ランタン(III) chloride heptahydrate ALFAA11268 SDS

ページ 1 / 8 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026 Version 6

ALFAA11268

Lanthanum(III) chloride heptahydrate

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 氯化镧(III)七水合物氯化镧(III)七水合物氯化镧(III)七水合物氯化镧(III)七水合物 Product 説明: Lanthanum(III) chloride heptahydrate

Cat No. : 11268 別名 Lanthanum trichloride heptahydrate. CAS No 10025-84-0 Molecular Formula Cl3La.7H2O

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Solid White Odorless

Emergency 概要 May be corrosive to metals. May cause an allergic skin reaction. Causes serious eye damage. Toxic to aquatic life with long lasting effects.

Classification of the substance or mixture

Substances/mixtures corrosive to metal Category 1 Serious Eye Damage/Eye Irritation Category 1 Skin Sensitization Category 1 Chronic aquatic toxicity Category 2

Label 元素s

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ALFAA11268 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 2 / 8 Lanthanum(III) chloride heptahydrate ______________________________________________________________________________________________ Signal Word Danger

Hazard Statements H290 - May be corrosive to metals H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements Prevention P234 - Keep only in original packaging P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P363 - Wash contaminated clothing before reuse P390 - Absorb spillage to prevent material damage Storage P406 - Store in corrosion resistant polypropylene container with a resistant inliner Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards May be corrosive to metals. Health Hazards May cause an allergic skin reaction. Environmental hazards Toxic to aquatic life with long lasting effects.

This product does not contain any known or suspected endocrine disruptors. Toxic to terrestrial vertebrates.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Lanthanum chloride (LaCl3), heptahydrate 10025-84-0 <=100 Lanthanum chloride 10099-58-8 -

SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Most important symptoms and effects None reasonably foreseeable. . Causes severe eye damage. May cause allergic skin reaction. Symptoms of allergic reaction may ______________________________________________________________________________________________ ページ 2

ALFAA11268 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 3 / 8 Lanthanum(III) chloride heptahydrate ______________________________________________________________________________________________ include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation.

Environmental Precautions Do not flush into surface water or sanitary sewer system. Should not be released into the environment. Do not allow material to contaminate ground water system.

Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage Keep container tightly closed in a dry and well-ventilated place.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

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ALFAA11268 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 4 / 8 Lanthanum(III) chloride heptahydrate ______________________________________________________________________________________________

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection Goggles (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced おすすめ 絞り込み type: Particulates filter conforming to EN 143

Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. おすすめ half mask:- Particle filtering: EN149:2001 When RPE is used a face piece Fit Test should be conducted

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls Prevent product from entering drains. Do not allow material to contaminate ground water system.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance White Physical State Solid

Odor Odorless Odor Threshold No data available pH No information available

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ALFAA11268 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 5 / 8 Lanthanum(III) chloride heptahydrate ______________________________________________________________________________________________ Melting Point/Range 91 °C / 195.8 °F Softening Point No data available Boiling Point/Range No information available Flash Point Not applicable Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure negligible Vapor Density Not applicable Solid Specific Gravity / Density No data available Bulk Density No data available Water Solubility No information available Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

Molecular Formula Cl3La.7H2O Molecular Weight 371.36

SECTION 10. STABILITY AND REACTIVITY

Stability Stable under normal conditions.

Hazardous Reactions None under normal processing. Hazardous Polymerization No information available.

Conditions to Avoid None known.

材料 to avoid No information available.

Hazardous Decomposition Products Lanthanum oxide. Hydrogen chloride.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity; Component LD50 Oral LD50 Dermal LC50 Inhalation Lanthanum chloride LD50 = 4184 mg/kg ( Rat ) LD50 > 2000 mg/kg ( Rabbit )

(b) skin corrosion/irritation; No data available

(c) serious eye damage/irritation; Category 1

(d) respiratory or skin sensitization; Respiratory No data available Skin Category 1

May cause sensitization by skin contact

(e) germ cell mutagenicity; No data available

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ALFAA11268 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 6 / 8 Lanthanum(III) chloride heptahydrate ______________________________________________________________________________________________

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs None known.

(j) aspiration hazard; Not applicable Solid

Symptoms / effects,both acute and Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling delayed of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment. May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.

Component Freshwater Fish Water Flea Freshwater Algae Microtox Lanthanum chloride (LaCl3), heptahydrate 0.0432 mg/l (48h)

Persistence and Degradability Product contains heavy metals. Discharge into the environment must be avoided. Special pre-treatment is necessary Persistence May persist. Degradability Not relevant for inorganic substances. Degradation in sewage Contains substances known to be hazardous to the environment or not degradable in waste treatment plant water treatment plants.

Bioaccumulative Potential Product has a high potential to bioconcentrate

Mobility in soil No information available

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point.

Other Information Do not flush to sewer. Waste codes should be assigned by the user based on the

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ALFAA11268 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 7 / 8 Lanthanum(III) chloride heptahydrate ______________________________________________________________________________________________ application for which the product was used. Do not empty into drains. Do not let this chemical enter the environment.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. Technical Shipping Name Lanthanum(III) chloride heptahydrate Hazard Class 8 Packing Group III

IMDG/IMO

UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. Technical Shipping Name Lanthanum(III) chloride heptahydrate Hazard Class 8 Packing Group III

IATA

UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. Technical Shipping Name Lanthanum(III) chloride heptahydrate Hazard Class 8 Packing Group III

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories 中国, X = listed, オーストラリア, U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), オーストラリア (AICS), Korea (KECL), 中国 (IECSC), 日本 (ENCS), Philippines (PICCS), Taiwan (TCSI), 日本 (ISHL), New Zealand (NZIoC), 日本 (ISHL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Lanthanum chloride - - X - - - X - X - (LaCl3), heptahydrate Lanthanum chloride - - X 233-237-5 X X X X X X KE-21827

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department 改訂版 Date 25-Jul-2026 改訂版 Summary SDS sections updated.

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ALFAA11268 SAFETY DATA SHEET 改訂版 Date 25-Jul-2026ページ 8 / 8 Lanthanum(III) chloride heptahydrate ______________________________________________________________________________________________ Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers.

Legend

CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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