Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III) GD8151 SDS

Ereztech GD8151 ページ 1 of 12 改訂版: 1.10 Date of Issue: 4/18/2020 EREZTECH LLC 11555 Medlock Bridge Road, Suite 100, Johns Creek, GA 30097, USA T: +1.888.658.1221 F: 1.678.619.2020 E: info@ereztech.com W: https://ereztech.com

Product Name: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III) Product 種類: Solid CAS番号: 14768-15-1 Product Number: GD8151 Product メーカー: Ereztech LLC 11555 Medlock Bridge Road, Suite 100 Johns Creek, GA 30097 Product Information: (888) 658-1221 In Case of an Emergency: CHEMTREC: 1-800-424-9300 (USA); +1 703-527-3887 (International); CCN836180 *** Contact manufacturer for all non-emergency calls.

Appearance/Odor: Off-white crystals, odor not determined. Classification: SKIN CORROSION/IRRITATION - Category 2, H315 SERIOUS EYE DAMAGE/IRRITATION - Category 2A, H319 SPECIFIC ORGAN TOXICITY, SINGLE EXPOSURE; RESPIRATORY TRACT IRRITATION - Category 3, H335 GHS Label 元素s Hazard Pictograms: Signal Word: WARNING Hazard Statements: H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation. Precautionary Statements Prevention: P261: Avoid breathing fumes/gas/mist/vapors/spray. P264: Wash exposed skin thoroughly after handling. P271: Use only outdoors or in a well ventilated area.

Section 2. Hazards Identification

Section 1. Identification

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Prevention (cont.): P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P332 + P313: If skin irritation occurs: Get medical advice/attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. Storage: P403 + P233: Store in a well ventilated place. Keep container tightly closed. P405: Store locked up. Disposal: P501: Dispose of contents/ container to an approved wasted disposal plant. General: None. OSHA/HCS 状態: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards Not Otherwise None identified. Classified (HNOC): Substances Formula : C33H57GdO6 Molecular Weight : 707.05 CAS-No. : 14768-15-1 EC-No. : 238-834-4 Ingredient Name % CAS番号 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III) /g149 98 14768-15-1 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.

Section 3. 組成/Information on Ingredients

Section 2. Hazards Identification

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説明 of Necessary First Aid Measures General Advice: Move out of dangerous area. Call a POISON CENTER or doctor/physician immediately if symptoms develop or if you feel unwell. Show this safety data sheet to the doctor in attendance. Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue rinsing. Seek medical attention if eye irritation develops and persists. Skin Contact: Take off contaminated clothing and shoes immediately. Wash off contaminated skin with soap and plenty of water. Seek medical attention if irritation develops and persists, if symptoms develop or if you feel unwell. Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Call a physician or POISON CONTROL CENTER if symptoms develop or if you feel unwell. Ingestion: Rinse mouth. Do NOT induce vomiting. Remove dentures if any. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Call a physician or POISON CONTROL CENTER if symptoms develop or if you feel unwell. Most Important Symptoms/Effects, Acute and Delayed Potential Acute Health Effects Eye Contact: Symptoms may include stinging, tearing, redness, swelling and blurred vision. Inhalation: Product may be irritating to respiratory system. Symptoms may include coughing, sneezing with phlegm production, sore throat, nausea, headache, vomiting. Skin Contact: Symptoms may include an itching or burning sensation, reddening, swelling and blistering with tissue necrosis. Ingestion: Product may be expected to be irritating to mucous membranes. Symptoms may include cramping, localized pain, headache, nausea and vomiting. Indication of Immediate Medical Attention and Special Treatment Needed, If Necessary Notes to Physician: Treat symptomatically. Specific Treatments: No specific treatment. Protection of First Responders: No action taken shall be taken involving any personal risk without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See Toxicological Information (Section 11)

Section 4. First Aid Measures

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General Hazards: None identified. Suitable Extinguishing Media: Use water spray, alcohol resistant foam, dry chemical or carbon dioxide (CO2). Unsuitable Extinguishing Media: None identified. Unusual Fire and Explosion None identified. Hazards: Product of Combustion: Decomposition products may include irritating fumes, organic acid vapors, carbon oxides (COx) and gadolinium oxides. Protection of Firefighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protection equipment and self-contained breathing apparatus (SCBA) with a full face- piece operated in a positive pressure mode. Personal Precautions, Protective Equipment and Emergency Procedures For Non-Emergency Personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid inhalation of vapors or mist. Provide adequate ventilation. Wear respiratory protection. Put on appropriate personal protective equipment. For Emergency Responders: If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For Non-Emergency Personnel". Environmental Precautions: Do not allow dispersal of spilled material and contact with waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways or air). Methods for Containment General: Move containers from spill area if safe to do so. Avoid the formation and inhalation of dusts and aerosols. Small Spill: Contain and collect spillage with a dry binding material (e.g. sand, earth, vermiculite or diatomaceous earth) and place in dry, sealed container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Section 6. Accidental Release Measures

Section 5. Fire Fighting Measures

Ereztech GD8151 ページ 5 of 12 改訂版: 1.10 Date of Issue: 4/18/2020 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III) 安全データシート Large Spill: Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with a dry binding material (e.g. sand, earth, vermiculite or diatomaceous earth) and place in dry, sealed container for disposal according to local regulations (see

Section 13). Dispose of via a licensed waste disposal

contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and

Section 13 for waste disposal.

Precautions: Product is moisture sensitive; handle under a dry, inert gas. Nitrogen with less than 5 ppm each of moisture and oxygen is recommended. Avoid formation and inhalation of dusts and aerosols. Keep container tightly sealed. Avoid contact with skin, eyes and clothing. Do not ingest. Avoid prolonged exposure. Ensure adequate ventilation. Protective Measures: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep in the original container kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. General Occupational Hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Safe Storage Conditions: Product is moisture sensitive; store under an inert gas. Nitrogen with less than 5 ppm each of moisture and oxygen is recommended. Store in original container protected from direct sunlight in a dry and well-ventilated area, away from incompatible materials and food and drink. Keep container tightly closed and sealed until ready for use. Store locked up.

Section 6. Accidental Release Measures

Section 7. Handling and Storage

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Introductory Remarks: These recommendations provide general guidance for handling this product. Because work environments and material handling practices vary, safety procedures should be developed for each intended application. While developing safe handling procedures, do not overlook the need to clean equipment and conduct regular repairs. Waste from these procedures should be handled in accordance with Section 13. Occupational Exposure Limits: No exposure limits noted for this material. Engineering Controls: Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute. Provide an eyewash/shower station. Environmental Exposure Controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual Protection Measures Hygiene Measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Remove all soiled and contaminated clothing immediately. Do not inhale dusts produced by product. Avoid contact with eyes and skin. Ensure that eyewash stations and safety showers are close to the workstation/g182s location. Eye/Face Protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles, faceshield (8-inch minimum). Refer to 29 CFR 1910.133, ANSI Z87.1, or European Standard EN166. Skin Protection Hand Protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties.

Section 8. Exposure Controls/Personal Protection

Ereztech GD8151 ページ 7 of 12 改訂版: 1.10 Date of Issue: 4/18/2020 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III) 安全データシート Hand Protection (cont.): It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: Chemical-resistant gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. For full contact, wear Neoprene or nitrile rubber gloves. Other Skin Protection: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Physical State: Solid, crystals. Color: Off-white. Odor: Not determined. Odor Threshold: No data available. pH: No data available. Melting Point: 182-184 /g131C (360-363 /g131F). Boiling Point: No data available. Flash Point: No data available. Auto-ignition temperature: No data available. Specific Gravity: No data available. Vapor Pressure: No data available. Water Solubility: Insoluble. Product hydrolyzes slowly when exposed to water.

Section 9. Physical and Chemical Properties

Section 8. Exposure Controls/Personal Protection

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Reactivity: Product hydrolyzes slowly when exposed to water. Chemical Stability: This product is stable when stored under a dry, inert atmosphere and away from heat. Nitrogen containing less than 5 ppm each moisture and air is recommended. This product is not sensitive to impact. Conditions to Avoid: Exposure to water/moisture. Incompatible 材料: Water, compounds containing active hydrogen (alcohols, acids) and strong oxidizing agents. Hazardous Decomposition Products: Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous decomposition products formed under fire conditions: irritating fumes, organic acid vapors, carbon oxides (CO x) and gadolinium oxides. In the event of a fire: see section 5. Possibility of Hazardous Reactions: Under normal conditions of storage and use, hazardous reactions will not occur. Hazardous reactions or instability may occur under certain conditions of storage or use.

Information on Toxicological Effects Acute Toxicity : No specific data available. Irritation/Corrosion : Product causes skin irritation and serious eye irritation. Sensitization : No specific data available. Germ Cell Mutagenicity : No effects known. Carcinogenity IARC : No component of this product present at levels greater than 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH : No component of this product present at levels greater than 0.1% is identified as probable, possible or confirmed human carcinogen by ACGIH. NTP : No component of this product present at levels greater than 0.1% is identified as probable, possible or confirmed human carcinogen by NTP. OSHA : No component of this product present at levels greater than 0.1% is identified as probable, possible or confirmed human carcinogen by OSHA. Reproductive Toxicity : No specific data available. Teratogenicity : No specific data available.

Section 11. Toxicological Information

Section 10. Stability and Reactivity

Ereztech GD8151 ページ 9 of 12 改訂版: 1.10 Date of Issue: 4/18/2020 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III) 安全データシート Specific Target Organ Toxicity : Respiratory tract irritation. (Single Exposure) Specific Target Organ Toxicity : No specific data available. (Repeated Exposure) Aspiration Hazard : No specific data available. Information on the Likely : Common routes of exposure: inhalation (failure to Routes of Exposure prevent dust formation), dermal (failure to use skin protection), eye (failure to use safety eyewear). Less common: ingestion (failure to employ recommended hygiene measures (e.g. smoking after handling product without washing hands or using hand protection). Additional Information : To the best of our knowledge, the chemical, physical and toxicological properties of this product have not been thoroughly investigated.

Numerical Measures of Toxicity Toxicity to Fish : No specific data available. Toxicity to Daphnia and Other : No specific data available. Aquatic Invertebrates Toxicity to Algae : No specific data available. Persistence and Degradability Biodegradability : No specific data available. Bioaccumulative Potential : No specific data available. Mobility in Soil : No specific data available. Other Adverse Effects : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

Waste Treatment Methods Product Dispose of in accordance with local, state, and federal regulations. Refer to 40 CFR 260-299 for complete waste disposal regulations. Consult your local, state, or federal agency before disposing of any chemicals. Contaminated Packaging Empty containers retain product residue (dust) and can be dangerous. Dispose of as unused product.

Section 11. Toxicological Information

Section 13. Disposal Considerations

Section 12. Ecological Information

Ereztech GD8151 ページ 10 of 12 改訂版: 1.10 Date of Issue: 4/18/2020 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)gadolinium(III) 安全データシート DOT IMDG IATA UN Number Not regulated Not regulated Not regulated UN Proper Shipping Name - - - Transport Hazard Classes - - - Packing Group - - - Environmental Hazards - - - Additional Information - - - Special Precautions for User : Transport within user/g182s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transporting in Bulk According : Not applicable. to Annex II of MARPOL 73/78 and the IBC Code TSCA (Toxic Substance Control Act): This product is not listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory). Use of this product is restricted to research and development only. This product must be used under the supervision of a technically qualified individual as defined by the TSCA. This product must not be used for commercial purposes or in formulations for commercial purposes. SARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Acute Health Hazard (Skin corrosion or irritation; Serious eye damage or eye irritation; Specific Target Organ Toxicity (STOT), single exposure: respiratory irritation). Massachusetts Right to Know Components No components are subject to the Massachusetts Right to Know Act. Pennsylvania Right to Know Components No components are subject to the Pennsylvania Right to Know Act. New Jersey Right to Know Components No components are subject to the New Jersey Right to Know Act. California Proposition 65 Components This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 14. Transport Information

Section 15. Regulatory Information

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National Fire Protection Association (U.S.A.)

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of 材料 for Emergency Response Copyright /g1391997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright /g1392001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. HMIS Rating HEALTH 2 FLAMMABILITY 0 PHYSICAL HAZARD 0 History Date of Printing : 4/18/2020 Date of Issue/Date of 改訂版 : 4/18/2020 Date of 前へ Issue : 7/16/18 References : None available Abbreviations and Acronyms ACGIH: American Conference of Governmental Industrial Hygienists. ATE: Acute Toxicity Estimate CAS: Chemical Abstracts Service (division of the American Chemical Society). DOT: US Department of Transportation. GHS: Globally Harmonized System of Classification and Labeling of Chemicals. HMIS: Hazardous 材料 Identification System. HNOC: Hazards Not Otherwise Classified. IARC: International Agency for Research on Cancer. IATA: International Air Transport Association.

Section 16. Other Information

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Abbreviations and Acronyms (cont.) IDLH: Immediately Dangerous to Life or Health (US National Institute for Occupation Health and Safety (NIOSH)). IMDG: International Maritime Code for Dangerous Goods. NFPA: National Fire Protection Association. NIOSH: National Institute of Occupational Safety and Health. NTP: National Toxicology Program. OSHA: Occupational Safety and Health Administration. PEL: Permissible Exposure Limits. REL: おすすめ Exposure Limits. SARA: Superfund Amendments and Reauthorization Act. STOT: Specific Target Organ Toxicity. TLV: Threshold Limit Values (ACGIH). TWA: Time Weighted Average. VOC: Volatile Organic 化合物.

Disclaimer The information herein is believed to be accurate and is presented in good faith; however, no warranties or representations are made by Ereztech LLC regarding the accuracy or completeness of the information. Ereztech LLC shall not be liable for any damages resulting from the handling, or from the contact with the above product. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Section 16. Other Information