イットリウム(III) nitrate hexahydrate ALFAA12898 SDS

ページ 1 / 8 SAFETY DATA SHEET Creation Date 01-May-2012 改訂版 Date 26-Jul-2026 Version 5

ALFAA12898

Yttrium(III) nitrate hexahydrate

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 六水合硝酸钇(III)六水合硝酸钇(III)六水合硝酸钇(III)六水合硝酸钇(III) Product 説明: Yttrium(III) nitrate hexahydrate

Cat No. : 12898 別名 Nitric acid, yttrium(3+) salt, hexahydrate; Yttrium nitrate hexahydrate (1:3:6) CAS No 13494-98-9 Molecular Formula N3 O9 Y . 6 H2 O

供給元 Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, 英国 Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

おすすめ Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Solid White Odorless

Emergency 概要 May intensify fire; oxidizer. Harmful if swallowed. Causes serious eye irritation. Very toxic to aquatic life with long lasting effects. Hygroscopic.

Classification of the substance or mixture

Oxidizing solids Category 2 Acute Oral Toxicity Category 4 Serious Eye Damage/Eye Irritation Category 2 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1

Label 元素s

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Signal Word Danger

Hazard Statements H272 - May intensify fire; oxidizer H302 - Harmful if swallowed H319 - Causes serious eye irritation H410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements Prevention P264 - Wash face, hands and any exposed skin thoroughly after handling P280 - Wear eye protection/ face protection P270 - Do not eat, drink or smoke when using this product Response P330 - Rinse mouth P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention Storage P403 - Store in a well-ventilated place Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Oxidizing. Contact with combustible material may cause fire. Hygroscopic. Health Hazards Harmful if swallowed. Causes serious eye irritation. Environmental hazards Very toxic to aquatic life with long lasting effects. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems.

Other Hazards

This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Nitric acid, yttrium(3+) salt, hexahydrate 13494-98-9 >95 Nitric acid, yttrium(3+) salt 10361-93-0 -

SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

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ALFAA12898 SAFETY DATA SHEET 改訂版 Date 26-Jul-2026ページ 3 / 8 Yttrium(III) nitrate hexahydrate ______________________________________________________________________________________________ Most important symptoms and effects None reasonably foreseeable.

Self-Protection of the First Aider Use personal protective equipment as required.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Water spray, carbon dioxide (CO2), dry chemical, alcohol-resistant foam.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Do not allow run-off from fire-fighting to enter drains or water courses.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust formation.

Environmental Precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained.

Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Do not store near combustible materials.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Component 中国 ACGIH TLV OSHA PEL NIOSH

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ALFAA12898 SAFETY DATA SHEET 改訂版 Date 26-Jul-2026ページ 4 / 8 Yttrium(III) nitrate hexahydrate ______________________________________________________________________________________________ Nitric acid, yttrium(3+) salt, - TWA: 1 mg/m3 IDLH: 500 mg/m3 hexahydrate REL = 1 mg/m3 (TWA) Nitric acid, yttrium(3+) salt - TWA: 1 mg/m3 IDLH: 500 mg/m3 REL = 1 mg/m3 (TWA)

Legend

ACGIH - American Conference of Governmental Industrial Hygienists NIOSH: NIOSH - National Institute for Occupational Safety and Health

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection Wear safety glasses with side shields (or goggles) Goggles (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced おすすめ 絞り込み type: Particulates filter conforming to EN 143

Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. おすすめ half mask:- Particle filtering: EN149:2001 When RPE is used a face piece Fit Test should be conducted

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls Prevent product from entering drains. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained.

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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance White Physical State Solid

Odor Odorless Odor Threshold No data available pH No information available Melting Point/Range No data available Softening Point No data available Boiling Point/Range No information available Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No data available Vapor Density Not applicable Solid Specific Gravity / Density 2.68 Bulk Density No data available Water Solubility Soluble Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties Oxidizer

Molecular Formula N3 O9 Y . 6 H2 O Molecular Weight 383.01

SECTION 10. STABILITY AND REACTIVITY

Stability Stable under normal conditions. Hygroscopic.

Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur.

Conditions to Avoid Incompatible products. Combustible material. Excess heat. Avoid dust formation. Exposure to moist air or water.

材料 to avoid Combustible material. Strong acids. Strong reducing agents.

Hazardous Decomposition Products Nitrogen oxides (NOx).

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity; Component LD50 Oral LD50 Dermal LC50 Inhalation Nitric acid, yttrium(3+) salt 1650 mg/kg ( Rat ) LD50 > 2000 mg/kg ( Rat )

(b) skin corrosion/irritation; No data available

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(c) serious eye damage/irritation; Category 2

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

The table below indicates whether each agency has listed any ingredient as a carcinogen

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs No information available.

(j) aspiration hazard; Not applicable Solid

Other Adverse Effects The toxicological properties have not been fully investigated.

Symptoms / effects,both acute and No information available delayed

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment.

Persistence and Degradability Persistence Soluble in water, Persistence is unlikely, based on information available. Degradability Not relevant for inorganic substances. Degradation in sewage Contains substances known to be hazardous to the environment or not degradable in waste treatment plant water treatment plants.

Bioaccumulative Potential Bioaccumulation is unlikely

Mobility in soil The product is water soluble, and may spread in water systems Will likely be mobile in the environment due to its water solubility Highly mobile in soils

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

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Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations. Should not be released into the environment.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point.

Other Information Do not flush to sewer. Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains. Do not let this chemical enter the environment.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN3077 Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Technical Shipping Name Nitric acid, yttrium(3+) salt, hexahydrate Hazard Class 9 Packing Group III

IMDG/IMO

UN-No UN3077 Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Technical Shipping Name Nitric acid, yttrium(3+) salt, hexahydrate Hazard Class 9 Packing Group III

IATA

UN-No UN3077 Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Technical Shipping Name Nitric acid, yttrium(3+) salt, hexahydrate Hazard Class 9 Packing Group III

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, 中国 (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), 日本 (ENCS), 日本 (ISHL), オーストラリア (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Nitric acid, yttrium(3+) X - X - - - - X X X - salt, hexahydrate Nitric acid, yttrium(3+) - - X 233-802-6 X X X X X - KE-35503 salt

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SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Creation Date 01-May-2012 改訂版 Date 26-Jul-2026 改訂版 Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, 安全データシート (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers. Chemical incident response training.

Legend

CAS - Chemical Abstracts Service TSCA - 米国 Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - 日本語 Existing and New Chemical Substances IECSC - 中国語 Inventory of Existing Chemical Substances AICS - オーストラリアn Inventory of Chemical Substances KECL - 韓国語 Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic 化合物)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals 供給元s safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this 安全データシート is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of 安全データシート

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