Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD 64-3575 SDS

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Printing date 07/18/2021 Reviewed on 07/18/2021

1 化学品および会社情報

· 製品名

· 商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

· Item number: 64-3575 · CAS番号: 1034537-36-4

· 詳細 of the supplier of the safety data sheet · メーカー/供給元: Strem Chemicals, Inc. 7 Mulliken Way NEWBURYPORT, MA 01950 USA info@strem.com

· Information department: Technical Department · Emergency telephone number: EMERGENCY: CHEMTREC: + 1 (800) 424-9300 During normal opening times: +1 (978) 499-1600

2 危険有害性の要約

· Classification of the substance or mixture

GHS05 Corrosion d~ Skin Corr. 1B H314 Causes severe skin burns and eye damage.

GHS07 d~ Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H335 May cause respiratory irritation.

· Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms d~ d~ GHS05 GHS07

· Signal word Danger · Hazard statements H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. · Precautionary statements P231 Handle under inert gas. P262 Do not get in eyes, on skin, or on clothing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P422 Store contents under inert gas. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 2) US

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 1) · Classification system: · NFPA ratings (scale 0 - 4)

Health = 4

2 Fire = 2

4 0 Reactivity = 0

· HMIS-ratings (scale 0 - 4)

HEALTH 4 Health = 4 FIRE 2 Fire = 2 REACTIVITY 0 Reactivity = 0

· Other hazards · 検索結果 of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

3 組成・成分情報

· Chemical characterization: Substances · CAS No. 説明 242751-48-1 Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD · Chemical characterization: 混合物s · 説明: 混合物 of the substances listed below with nonhazardous additions.

· Dangerous components: not applicable

4 応急措置

· 説明 of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 火災時の措置

· Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: No special measures required. US (Contd. on page 3)

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 2)

6 漏出時の措置

· Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · Environmental precautions: No special measures required. · Methods and material for containment and cleaning up: Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. · Protective Action Criteria for Chemicals · PAC-1: None of the ingredients is listed.

· PAC-2: None of the ingredients is listed.

· PAC-3: None of the ingredients is listed.

7 取扱い・保管上の注意

· Handling: · Precautions for safe handling Thorough dedusting. 開く and handle receptacle with care. · Information about protection against explosions and fires: No special measures required.

· Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. · Specific end use(s) No further relevant information available.

8 ばく露防止・保護措置

· Additional information about design of technical systems: No further data; see item 7.

· Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis.

· Exposure controls · Personal protective equipment: Wear protective clothing · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. (Contd. on page 4) US

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 3) Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. · Breathing equipment: A NIOSH approved respirator in accordance with 29 CFR 1910.134. · Protection of hands:

Protective gloves _S

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection:

Tightly sealed goggles _R

9 物理的・化学的性質

· Information on basic physical and chemical properties · General Information · Appearance: Form: Powder Color: Whitish · Odor: Odorless · Odor threshold: Not determined.

· pH-value: Not applicable.

· Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 0 °C (32 °F)

· Flash point: 0 °C (32 °F)

· Flammability (solid, gaseous): Not determined.

· Ignition temperature:

Decomposition temperature: Not determined.

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

(Contd. on page 5) US

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 4)

· Explosion limits: Lower: Not determined. Upper: Not determined.

· Vapor pressure: Not applicable.

· Density: Not determined. · Relative density Not determined. · Vapor density Not applicable. · Evaporation rate Not applicable.

· Solubility in / Miscibility with Water: Insoluble.

· Partition coefficient (n-octanol/water): Not determined.

· Viscosity: Dynamic: Not applicable. Kinematic: Not applicable.

· Solvent content: Organic solvents: 0.0 % VOC content: 0.0 g/l / 0.00 lb/gl · Other information No further relevant information available.

10 安定性・反応性

· Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known.

11 有害性情報

· Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: Caustic effect on skin and mucous membranes. · on the eye: Strong caustic effect. Irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Corrosive Irritant Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. (Contd. on page 6) US

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 5)

· Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed.

· NTP (National Toxicology Program) None of the ingredients is listed.

· OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

12 環境影響情報

· Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Must not reach bodies of water or drainage ditch undiluted or unneutralized. · 検索結果 of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

13 廃棄上の注意

· Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

· Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.

14 輸送上の注意

· UN-Number · DOT, IMDG, IATA UN3263

· UN proper shipping name · DOT Corrosive solid, basic, organic, n.o.s. (Lanthanum tris(formamidinate)) · IMDG, IATA CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Lanthanum tris(formamidinate))

(Contd. on page 7) US

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 6)

· Transport hazard class(es)

· DOT dc`oa}y

· Class 8 Corrosive substances · Label 8

· IMDG, IATA dc`oa}

· Class 8 Corrosive substances · Label 8

· Packing group · DOT, IMDG, IATA II

· Environmental hazards: · Marine pollutant: No

· Special precautions for user Warning: Corrosive substances · EMS Number: F-A,S-B · Segregation groups Alkalis · Stowage Category B · Segregation Code SG35 Stow "separated from" acids.

· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information:

· IMDG · Limited quantities (LQ) 1 kg · Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g

· UN "Model Regulation": UN 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (LANTHANUM TRIS(FORMAMIDINATE)), 8, II

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed.

· Section 313 (Specific toxic chemical listings): None of the ingredients is listed. (Contd. on page 8) US

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 7) · TSCA (Toxic Substances Control Act): This product is in compliance with the rules, regulations, and/or orders of TSCA and should be used in the accordance with the LVE (Low Volume Exemptions) regulations of TSCA. None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed.

· Chemicals known to cause developmental toxicity: None of the ingredients is listed.

· Carcinogenic categories · EPA (Environmental Protection Agency) None of the ingredients is listed.

· TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed.

· NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms d~ d~ GHS05 GHS07

· Signal word Danger · Hazard statements H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. · Precautionary statements P231 Handle under inert gas. P262 Do not get in eyes, on skin, or on clothing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P422 Store contents under inert gas. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 その他の情報

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Department issuing SDS: Technical Department. (Contd. on page 9) US

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商品名： Tris(N,N'-di-i-propylformamidinato)gadolinium(III), Gd-FMD

(Contd. of page 8) · Contact: Technical Director · Date of preparation / last revision 07/18/2021 / - · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous 材料 Identification System (USA) VOC: Volatile Organic 化合物s (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: おすすめ Exposure Limit Skin Corr. 1B: Skin corrosion/irritation – Category 1B Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 US

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