ガドリニウム(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol ALFAA42277 SDS

ページ 1 / 10 SAFETY DATA SHEET 改訂版 Date 04-Aug-2026 Version 6

ALFAA42277

Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 异丙醇钆(III)异丙醇钆(III)异丙醇钆(III)异丙醇钆(III) Product 説明: Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)

Cat No. : 42277 Molecular Formula C9 H21 GdO3

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Liquid No information available No information available

Emergency 概要 Highly flammable liquid and vapor. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause drowsiness and dizziness. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. Moisture sensitive.

Classification of the substance or mixture

Flammable liquids. Category 2 Aspiration Toxicity Category 1 Skin Corrosion/Irritation Category 1 C Serious Eye Damage/Eye Irritation Category 1 Reproductive Toxicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Specific target organ toxicity - (repeated exposure) Category 2 Acute aquatic toxicity Category 2 Chronic aquatic toxicity Category 3

Label 元素s

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Signal Word Danger

Hazard Statements H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H336 - May cause drowsiness or dizziness H401 - Toxic to aquatic life H412 - Harmful to aquatic life with long lasting effects H314 - Causes severe skin burns and eye damage H373 - May cause damage to organs through prolonged or repeated exposure H361 - Suspected of damaging fertility or the unborn child

Precautionary Statements Prevention P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P243 - Take action to prevent static discharges P260 - Do not breathe dust/fume/gas/mist/vapors/spray P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P362 + P364 - Take off contaminated clothing and wash it before reuse Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Vapors may cause flash fire or explosion. Highly flammable. Health Hazards Aspiration hazard if swallowed - can enter lungs and cause damage. Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. Corrosive. Causes skin and eye burns. May cause damage to organs through prolonged or repeated exposure. Environmental hazards Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Is not likely mobile in the environment due its low water solubility. Spillage unlikely to penetrate soil.

Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight %

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SECTION 4. FIRST AID MEASURES

General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Call a physician immediately.

Inhalation If not breathing, give artificial respiration. Remove from exposure, lie down. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician immediately. Risk of serious damage to the lungs (by aspiration).

Ingestion Do NOT induce vomiting. Clean mouth with water. Never give anything by mouth to an unconscious person. Call a physician immediately. Call a physician or poison control center immediately. If vomiting occurs naturally, have victim lean forward.

Most important symptoms and effects Causes burns by all exposure routes. Difficulty in breathing. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting: Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician Treat symptomatically. Symptoms may be delayed.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam. Water mist may be used to cool closed containers.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

SECTION 6. ACCIDENTAL RELEASE MEASURES

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Environmental Precautions Do not flush into surface water or sanitary sewer system. Should not be released into the environment. Do not allow material to contaminate ground water system.

Methods for Containment and Clean Up Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges.

Storage Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks and flame.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Component 中国 ACGIH TLV OSHA PEL NIOSH Toluene TWA: 50 mg/m3 TWA: 20 ppm (Vacated) TWA: 100 ppm IDLH: 500 ppm STEL: 100 mg/m3 (Vacated) TWA: 375 mg/m3 REL = 100 ppm (TWA) Skin Ceiling: 300 ppm REL = 375 mg/m3 (TWA) (Vacated) STEL: 150 ppm STEL: 150 ppm (Vacated) STEL: 560 mg/m3 STEL: 560 mg/m3 TWA: 200 ppm Isopropyl alcohol TWA: 350 mg/m3 TWA: 200 ppm (Vacated) TWA: 400 ppm IDLH: 2000 ppm STEL: 700 mg/m3 STEL: 400 ppm (Vacated) TWA: 980 mg/m3 REL = 400 ppm (TWA) (Vacated) STEL: 500 ppm REL = 980 mg/m3 (TWA) (Vacated) STEL: 1225 STEL: 500 ppm mg/m3 STEL: 1225 mg/m3 TWA: 400 ppm TWA: 980 mg/m3

Component Hong Kong Thailand European Union The 英国 Toluene TWA: 50 ppm Ceiling: 300 ppm TWA: 50 ppm (8hr) STEL: 100 ppm 15 min TWA: 188 mg/m3 STEL: 500 ppm TWA: 192 mg/m3 (8hr) STEL: 384 mg/m3 15 min TWA: 200 ppm STEL: 100 ppm (15min) TWA: 50 ppm 8 hr STEL: 384 mg/m3 (15min) TWA: 191 mg/m3 8 hr Skin Skin Isopropyl alcohol TWA: 400 ppm TWA: 400 ppm STEL: 500 ppm 15 min TWA: 983 mg/m3 STEL: 1250 mg/m3 15 min STEL: 500 ppm TWA: 400 ppm 8 hr STEL: 1230 mg/m3 TWA: 999 mg/m3 8 hr

Legend

ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration

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Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS70 General methods for sampling airborne gases and vapours MDHS 88 Volatile organic compounds in air. Laboratory method using diffusive samplers, solvent desorption and gas chromatography MDHS 96 Volatile organic compounds in air - Laboratory method using pumped solid sorbent tubes, solvent desorption and gas chromatography MDHS 91 Metals and metalloids in workplace air by X-ray fluorescence spectrometry MDHS 99 Metals in air by ICP-AES

Exposure Controls

Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting equipment. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection Goggles (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Nitrile rubber See manufacturers - EN 374 (minimum requirement) Viton (R) recommendations Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced おすすめ 絞り込み type: low boiling organic solvent 種類 AX Brown conforming to EN371 or Organic gases and vapours filter 種類 A Brown conforming to EN14387

Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. おすすめ half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141 When RPE is used a face piece Fit Test should be conducted

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls Prevent product from entering drains. Do not allow material to contaminate ground water system.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Physical State Liquid ______________________________________________________________________________________________ ページ 5

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Odor No information available Odor Threshold No data available pH No information available Melting Point/Range No data available Softening Point No data available Boiling Point/Range No information available Flash Point 4 °C / 39.2 °F Method - No information available Evaporation Rate No data available Flammability (solid,gas) Not applicable Liquid Explosion Limits No data available

Vapor Pressure No data available Vapor Density No data available (Air = 1.0) Specific Gravity / Density No data available Bulk Density Not applicable Liquid Water Solubility Immiscible Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Component log Pow Toluene 2.73 Isopropyl alcohol 0.05 Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties Vapors may form explosive mixtures with air Oxidizing Properties No information available

Molecular Formula C9 H21 GdO3 Molecular Weight 334.51

SECTION 10. STABILITY AND REACTIVITY

Stability Moisture sensitive.

Hazardous Reactions None under normal processing. Hazardous Polymerization No information available.

Conditions to Avoid Keep away from open flames, hot surfaces and sources of ignition.

材料 to avoid No information available.

Hazardous Decomposition Products Carbon monoxide (CO). Carbon dioxide (CO2). Gadolinium oxide.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity; Toxicology data for the components

Component LD50 Oral LD50 Dermal LC50 Inhalation Toluene > 5000 mg/kg ( Rat ) LD50 = 12000 mg/kg ( Rabbit ) 26700 ppm ( Rat ) 1 h

Isopropyl alcohol 5045 mg/kg ( Rat ) 12800 mg/kg ( Rat ) 72.6 mg/L ( Rat ) 4 h 3600 mg/kg ( Mouse )

(b) skin corrosion/irritation; Category 1 C

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(c) serious eye damage/irritation; Category 1

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; Category 2 Reproductive Effects California Proposition 65. Reproductive toxicity.

(h) STOT-single exposure; Category 3

検索結果 / Target organs Central nervous system (CNS)

(i) STOT-repeated exposure; Category 2

Target Organs Ears, Neuropsychological effects, Eyes.

(j) aspiration hazard; Category 1

Symptoms / effects,both acute and Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, delayed tiredness, nausea and vomiting: Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects The product contains following substances which are hazardous for the environment. Contains a substance which is:. Toxic to aquatic organisms. May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.

Component Freshwater Fish Water Flea Freshwater Algae Microtox Toluene 50-70 mg/L LC50 96 h EC50: = 11.5 mg/L, 48h EC50: = 12.5 mg/L, 72h EC50 = 19.7 mg/L 30 5-7 mg/L LC50 96 h (Daphnia magna) static min 15-19 mg/L LC50 96 h EC50: 5.46 - 9.83 mg/L, (Pseudokirchneriella 28 mg/L LC50 96 h 48h Static (Daphnia subcapitata) 12 mg/L LC50 96 h magna) EC50: > 433 mg/L, 96h (Pseudokirchneriella subcapitata)

Isopropyl alcohol LC50: = 9640 mg/L, 96h 13299 mg/L EC50 = 48 EC50: > 1000 mg/L, 72h = 35390 mg/L EC50 flow-through h (Desmodesmus Photobacterium (Pimephales promelas) 9714 mg/L EC50 = 24 h subspicatus) phosphoreum 5 min LC50: > 1400000 µg/L, EC50: > 1000 mg/L, 96h 96h (Lepomis (Desmodesmus macrochirus) subspicatus) LC50: = 11130 mg/L, 96h static (Pimephales promelas) LC50: = 10000000 µg/L, 96h (Daphnia)

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Persistence and Degradability Product contains heavy metals. Discharge into the environment must be avoided. Special pre-treatment is necessary Persistence Immiscible with water, May persist. Component Degradability Toluene 86% (20d) 108-88-3 ( 57.00 ) Degradation in sewage Contains substances known to be hazardous to the environment or not degradable in waste treatment plant water treatment plants.

Bioaccumulative Potential May have some potential to bioaccumulate; Product has a high potential to bioconcentrate

Component log Pow Bioconcentration factor (BCF) Toluene 2.73 90 Isopropyl alcohol 0.05 No data available

Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water solubility

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep product and empty container away from heat and sources of ignition.

Other Information Do not flush to sewer. Waste codes should be assigned by the user based on the application for which the product was used. Can be landfilled or incinerated, when in compliance with local regulations. Do not empty into drains. Large amounts will affect pH and harm aquatic organisms.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN1993 Proper Shipping Name Flammable liquid, n.o.s. Technical Shipping Name (TOLUENE, ISOPROPANOL (ISOPROPYL ALCOHOL)) Hazard Class 3 Packing Group II

IMDG/IMO

UN-No UN1993 Proper Shipping Name Flammable liquid, n.o.s. Technical Shipping Name (TOLUENE, ISOPROPANOL (ISOPROPYL ALCOHOL)) Hazard Class 3 Packing Group II

IATA

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UN-No UN1993 Proper Shipping Name Flammable liquid, n.o.s. Technical Shipping Name (TOLUENE, ISOPROPANOL (ISOPROPYL ALCOHOL)) Hazard Class 3 Packing Group II

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Toluene X X X 203-625-9 X X X X X X KE-33936 Isopropyl alcohol X X X 200-661-7 X X X X X X KE-29363

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department 改訂版 Date 04-Aug-2026 改訂版 Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers. Fire prevention and fighting, identifying hazards and risks, static electricity, explosive atmospheres posed by vapours and dusts. Chemical incident response training.

Legend

CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative ______________________________________________________________________________________________ ページ 9

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ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Physical hazards On basis of test data Health Hazards Calculation method Environmental hazards Calculation method

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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