium pentoxide / CAS No. 1314-62-1 / 改訂版 Date 2007-07-01 SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard. Massachusetts Right To Know Components: Vanadium pentoxide / CAS No. 1314-62-1 / 改訂版 Date 2007-07-01 Pennsylvania Right To Know Components: Vanadium pentoxide / CAS No. 1314-62-1 / 改訂版 Date 2007-07-01 New Jersey Right To Know Components: Vanadium pentoxide / CAS No. 1314-62-1 / 改訂版 Date 2007-07-01 California Prop. 65 Components: This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm. National regulations: Follow national regulation for work with chemical agents. Chemical safety assessment: No Chemical Safety Assessment has been carried out.

Section 16: Other Information

List of abbreviations: ACGIH American Conference of Governmental Industrial Hygienists ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road ALARA As Low As Is Reasonably Achievable AMU Atomic Mass Unit ANSI American National Standards Institute BLS Basic Life Support CAM Continuous Air Monitor CAS Chemical Abstracts Service (division of the American Chemical Society) CEN European Committee for Standardization CERCLA Comprehensive Environmental Response Compensation and Liability Act CLP Classification, Labelling and Packaging (European Union) CPR Controlled Products Regulations (Canada) CWA Clean Water Act (USA) DAC Derived Air Concentration (USA) DOE 米国 Department of Energy (USA) DOT 米国 Department of Transportation (USA) DSL Domestic Substances List (Canada) EC50 Half Maximal Effective Concentration EINECS European Inventory of Existing Commercial Chemical Substances EHS Environmentally Hazardous Substance ELINCS European List of Notified Chemical Substances EMS Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency (USA) EPCRA Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 GHS Globally Harmonized System HMIS Hazardous 材料 Identification System (USA) IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Containers ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life or Health IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 10/11 LD50 Lethal dose, 50 percent LDLO Lethal Dose Low LOEC Lowest-Observed-Effective Concentration MARPOL International Convention for the Prevention of Pollution from Ships MSHA Mine Safety and Health Administration (USA) NCRP National Council on Radiation Protection & Measurements (USA) NDSL Non-Domestic Substances List (Canada) NFPA National Fire Protection Association (USA) NIOSH National Institute for Occupational Safety and Health (USA) NOEC No Observed Effect Concentration N.O.S. Not Otherwise Specified NRC Nuclear Regulatory Commission (USA) NTP National Toxicology Program (USA) OSHA Occupational Safety and Health Administration (USA) PBT Persistent Bioaccumulative and Toxic Chemical PEL Permissible Exposure Limit PIH Poisonous by Inhalation Hazard RCRA Resource Conservation and Recovery Act (USA) RCT Radiation Control Technician REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (Europe) RID Regulations Concerning the International Transport of Dangerous Goods by Rail RTECS Registry of Toxic Effects of Chemical Substances SARA Superfund Amendments and Reauthorization Act (USA) TDG Transportation of Dangerous Goods (Canada) TIH Toxic by Inhalation Hazard TLV Threshold Limit Value TPQ Threshold Planning Quantity TSCA Toxic Substances Control Act TWA Time Weighted Average UN United Nations (Number) VOC Volatile Organic 化合物 vPvB Very Persistent Very Bioaccumulative Chemical WGK Wassergefährdungsklassen (ドイツ: Water Hazard Classes) WHMIS Workplace Hazardous 材料 Information System References: 情報なし. 全文 of any H-statements not written out in full under Sections 2 to 15: H302 Harmful if swallowed. H332 Harmful if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. 改訂版 information: None. Training information:

安全データシート for Vanadium Oxide, Enriched Vanadium Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 24-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Vanadium(V) oxide, Enriched Vanadium https://www.buyisotope.com ページ 11/11 Follow training instructions when handling this material. Further Information: The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.