Molybdenum-100 SDS

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 1/10

Section 1: Identification of the Substance/混合物 and of the Company/Undertaking

Product Identifier: Identification as on the label/商品名： Molybdenum Trioxide, Enriched Molybdenum Trioxide. 分子量: 143.94 化学式: MoO 3 別名: Molybdic anhydride; molybdic trioxide; molybdenum oxide. 詳細 of the supplier of the 安全データシート: Neonest AB Storgatan 70C, Solna SE-17152 Sweden Contact details: +46-76-219-9731 24-hour Emergency Contact: Swedish Poisons Centre 電話番号: 112 - Ask for Poisons Information, 112 – begär Giftinformation . Other International Contacts: CHEMTREC 24-hour: +1-703-741-5500 (US + Worldwide) NHS: 111 (UK) Charite: +49 30 450 531 000 (Netherlands) INTCF: +34 917689800 (Spain) CapTv: +33 1 40 05 48 48 (フランス)

Section 2: Hazards Identification

Classification of the substances or mixture: The mixture is classified according to: Regulation EC 1272/2008 [EU-GHS/CLP] Hazard classes/Hazard categories: Hazard statement: Eye Irritant (Category 2) H319 STOT SE (Category 3) H335 Carcinogenicity (Category 2) H351 Label elements: Hazard pictograms: Signal Words: Warning.

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 2/10 Hazard Statements: H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer. Precautionary Statements: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/national regulations. Other hazards: None known.

Section 3: 組成/Information on Ingredients

Substance/混合物: Substance. Ingredients: Substance name (IUPAC/EC) CAS - No. Molecular weight Concentration % by weight Classification EC1272/2008 EC - No. Molybdenum trioxide 1313-27-5 143.94 >99% Acute Tox. 4 H302 Eye Irrit. 2 H319 Acute Tox. 4 H332 STOT SE 3 H335 215-204-7 For explanation of abbreviations see Section 16.

Section 4: First - Aid Measures

説明 of first aid measures: In case of inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. In case of skin contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. In case of eye contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. In case of ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Most important symptoms and effects, both acute and delayed: Inhalation: May be harmful if inhaled; causes respiratory tract irritation.

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 3/10 Eyes: Causes eye irritation. Skin contact: May be harmful if absorbed through skin; causes skin irritation. Ingestion: May be harmful if swallowed. Indication of any immediate medical attention and special treatment needed: Treat symptomatically. Show this safety data sheet to a physician or emergency room. Sect ion 5: Fire - Fighting Measures Extinguisher media: Suitable extinguisher media: Use any means suitable for extinguishing surrounding fire. Unsuitable extinguishing media: None known. Special hazards arising from the mixture: None known. Advice for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Further information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode.

Section 6: Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Personal precautions: Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in

Section 8.

Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. Methods for containment and cleaning up: Methods for cleaning up: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. Reference to other sections: Treat recovered material as described in the section "Disposal considerations".

Section 7: Handling and Storage

Precautions for safe handling: Advice on safe handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Hygiene measures: Do not eat, drink or smoke when using this product. Conditions for safe storage, including incompatibilities: Requirements for storage areas and containers: Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 4/10

Section 8: Exposure Controls/ Personal Protection

Control parameters: Occupational exposure limits: OSHA Permissible Exposure Limit (PEL): 5 mg/m 3 for soluble molybdenum compounds as Mo. 15 mg/m 3 total dust, for insoluble molybdenum compounds as Mo. ACGIH Threshold Limit Value (TLV): Molybdenum, metal and insoluble compounds, inhalable fraction, as Mo: 10 mg/m 3 Molybdenum, metal and insoluble compounds, respirable fraction, as Mo: 3 mg/m 3 Molybdenum, soluble compounds, respirable fraction, as Mo: 0.5 mg/m 3 , A3 - Confirmed animal carcinogen with unknown relevance to humans. Exposure controls: Appropriate engineering controls: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Individual protection measures, such as personal protective equipment: Eye/face protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick drench facilities in work area. Hand protection: Use chemical resistant gloves. Examples of preferred glove barrier materials include: Butyl rubber, Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate, polyvinyl alcohol, Polyvinyl chloride. Body protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection: If the exposure limit is exceeded and engineering controls are not feasible, (NIOSH Approved) a full facepiece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids. glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator.

Section 9: Physical and Chemical Properties

Information on basic physical and chemical properties Appearance (form): Solid (powder). Colour: White, or slightly yellow to blue. Odour: Odourless. Odour threshold: No data available. Molecular Weight: 143.94 pH (concentration): No data available. Melting point/range (° C): 795 °C Boiling point/range (° C): 1150 °C Freezing point (°C): No data available. Flash point (° C): No data available. Evaporation rate: No data available.

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 5/10 Flammability (solid, gas): No data available. Ignition temperature (° C): No data available. Upper/lower flammability/explosive limits: No data available. Vapour pressure (20 ° C): No data available. Vapour density: No data available. Relative densi ty (25 ° C): 4.69 g/cm 3 Water solubility (g/L ) at 20 ° C: 0.107 g/100 g water @ 18 °C n-Octanol/Water partition coefficient : No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity, dynamic (mPa s): No data available. Explosive properties: The substance or mixture is not classified as explosive. Oxidising properties: The substance or mixture is not classified as oxidizing.

Section 10: Stability and Reactivity

Reactivity: No dangerous reaction known under conditions of normal use. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use. Conditions to avoid: None known . Incompatible materials: Incompatible with alkali metals, most common metals and oxidizing agents. Explodes on contact with molten magnesium. Violent reaction with interhalogens (e.g., bromine pentafluoride; chlorine trifluoride). Incandescent reaction with hot sodium, potassium or lithium. Hazardous decomposition products: Toxic metal fumes may form when heated to decomposition.

Section 11: Toxicological Information

Information on toxicological effects: Acute Toxicity: Oral - Rat LD 50 2689 mg/kg Inhalation - Rat LC50 > 5840 mg/m 3 /4H. Investigated as a tumorigen. Germ Cell Mutagenicity - Genotoxicity in vitro - Ames test - S. typhimurium - with and without metabolic activation - negative. Classification according to GHS (1272/2008/EG, CLP) Skin corrosion/irritation: Not classified based on available information. Serious eye damage/eye irritation: Causes serious eye damage. Symptoms include pain, redness, tearing, and corneal abrasion. Respiratory or skin sensitisation: Harmful if inhaled. Symptoms include coughing, sneezing, nasal discharge, headache, and hoarseness. Germ cell mutagenicity: Not classified based on available information. Carcinogenicity: Carcinogenicity - Rat – Inhalation. Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Lungs, Thorax, or Respiration: Tumors. Limited evidence of a carcinogenic effect. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as a probable, possible or confirmed human carcinogen by IARC.

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 6/10 NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Reproductive toxicity: Not classified based on available information. Specific target organ toxicity – single exposure (STOT): May cause respiratory irritation. Specific target organ toxicity (STOT) – repeated exposure: Not classified based on available information. Aspiration toxicity: Not classified based on available information.

Section 12: Ecological Information

Toxicity: Toxicity to fish: Static test LC 50 , Pimephales promelas , 577 mg/l, 96 hours. Toxicity to daphnia: Static test LC 50 , Daphnia magna , 206.8 mg/l, 48 hours and other aquatic invertebrates. Toxicity to Bacteria: Respiration inhibition EC 50, Sludge Treatment, 820 mg/l, 3 hours. Method: OECD Test Guideline 209 Persistence and degradability: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. 検索結果 of PBT& vPvB assessment: Not relevant. Other adverse effects: No data available.

Section 13: Disposal Considerations

Waste treatment methods: Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.

Section 14: Transport Information

DOT: Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (Molybdenum trioxide). Hazard Class : 6.1 UN Number: 3288 Packing Group: III EMS No.: F-A, S-A Marine Pollutant: No IMDG: Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (Molybdenum trioxide). Hazard Class : 6.1 UN Number: 3288 Packing Group: III EMS No.: F-A, S-A

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 7/10 Marine Pollutant: No IATA: Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (Molybdenum trioxide). Hazard Class : 6.1 UN Number: 3288 Packing Group: III EMS No.: F-A, S-A Marine Pollutant: No

Section 15: Regulatory Information

EU regulations: Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed. Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed. Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Not listed. Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed. Authorisations: Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed. Restrictions on use: Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Not listed. Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated.

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 8/10 Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding. Not regulated. Other EU regulations: Directive 2012/18/EU on major accident hazards involving dangerous substances Not listed. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Always applicable. Directive 94/33/EC on the protection of young people at work Not listed. Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. This 安全データシート complies with the requirements of Regulation (EC) No 1907/2006, as amended. OSHA Hazards: Target Organ Effect, Irritant, Carcinogen. SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components : The following components are subject to reporting levels established by SARA Title III, Section 313: CAS No. 1313-27-5 / 改訂版 Date 2007-07-01. SARA 311/312 Hazards : Acute Health Hazard, Chronic Health Hazard. Massachusetts Right to Know Components: CAS No. 1313-27-5 / 改訂版 Date 2007-07-01 Pennsylvania Right to Know Components: CAS No. 1313-27-5 / 改訂版 Date 2007-07-01 New Jersey Right to Know Components: CAS No. 1313-27-5 / 改訂版 Date 2007-07-01 California Prop. 65 Components: This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16: Other Inf ormation

List of abbreviations: ACGIH American Conference of Governmental Industrial Hygienists ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road ALARA As Low As Is Reasonably Achievable AMU Atomic Mass Unit ANSI American National Standards Institute BLS Basic Life Support CAM Continuous Air Monitor CAS Chemical Abstracts Service (division of the American Chemical Society) CEN European Committee for Standardization CERCLA Comprehensive Environmental Response Compensation and Liability Act CLP Classification, Labelling and Packaging (European Union) CPR Controlled Products Regulations (Canada) CWA Clean Water Act (USA) DAC Derived Air Concentration (USA) DOE 米国 Department of Energy (USA) DOT 米国 Department of Transportation (USA) DSL Domestic Substances List (Canada)

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 9/10 EC50 Half Maximal Effective Concentration EINECS European Inventory of Existing Commercial Chemical Substances EHS Environmentally Hazardous Substance ELINCS European List of Notified Chemical Substances EMS Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency (USA) EPCRA Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 GHS Globally Harmonized System HMIS Hazardous 材料 Identification System (USA) IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Containers ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life or Health IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent LDLO Lethal Dose Low LOEC Lowest-Observed-Effective Concentration MARPOL International Convention for the Prevention of Pollution from Ships MSHA Mine Safety and Health Administration (USA) NCRP National Council on Radiation Protection & Measurements (USA) NDSL Non-Domestic Substances List (Canada) NFPA National Fire Protection Association (USA) NIOSH National Institute for Occupational Safety and Health (USA) NOEC No Observed Effect Concentration N.O.S. Not Otherwise Specified NRC Nuclear Regulatory Commission (USA) NTP National Toxicology Program (USA) OSHA Occupational Safety and Health Administration (USA) PBT Persistent Bioaccumulative and Toxic Chemical PEL Permissible Exposure Limit PIH Poisonous by Inhalation Hazard RCRA Resource Conservation and Recovery Act (USA) RCT Radiation Control Technician REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (Europe) RID Regulations Concerning the International Transport of Dangerous Goods by Rail RTECS Registry of Toxic Effects of Chemical Substances SARA Superfund Amendments and Reauthorization Act (USA) TDG Transportation of Dangerous Goods (Canada) TIH Toxic by Inhalation Hazard TLV Threshold Limit Value TPQ Threshold Planning Quantity TSCA Toxic Substances Control Act TWA Time Weighted Average UN United Nations (Number) VOC Volatile Organic 化合物

安全データシート for Molybdenum Oxide, Enriched Molybdenum Oxide According to ISO 11014:2010 First Print Date: 5-Mar-2015 改訂版 Date: 16-Aug-2019 Version: 1.1.1. 安全データシート (SDS) for Molybdenum Trioxide, Enriched Molybdenum https://www.buyisotope.com ページ 10/10 vPvB Very Persistent Very Bioaccumulative Chemical WGK Wassergefährdungsklassen (ドイツ: Water Hazard Classes) WHMIS Workplace Hazardous 材料 Information System References: 情報なし. 全文 of any H-statements not written out in full under Sections 2 to 15: H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer. 改訂版 information: None. Training information: Follow training instructions when handling this material. Further Information: The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.