CERIUM (III) NITRATE SOLUTION SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: CERIUM (III) NITRATE SOLUTION

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Danger

Hazard Statements

H272 May intensify fire; oxidizer H332 Harmful if Inhaled. H302 Harmful if Swallowed H314 Causes severe skin burns and eye damage

Precautionary Phrases

P210 Keep away from heat/sparks/open flames/hot surfaces. –No smoking P220 Keep/Store away from clothing/…/combustible materials. P261 Avoid breathing dust/fume/gas/mist/vapous/spray. P280 Wear protective gloves/eye protection/face protection P404 Store in closed container. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

HMIS CLASSIFICATION: Health: 3 Flammability: 0 Physical Hazard: 1

NFPA RATING: Health: 3 Fire: 0 Instability: 1

POTENTIAL HEALTH EFFECTS: Inhalation, Ingestion, Skin and Eye EYE CONTACT: Causes severe irritation to eyes. SKIN CONTACT: Causes irritation to skin. INHALATION: Causes irritation to respiratory system.

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SECTION 2 HAZARDS IDENTIFICATION (Cont.)

INGESTION: No data ACUTE HEALTH EFFECTS: No data CHRONIC HEALTH EFFECTS: No information available on long-term chronic effects.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: H2Ce(NO3)6

Molecular Weight: 514.1800

CHEMICAL NAME CAS# % ACGIH (TWA) OSHA (PEL)

Cerium (III) Nitrate 10294-41-4 65-75 Not Determined Not Determined

Nitric Acid 7697-37-2 0-5

Water 7732-18-5 25-35 Not Applicable Not Applicable

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water (lukewarm if possible) for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Got immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation, burns, or redness persists. INHALATION: Remove victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Give oxygen if deemed necessary. If not breathing administer CPR. Get emergency care immediately. INGESTION: Seek medical assistance immediately. Keep the victim calm. Do not induce vomiting.

SECTION 5 FIREFIGHTING MEASURES

EXTINGUISHING MEDIUM: Use water only SPECIAL FIRE FIGHTING PROCEDURES: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. Use water spray to cool fire-exposed containers and structures. . HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: If involved in a fire this material may emit oxides and nitrogen. UNUSUAL FIRE OR EXPLOSION HAZARDS: None known.

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECUATIONS: Evacuate all personnel to safe areas. Use adequate protection when handling. Use self-contained breathing apparatus for large spills. ENVIRONMENTAL PRECAUTIONS: This material should be prevented from contaminating soil or from sewer and drainage systems and bodies of water. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Isolate spillage. Absorb spill with inert materials, then place in applicable chemical waste container.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Be sure to have appropriate exhaust and ventilation. CONDITIONS FOR SAFE STORAGE: Keep containers tightly closed. Store in a cool, dry, and well-ventilated area away from heat and all sources of ignition. Store away from incompatible materials..

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SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EYE PROTECTION: Always wear approved safety glasses w/side shields, or safety goggles, faceshield when handling a chemical substance in the laboratory. SKIN PROTECTION: Wear PVC, rubber, neoprene.

VENTILATION: If possible, handle the material in a local exhaust hood. RESPIRATOR: If ventilation is not available, a high efficiency acid/mist respirator should be worn. The use of respirators required a Respirator Protection Program to be in compliance with 29CFR 1910.34. ADDITIONAL PROTECTION: Protection to avoid contact with clothing and shoes. OTHER PROTECTIVE EQUIPMENT: Eye was and quick-drench shower facilities should be available in work area. Use in a controlled environment. Do not smoke, eat, or drink in area.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: Clear to yellow liquid MELTING POINT: Not applicable BOILING POINT: No data FLASH POINT: Not applicable MOLECULAR WEIGHT: ODOR: Acrid, pungent VAPOR PRESSURE: Not applicable VAPOR DENSITY (AIR = 1): Not applicable % VOLATILE BY VOLUME: Non volatile SOLUBILITY IN WATER: Not applicable

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Excessive temperatures INCOMPATIBILITY: Reducing agents DECOMPOSITION PRODUCTS: Gaseous oxides of nitrogen form on decomposition of nitrates by temperature exceeding 150 deg. C. and/or by oxidation reactions.

SECTION 11 TOXICOLOGICAL DATA

CARCINOGENIC EFFECTS: No MUTAGENIC EFFECTS: No TETRATOGENIC EFFECTS: No

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No information available

SECTION 13 DISPOSAL CONSIDERATIONS

Retain all contaminated solage from removal and treatment. Dispose of in according to local state and federal regulations.

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SECTION 14 TRANSPORTATION DATA

Nitrates, inorganics, n.o.s.

Class 5.1

UN1477

PGIII

SECTION 15 REGULATORY INFORMATION

TSCA Listed in TSCA inventory SARA (TITLE 313): Total Nitrates (in solution) RCRA STATUS: Meets criteria for nitrated and should be managed as a hazardous waste.

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 09/13

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