Gadolinium (III) Bromide, Anhydrous SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Gadolinium (III) Bromide, Anhydrous

PRODUCT NUMBER: 1814

CAS NUMBER: 13818-75-2

MANUFACTURER:

ProChem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Warning

Hazard Statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.

Precautionary Phrases

P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors of in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340+P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with waster for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 0

GADOLINIUM (III) BROMIDE, ANHYDROUS PAGE 1

SECTION 2 HAZARDS IDENTIFICATION (Cont.)

EYE CONTACT: Causes serious irritation of the eyes. SKIN CONTACT: Causes irritation to the skin. INHALATION: Causes irritation to the nose, throat, and respiratory tract. INGESTION: May cause irritation.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: GdBr3

Molecular Weight: 396.96

CHEMICAL NAME CAS# %

Gadolinium (III) Bromide Anhydrous 13818-75-2 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with soap and plenty of water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Product is not flammable AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: This product does not present explosion hazards. EXTINGUISHING MEDIUM: Use firefighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Gadolinium oxides and hydrogen bromide

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the formation of dust. Avoid breathing vapors, mist, gas, or dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Sweep up and place in suitable container for proper disposal.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Avoid formation of dusts and aerosols. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator.

GADOLINIUM (III) BROMIDE, ANHYDROUS PAGE 2

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: Colorless solid ODOR: No data available MOLECULAR WEIGHT: 396.96 BOILING POINT: 1490° C MELTING POINT: 770° C SPECIFIC GRAVITY: 4.57 SOLUBILITY IN WATER: Soluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None known INCOMPATIBILITY: Strong oxidizing agents and acids. DECOMPOSITION PRODUCTS: Gadolinium oxides and hydrogen bromide

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available RTECS: No data

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No data available.

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good.

SECTION 15 REGULATORY INFORMATION

SARA 302/304: Not Listed SARA 311/312: Acute Health Hazard, Chronic Health Hazard SARA (TITLE 313): Not Listed PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Gadolinium (III) Bromide NEW JERSEY RIGHT TO KNOW COMPONENTS: Gadolinium (III) Bromide CALIFORNIA PROP. 65: Not Listed

GADOLINIUM (III) BROMIDE, ANHYDROUS PAGE 3

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, ProChem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 10/24 SDS DEPT.

GADOLINIUM (III) BROMIDE, ANHYDROUS PAGE 4