ガドリニウム(III) oxide ALFAA11291 SDS

ページ 1 / 8 SAFETY DATA SHEET Creation Date 26-Sep-2009 改訂版 Date 24-Jul-2026 Version 6

ALFAA11291

Gadolinium(III) oxide

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 氧化钆,氧化钆,氧化钆,氧化钆,REactonREactonREactonREacton Product 説明: Gadolinium(III) oxide

Cat No. : 11291 別名 Gadolinium(III)Oxide; Gadolinia; Digadolinium Trioxide CAS No 12064-62-9 Molecular Formula Gd2 O3

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Powder Solid White No information available

Emergency 概要 Causes serious eye irritation. Air sensitive. Hygroscopic.

Classification of the substance or mixture

Serious Eye Damage/Eye Irritation Category 2

Label 元素s

Signal Word Warning

Hazard Statements H319 - Causes serious eye irritation

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Precautionary Statements Prevention P264 - Wash face, hands and any exposed skin thoroughly after handling P280 - Wear eye protection/ face protection Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention Storage P403 - Store in a well-ventilated place Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Hygroscopic. Health Hazards Causes serious eye irritation. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Is not likely mobile in the environment due its low water solubility. Spillage unlikely to penetrate soil.

This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Gadolinium oxide (Gd2O3) 12064-62-9 >95

SECTION 4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention.

Ingestion Do NOT induce vomiting. Get medical attention.

Most important symptoms and effects No information available.

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Carbon dioxide (CO 2). Dry chemical. Chemical foam.

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ALFAA11291 SAFETY DATA SHEET 改訂版 Date 24-Jul-2026ページ 3 / 8 Gadolinium(III) oxide ______________________________________________________________________________________________ Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation.

Environmental Precautions Prevent further leakage or spillage if safe to do so.

Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Avoid dust formation.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Ensure adequate ventilation. Wear personal protective equipment/face protection. Avoid contact with skin and eyes. Do not breathe dust. Do not ingest. If swallowed then seek immediate medical assistance. Minimize dust generation and accumulation. Wash hands before breaks and immediately after handling the product.

Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep under nitrogen.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection Goggles (European standard - EN 166) ______________________________________________________________________________________________ ページ 3

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Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure

Respiratory Protection No protective equipment is needed under normal use conditions.

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced

Small scale/Laboratory use Maintain adequate ventilation

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance White Physical State Powder Solid

Odor No information available Odor Threshold No data available pH No information available Melting Point/Range 1900 °C / 3452 °F Softening Point No data available Boiling Point/Range No information available Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No data available Vapor Density Not applicable Solid Specific Gravity / Density No data available Bulk Density No data available Water Solubility Insoluble Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

Molecular Formula Gd2 O3 ______________________________________________________________________________________________ ページ 4

ALFAA11291 SAFETY DATA SHEET 改訂版 Date 24-Jul-2026ページ 5 / 8 Gadolinium(III) oxide ______________________________________________________________________________________________ Molecular Weight 362.5

SECTION 10. STABILITY AND REACTIVITY

Stability Hygroscopic. Air sensitive.

Hazardous Reactions No information available. Hazardous Polymerization No information available.

Conditions to Avoid Exposure to air. Incompatible products. Exposure to moisture. Avoid dust formation.

材料 to avoid Strong acids. Finely powdered metals.

Hazardous Decomposition Products None under normal use conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity; Component LD50 Oral LD50 Dermal LC50 Inhalation Gadolinium oxide (Gd2O3) LD50 > 5 g/kg ( Rat ) LC50 > 5.04 mg/L ( Rat ) 4 h

(b) skin corrosion/irritation; No data available

(c) serious eye damage/irritation; Category 2

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs No information available.

(j) aspiration hazard; Not applicable Solid

Other Adverse Effects The toxicological properties have not been fully investigated.

Symptoms / effects,both acute and No information available delayed ______________________________________________________________________________________________ ページ 5

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SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects .

Persistence and Degradability Persistence Insoluble in water. Degradability Not relevant for inorganic substances.

Bioaccumulative Potential May have some potential to bioaccumulate

Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water solubility

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point.

Other Information Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport Not Regulated

IMDG/IMO Not regulated

IATA Not regulated

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 -

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ALFAA11291 SAFETY DATA SHEET 改訂版 Date 24-Jul-2026ページ 7 / 8 Gadolinium(III) oxide ______________________________________________________________________________________________ (2015 2012 Edition) Gadolinium oxide - - X 235-060-9 X X X X X X KE-10558 (Gd2O3)

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Creation Date 26-Sep-2009 改訂版 Date 24-Jul-2026 改訂版 Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers.

Legend

CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

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