ツリウム (III) Chloride Heptahydrate 3599 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Thulium (III) Chloride Heptahydrate

PRODUCT NUMBER: 3599

CAS NUMBER: 13778-39-7

SYNONYMS: Thulium trichloride heptahydrate

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Warning

Hazard Statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.

Precautionary Phrases

P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse.

HMIS CLASSIFICATION: Health: 1 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 1 Flammability: 0 Reactivity Hazard: 0

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SECTION 2 HAZARDS IDENTIFICATION (Cont.)

EYE CONTACT: May cause irritation to the eyes. SKIN CONTACT: May cause irritation to the skin. INHALATION: May cause irritation to the respiratory tract. INGESTION: No information is available on the physiological effects of ingestion.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: TmCl3 Ÿ 7H2O

Molecular Weight: 401.40

CHEMICAL NAME CAS# %

Thulium Chloride Heptahydrate 12056-07-4 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with plenty of water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. 閉じるly monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Product is not flammable, AUTO IGNITION TEMPERATURE: 情報なし EXPLOSION LIMITS: Product does not present an explosion hazard. EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen chloride gas and thulium chloride.

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid dust formation. Avoid breathing dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND 材料名S FOR CONTAINMENT AND CLEANING UP: Mix spills with vermiculite or sodium carbonate. Sweep up and place in suitable container for proper disposal.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Ensure adequate ventilation. Avoid contact with skin and eyes. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area.

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SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: Light green solid ODOR: None MOLECULAR WEIGHT: 401.40 BOILING POINT: No data available MELTING POINT: 824° C SPECIFIC GRAVITY: No data available VAPOR DENSITY: No data available SOLUBILITY: Very soluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Moisture INCOMPATIBILITY: Strong oxidizing agents, strong acids, and strong bases. DECOMPOSITION PRODUCTS: Hydrogen chloride gas and thulium chloride.

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: 情報なし CARCINOGENIC EFFECTS: No component of this product present at levels greater than or equal to 0.1% is considered to be a human carcinogen. MUTAGENIC EFFECTS: 情報なし TETRATOGENIC EFFECTS: 情報なし CHRONIC TOXICITY: 情報なし RTECS: No data

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No information available

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good.

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SECTION 15 REGULATORY INFORMATION

TSCA: Not listed in the TSCA Inventory

SARA (TITLE 313): Not listed

SARA 311/312: Acute Health Hazard

MASSACHUSETTS RIGHT TO KNOW: Not listed

PENNSLVANIA RIGHT TO KNOW: Thulium (III) Chloride Heptahydrate

NEW JERSEY RIGHT TO KNOW: Thulium (III) Chloride Heptahydrate

CALIFORNIA PROP. 65: Not Listed

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 06/15 SDS DEPT.

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