ジスプロシウム (III) fluoride, anhydrous 1646 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Dysprosium (III) fluoride, anhydrous

PRODUCT NUMBER: 1646

CAS NUMBER: 13569-80-7

SYNONYMS: Dysprosium trifluoride

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Warning

Hazard Statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.

Precautionary Phrases

P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with waster for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 0

DYSPROSIUM (III) FLUORIDE, ANHYDROUS PAGE 1

SECTION 2 HAZARDS IDENTIFICATION (Cont.)

EYE CONTACT: May cause irritation of the eyes. SKIN CONTACT: May cause mild irritation and redness. INHALATION: May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath. INGESTION: Toxicity reduced to the extent that this compound is relatively insoluble. In large amounts may cause vomiting, abdominal pain, and diarrhea.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: DyF3

Molecular Weight: 219.5

CHEMICAL NAME CAS# %

Dysprosium (III) fluoride 13569-80-7 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with plenty of water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. 閉じるly monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Product is not flammable AUTO IGNITION TEMPERATURE: 情報なし EXPLOSION LIMITS: Product does not present explosion hazards EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen fluoride and dysprosium oxides

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the formation of dust. Avoid breathing vapors, mist, gas, or dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND 材料名S FOR CONTAINMENT AND CLEANING UP: Spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate. Sweep up and place in suitable container for proper disposal.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Avoid formation of dusts and aerosols. Handle under a dry inert gas. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Store away from oxidizing agents.

DYSPROSIUM (III) FLUORIDE, ANHYDROUS PAGE 2

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Component Exposure Limits Basis Entity Dysprosium (III) fluoride (As fluoride) 2.5 mg/m3 TLV ACGIH 2.5 mg/m3 PEL OSHA 1 mg/m3 REL NIOSH 3 mg/g (Before shift) BEI-U ACGIH 10mg/g (End of shift) BEI-U ACGIH 2mg/l (16hrs after exposure) BEI-U ACGIH 3mg/l (After exposure ceases) BEI-U ACGIH TLV: Threshold Limit Value over 8 hours of work. REL: おすすめ Exposure Limit PEL: Permissible Exposure Limit BEI-U: Biological Exposure Indices in Urine

EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: White powder ODOR: None MOLECULAR WEIGHT: 219.5 BOILING POINT: 2200° C MELTING POINT: 1360° C SPECIFIC GRAVITY: No data available SOLUBILITY: Insoluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Avoid moisture INCOMPATIBILITY: Strong oxidizing agents and mineral acids DECOMPOSITION PRODUCTS: Hydrogen fluoride and dysprosium oxide fumes

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: 情報なし CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: 情報なし TETRATOGENIC EFFECTS: 情報なし CHRONIC TOXICITY: Lanthanons can cause delayed blood clotting leading to hemorrhages. Exposure may also lead to sensitivity heat, itching, increased awareness of odor and taste, and liver damage. Fluorides may cause salivation, nausea, vomiting, diarrhea, and abdominal pain, followed by weakness, tremors, shallow respiration, convulsions, and coma. May cause brain and kidney damage. Chronic fluoride poisoning can cause severe bone changes, loss of weight, anorexia, anemia, and dental defects. RTECS: No data

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

DYSPROSIUM (III) FLUORIDE, ANHYDROUS PAGE 3

SECTION 12 ECOLOGICAL DATA

No data available.

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good.

SECTION 15 REGULATORY INFORMATION

TSCA: Listed in the TSCA inventory

SARA 302/304: Not Listed

SARA 311/312: Acute Health Hazard

SARA (TITLE 313): Not Listed

CALIFORNIA PROP. 65: Not Listed

MASSACHUSETTS RIGHT TO KNOW COMPONENTS: No components are subject to the Massachusetts Right to Know Act.

NEW JERSEY RIGHT TO KNOW COMPONENTS: Dysprosium (III) fluoride

PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Dysprosium (III) fluoride

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 01/15 SDS DEPT.

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