テルビウム powder (99.9% REO) 93-6515 SDS

ページ 1/7 Safety data sheet according to 1907/2006/EC, Article 31

Printing date 21.07.2021 改訂版: 21.07.2021

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier

· 商品名： Terbium powder (99.9% REO)

· Item number: 93-6515 · CAS番号: 7440-27-9 · EC number: 231-137-6 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available.

· 1.3 詳細 of the supplier of the safety data sheet · メーカー/供給元: Strem Chemicals, Inc. 7 Mulliken Way NEWBURYPORT, MA 01950 USA info@strem.com

· Further information obtainable from: Technical Department · 1.4 Emergency telephone number: EMERGENCY: CHEMTREC: + 1 (800) 424-9300 During normal opening times: +1 (978) 499-1600

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008

GHS02 flame d~ Flam. Sol. 1 H228 Flammable solid.

· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. · Hazard pictograms d~ GHS02

· Signal word Danger · Hazard statements H228 Flammable solid. · Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P231 Handle under inert gas. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P222 Do not allow contact with air. P280 Wear protective gloves/protective clothing/eye protection/face protection. P232 Protect from moisture. (Contd. on page 2) GB

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ページ 2/7 Safety data sheet according to 1907/2006/EC, Article 31

Printing date 21.07.2021 改訂版: 21.07.2021

商品名： Terbium powder (99.9% REO)

(Contd. of page 1) P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards · 検索結果 of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

SECTION 3: 組成/information on ingredients

· 3.1 Chemical characterisation: Substances · CAS No. 説明 7440-27-9 none · Identification number(s) · EC number: 231-137-6

SECTION 4: First aid measures

· 4.1 説明 of first aid measures · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Generally the product does not irritate the skin. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media · Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: No special measures required.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: No special measures required. · 6.3 Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling No special precautions are necessary if used correctly. (Contd. on page 3) GB

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ページ 3/7 Safety data sheet according to 1907/2006/EC, Article 31

Printing date 21.07.2021 改訂版: 21.07.2021

商品名： Terbium powder (99.9% REO)

(Contd. of page 2)

· Handling: Handle under inert gas. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges.

· 7.2 Conditions for safe storage, including any incompatibilities · Storage: Store contents under inert gas. · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles. · 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.

· 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: Not required. · Additional information: The lists valid during the making were used as basis.

· 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: Wash hands before breaks and at the end of work. · Respiratory protection: Not required. · Protection of hands:

Protective gloves _S

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses

· 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Powder Colour: Grey · Odour: Odourless · Odour threshold: Not determined.

· pH-value: Not applicable.

· Change in condition Melting point/freezing point: 1.360 °C

(Contd. on page 4) GB

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ページ 4/7 Safety data sheet according to 1907/2006/EC, Article 31

Printing date 21.07.2021 改訂版: 21.07.2021

商品名： Terbium powder (99.9% REO)

(Contd. of page 3)

Initial boiling point and boiling range: 3.041 °C

· Flash point: Not applicable.

· Flammability (solid, gas): Flammable.

· Ignition temperature:

Decomposition temperature: Not determined.

· Auto-ignition temperature: Not determined.

· Explosive properties: Not determined.

· Explosion limits: Lower: Not determined. Upper: Not determined.

· Vapour pressure: Not applicable.

· Density at 20 °C: 8.234 g/cm³ · Relative density Not determined. · Vapour density Not applicable. · Evaporation rate Not applicable.

· Solubility in / Miscibility with water: Insoluble.

· Partition coefficient: n-octanol/water: Not determined.

· Viscosity: Dynamic: Not applicable. Kinematic: Not applicable.

· Solvent content: Organic solvents: 0.0 % VOC (EC) 0.00 %

Solids content: 100.0 % · 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known. · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · Primary irritant effect: · Skin corrosion/irritation Based on available data, the classification criteria are not met. · Serious eye damage/irritation Based on available data, the classification criteria are not met. (Contd. on page 5) GB

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ページ 5/7 Safety data sheet according to 1907/2006/EC, Article 31

Printing date 21.07.2021 改訂版: 21.07.2021

商品名： Terbium powder (99.9% REO)

(Contd. of page 4) · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity · Aquatic toxicity: No further relevant information available. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Not known to be hazardous to water. · 12.5 検索結果 of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number · ADR, IMDG, IATA UN3089

· 14.2 UN proper shipping name · ADR 3089 METAL POWDER, FLAMMABLE, N.O.S. · IMDG, IATA METAL POWDER, FLAMMABLE, N.O.S.

· 14.3 Transport hazard class(es)

· ADR dhc`gy

· Class 4

(Contd. on page 6) GB

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ページ 6/7 Safety data sheet according to 1907/2006/EC, Article 31

Printing date 21.07.2021 改訂版: 21.07.2021

商品名： Terbium powder (99.9% REO)

(Contd. of page 5)

· Label 4.1

· IMDG, IATA dhc`gy

· Class 4.1 Flammable solids, self-reactive substances and solid desensitised explosives. · Label 4.1

· 14.4 Packing group · ADR, IMDG, IATA II

· 14.5 Environmental hazards: · Marine pollutant: No

· 14.6 Special precautions for user Not applicable. · Segregation groups Heavy metals and their salts (including their organometallic compounds), powdered metals · Stowage Category B · Handling Code H1 Keep as dry as reasonably practicable · Segregation Code SG17 Stow "separated from" class 5.1 SG25 Stow "separated from" goods of classes 2.1 and 3. SG26 In addition: from goods of classes 2.1 and 3 when stowed on deck of a containership a minimum distance of two container spaces athwartship shall be maintained, when stowed on ro-ro ships a distance of 6 m athwartship shall be maintained.

· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable.

· Transport/Additional information:

· ADR · Limited quantities (LQ) 1 kg · Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g

· IMDG · Limited quantities (LQ) 1 kg · Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g

· UN "Model Regulation": UN 3089 METAL POWDER, FLAMMABLE, N.O.S., 4.1, II

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

· Directive 2012/18/EU · Named dangerous substances - ANNEX I Substance is not listed. (Contd. on page 7) GB

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ページ 7/7 Safety data sheet according to 1907/2006/EC, Article 31

Printing date 21.07.2021 改訂版: 21.07.2021

商品名： Terbium powder (99.9% REO)

(Contd. of page 6) · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Department issuing SDS: Technical Department. · Contact: Technical Director · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic 化合物s (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Flam. Sol. 1: Flammable solids – Category 1 GB

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