サマリウム(III) oxide ALFAA11229 SDS

ページ 1 / 7 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026 Version 5

ALFAA11229

Samarium(III) oxide

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 氧化钐氧化钐氧化钐氧化钐 Product 説明: Samarium(III) oxide

Cat No. : 11229 別名 Samaria; Samarium Sesquioxide; Samarium Trioxide CAS No 12060-58-1 Molecular Formula O3 Sm2

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Solid No information available Odorless

Emergency 概要 Air sensitive. Hygroscopic.

Classification of the substance or mixture Based on available data, the classification criteria are not met

Label 元素s

None required

Physical and Chemical Hazards Hygroscopic. Health Hazards The product contains no substances which at their given concentration are considered to be hazardous to health. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Is not likely mobile in the environment due its low water solubility. Spillage unlikely to penetrate soil.

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This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Samarium oxide (Sm2O3) 12060-58-1 99.9

SECTION 4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention.

Inhalation Remove from exposure, lie down. Remove to fresh air. Get medical attention.

Ingestion Clean mouth with water. Get medical attention.

Most important symptoms and effects No information available.

Self-Protection of the First Aider No special precautions required.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Water spray. Carbon dioxide (CO 2). Dry chemical. Chemical foam.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation.

Environmental Precautions See Section 12 for additional Ecological Information.

Methods for Containment and Clean Up ______________________________________________________________________________________________ ページ 2

ALFAA11229 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026ページ 3 / 7 Samarium(III) oxide ______________________________________________________________________________________________ Sweep up and shovel into suitable containers for disposal.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Avoid contact with skin and eyes. Do not breathe dust. Handle product only in closed system or provide appropriate exhaust ventilation.

Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures None under normal use conditions. .

Personal protective equipment

Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Neoprene See manufacturers - EN 374 (minimum requirement) recommendations Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure

Respiratory Protection No protective equipment is needed under normal use conditions.

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced おすすめ 絞り込み type: Particle filter

Small scale/Laboratory use Maintain adequate ventilation おすすめ half mask:- Valve filtering: EN405; or; Half mask: EN140; plus filter, EN 141

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Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Physical State Solid

Odor Odorless Odor Threshold No data available pH No data available . 8 10 g/L aq.sol Melting Point/Range 2325 °C / 4217 °F Softening Point No data available Boiling Point/Range No information available Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No data available Vapor Density Not applicable Solid Specific Gravity / Density 8.347 Bulk Density No data available Water Solubility Insoluble Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

Molecular Formula O3 Sm2 Molecular Weight 348.7

SECTION 10. STABILITY AND REACTIVITY

Stability Stable under normal conditions. Air sensitive. Hygroscopic.

Hazardous Reactions No information available. Hazardous Polymerization No information available.

Conditions to Avoid Incompatible products. Exposure to moist air or water.

材料 to avoid Acids. Strong oxidizing agents. Carbon dioxide (CO2).

Hazardous Decomposition Products None under normal use conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information No acute toxicity information is available for this product

(a) acute toxicity; Component LD50 Oral LD50 Dermal LC50 Inhalation ______________________________________________________________________________________________ ページ 4

ALFAA11229 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026ページ 5 / 7 Samarium(III) oxide ______________________________________________________________________________________________ Samarium oxide (Sm2O3) LD50 > 5 g/kg ( Rat )

(b) skin corrosion/irritation; No data available

(c) serious eye damage/irritation; No data available

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs No information available.

(j) aspiration hazard; Not applicable Solid

Other Adverse Effects The toxicological properties have not been fully investigated.

Symptoms / effects,both acute and No information available delayed

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Contains no substances known to be hazardous to the environment or that are not degradable in waste water treatment plants.

Persistence and Degradability Persistence Insoluble in water.

Bioaccumulative Potential May have some potential to bioaccumulate

Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water solubility

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

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SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Chemical waste generators must determine whether a discarded chemical is classified as a Products hazardous waste. Consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Contaminated Packaging Empty remaining contents. Dispose of in accordance with local regulations. Do not re-use empty containers.

Other Information Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport Not Regulated

IMDG/IMO Not regulated

IATA Not regulated

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Samarium oxide - - X 235-043-6 X X - X X X KE-30864 (Sm2O3)

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department 改訂版 Date 27-Jul-2026 改訂版 Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene.

Legend

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ALFAA11229 SAFETY DATA SHEET 改訂版 Date 27-Jul-2026ページ 7 / 7 Samarium(III) oxide ______________________________________________________________________________________________ CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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