セリウム(IV) sulfate hydrate, REacton® ALFAA11323 SDS

ページ 1 / 8 SAFETY DATA SHEET 改訂版 Date 30-Jul-2026 Version 5

ALFAA11323

Cerium(IV) sulfate hydrate, REacton®

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 水合硫酸铈(IV)水合硫酸铈(IV)水合硫酸铈(IV)水合硫酸铈(IV) Product 説明: Cerium(IV) sulfate hydrate, REacton®

Cat No. : 11323 CAS No 95838-16-7 Molecular Formula Ce(SO4)2. xH2 O

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Solid Crystalline Yellow Odorless

Emergency 概要 May intensify fire; oxidizer. Causes severe skin burns and eye damage. Moisture sensitive.

Classification of the substance or mixture

Oxidizing solids Category 3 Skin Corrosion/Irritation Category 1 C Serious Eye Damage/Eye Irritation Category 1

Label 元素s

Signal Word Danger

Hazard Statements ______________________________________________________________________________________________ ページ 1

ALFAA11323 SAFETY DATA SHEET 改訂版 Date 30-Jul-2026ページ 2 / 8 Cerium(IV) sulfate hydrate, REacton® ______________________________________________________________________________________________ H272 - May intensify fire; oxidizer H314 - Causes severe skin burns and eye damage

Precautionary Statements Prevention P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P220 - Keep away from clothing and other combustible materials P221 - Take any precaution to avoid mixing with combustibles P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P362 + P364 - Take off contaminated clothing and wash it before reuse Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Oxidizing. Contact with combustible material may cause fire. Health Hazards Corrosive. Causes skin and eye burns. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems.

This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Cerium(IV) sulfate hydrate 95838-16-7 <=100

SECTION 4. FIRST AID MEASURES

General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Keep eye wide open while rinsing.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Call a physician immediately.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Call a physician or poison control center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an ______________________________________________________________________________________________ ページ 2

ALFAA11323 SAFETY DATA SHEET 改訂版 Date 30-Jul-2026ページ 3 / 8 Cerium(IV) sulfate hydrate, REacton® ______________________________________________________________________________________________ unconscious person.

Most important symptoms and effects Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Self-Protection of the First Aider No special precautions required.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Carbon dioxide (CO 2). Powder. Foam. Water may be ineffective. CO 2, dry chemical, dry sand, alcohol-resistant foam.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical The product causes burns of eyes, skin and mucous membranes. Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.).

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing.

Environmental Precautions Should not be released into the environment. Do not allow material to contaminate ground water system. See Section 12 for additional Ecological Information. Do not flush into surface water or sanitary sewer system.

Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Sweep up and shovel into suitable containers for disposal.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from clothing and other combustible materials.

Storage Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place. Do not store near combustible materials.

Specific Use(s) Use in laboratories

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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust MDHS 91 Metals and metalloids in workplace air by X-ray fluorescence spectrometry MDHS 99 Metals in air by ICP-AES

Exposure Controls

Engineering Measures None under normal use conditions. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. .

Personal protective equipment

Eye Protection Goggles (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection No protective equipment is needed under normal use conditions.

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced おすすめ 絞り込み type: Particle filter

Small scale/Laboratory use Maintain adequate ventilation

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Yellow Physical State Solid Crystalline

Odor Odorless Odor Threshold No data available pH No information available ______________________________________________________________________________________________ ページ 4

ALFAA11323 SAFETY DATA SHEET 改訂版 Date 30-Jul-2026ページ 5 / 8 Cerium(IV) sulfate hydrate, REacton® ______________________________________________________________________________________________ Melting Point/Range 195 °C / 383 °F (with decomposition) Softening Point No data available Boiling Point/Range No information available Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No data available Vapor Density Not applicable Solid Specific Gravity / Density 3.01 g/cm3 @ 20 °C Bulk Density No data available Water Solubility Soluble in water Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties Oxidizer

Molecular Formula Ce(SO4)2. xH2 O Molecular Weight 332.24(anhy)

SECTION 10. STABILITY AND REACTIVITY

Stability Moisture sensitive. Oxidizer: Contact with combustible/organic material may cause fire.

Hazardous Reactions None under normal processing. Hazardous Polymerization No information available.

Conditions to Avoid Incompatible products. Excess heat. Combustible material.

材料 to avoid Reducing Agent. Strong reducing agents. Combustible material.

Hazardous Decomposition Products Metal oxides. Cerium oxide.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity;

(b) skin corrosion/irritation; Category 1 C

(c) serious eye damage/irritation; Category 1

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

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(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs No information available.

(j) aspiration hazard; Not applicable Solid

Symptoms / effects,both acute and Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. delayed Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment. May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.

Persistence and Degradability Product contains heavy metals. Discharge into the environment must be avoided. Special pre-treatment is necessary Persistence based on information available, May persist. Degradability Not relevant for inorganic substances. Degradation in sewage Contains substances known to be hazardous to the environment or not degradable in waste treatment plant water treatment plants.

Bioaccumulative Potential May have some potential to bioaccumulate

Mobility in soil The product is water soluble, and may spread in water systems Will likely be mobile in the environment due to its water solubility Highly mobile in soils

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations. Should not be released into the environment.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point.

Other Information Do not flush to sewer. Large amounts will affect pH and harm aquatic organisms. Do not let this chemical enter the environment. Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains.

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SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN3085 Proper Shipping Name Oxidizing solid, corrosive, n.o.s. Technical Shipping Name (Cerium(IV) sulfate hydrate) Hazard Class 5.1 Subsidiary Hazard Class 8 Packing Group III

IMDG/IMO

UN-No UN3085 Proper Shipping Name Oxidizing solid, corrosive, n.o.s. Technical Shipping Name (Cerium(IV) sulfate hydrate) Hazard Class 5.1 Subsidiary Hazard Class 8 Packing Group III

IATA

UN-No UN3085 Proper Shipping Name OXIDIZING SOLID, CORROSIVE, N.O.S.* Technical Shipping Name (Cerium(IV) sulfate hydrate) Hazard Class 5.1 Subsidiary Hazard Class 8 Packing Group III

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department 改訂版 Date 30-Jul-2026 改訂版 Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene. Chemical incident response training.

Legend

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ALFAA11323 SAFETY DATA SHEET 改訂版 Date 30-Jul-2026ページ 8 / 8 Cerium(IV) sulfate hydrate, REacton® ______________________________________________________________________________________________ CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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