GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99% SDS

Page 1/8 Safety data sheet according to Regulation (EC) No. 1907/2006

Printing date 05.02.2014 Version number 1 Revision: 05.02.2014

1 Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

Article number: 7208

CAS Number: 38245-36-2 EC number: 227-583-6

Registration number A registration number is not available for this substance as the substance or its use are exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available.

Application of the substance / the mixture Laboratory chemical

1.3 Details of the supplier of the safety data sheet

Manufacturer/Supplier: Carl Roth GmbH + Co. KG Schoemperlenstraße 3-5 76185 Karlsruhe Germany Telefon: +49/(0)721 5606-0 Telefax: +49/(0)721 5606-149 E-Mail: sicherheit@carlroth.de

Further information obtainable from: Department Health, Safety and Environment

1.4 Emergency telephone number: Poison Centre Munich Telefon +49/(0)89 19240

2 Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Void

Classification according to Directive 67/548/EEC or Directive 1999/45/EC Void

Additional information: Note, not yet fully tested.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 Void

Hazard pictograms Void

Signal word Void

Hazard statements Void

Additional information: -

2.3 Other hazards

All chemicals are potentially dangerous. They are therefore only be handled by specially trained personnel with the necessary care.

Results of PBT and vPvB assessment PBT: Not applicable. (Contd. on page 2)

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Page 2/8 Safety data sheet according to Regulation (EC) No. 1907/2006

Printing date 05.02.2014 Version number 1 Revision: 05.02.2014

Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

(Contd. of page 1) vPvB: Not applicable.

* 3 Composition/information on ingredients

3.1 Chemical characterization: Substances

CAS No. Description 38245-36-2 Gandolinium (III)- carbonate hydrate

Identification number(s) EC number: 227-583-6 Formula: C೤GdೣO೪ * x HೣO Molar mass [g/mol]: 494,53

4 First aid measures

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4.1 Description of first aid measures

General information: Remove any clothing soiled by the product.

After inhalation: Supply fresh air; if there is any trouble seek medical help.

After skin contact: Wash with water and soap. If there is any trouble seek medical help.

After eye contact: To be sure rinse opened eye under running water. If there is any trouble seek medical help.

After swallowing: Rinse out mouth and then drink water. Seek medical treatment.

4.2 Most important symptoms and effects, both acute and delayed No information available.

4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Firefighting measures

5.1 Extinguishing media

Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

For safety reasons unsuitable extinguishing agents: For this substance/mixture no limitations of extinguishing agents are given.

5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide and carbon dioxide (Contd. on page 3)

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Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

(Contd. of page 2)

5.3 Advice for firefighters

Protective equipment: Wear self-contained respiratory protective device. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing.

6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures Do not breathe dust. Avoid contact with the eyes and skin.

6.2 Environmental precautions Do not allow product to reach sewage system or any water course.

6.3 Methods and material for containment and cleaning up Pick up mechanically. Dispose of the material collected according to regulations.

6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 Handling and storage

7.1 Precautions for safe handling Provide suction extractors if dust is formed. Keep containers, equipment and working place clean.

7.2 Conditions for safe storage, including any incompatibilities

Storage:

Requirements to be met by storerooms and receptacles: Store only in the original receptacle.

Information about storage in one common storage facility: Store away from foodstuffs.

Further information about storage conditions: Keep container tightly sealed. Store in dry conditions.

Recommended storage temperature: 15 - 25 °C

7.3 Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.

8.1 Control parameters

Ingredients with limit values that require monitoring at the workplace: Not required.

Additional information: The lists valid during the making were used as basis. (Contd. on page 4)

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Printing date 05.02.2014 Version number 1 Revision: 05.02.2014

Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

(Contd. of page 3)

8.2 Exposure controls

Personal protective equipment:

General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Avoid contact with the eyes and skin. Wash hands before breaks and at the end of work.

Individual protection measures Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.

Respiratory protection: `Q

When dusts are generated: protective device filter P1.

Protection of hands: `S

Protective gloves Check protective gloves prior to each use for their proper condition.

Material of gloves Nitrile rubber, NBR ุ 0.2 mm The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Penetration time of glove material Value for the permeation: Level ุ 6 The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye protection: `R

Tightly sealed goggles

Body protection: Protective work clothing

9 Physical and chemical properties

9.1 Information on basic physical and chemical properties General Information Appearance: Form: Like powder

(Contd. on page 5)

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Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

(Contd. of page 4)

Colour: white to yellowish Odour: Odourless Odour threshold: No information available.

pH-value: No information available.

Change in condition Melting point/Melting range: No information available. Boiling point/Boiling range: No information available.

Flash point: No information available

Flammability (solid, gaseous): No information available

Ignition temperature: No information available

Decomposition temperature: No information available

Self-igniting: No information available

Danger of explosion: No information available

Explosion limits: Lower: No information available. Upper: No information available. Oxidizing properties: No information available.

Vapour pressure: No information available

Density: Relative density No Information available. Vapour density No information available Evaporation rate No information available

Solubility in / Miscibility with water: Insoluble.

Partition coefficient (n-octanol/water): No information available

Viscosity: Dynamic: No information available. Kinematic: No information available.

9.2 Other information No further relevant information available.

10 Stability and reactivity

10.1 Reactivity No further relevant information available.

10.2 Chemical stability

Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications.

10.3 Possibility of hazardous reactions Reacts with strong acids and oxidizing agents.

10.4 Conditions to avoid No information available.

10.5 Incompatible materials: No information available.

10.6 Hazardous decomposition products:

In case of fire: see item 5. (Contd. on page 6)

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Printing date 05.02.2014 Version number 1 Revision: 05.02.2014

Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

(Contd. of page 5)

11 Toxicological information

11.1 Information on toxicological effects

Acute toxicity:

LD/LC50 values relevant for classification: Quantitative data on the toxicity of this product are not available.

Primary irritant effect:

on the skin: Prolonged or repeated contact may cause skin irritations.

on the eye: Slight irritations

after inhalation: Intensive contact with dusts may lead to irritations of the eyes and the respiratory tract.

Sensitization: No sensitizing effects known.

CMR effects: Germ cell mutagenicity: No information available. Carcinogenicity: No information available. Reproductive toxicity: No information available.

Aspiration hazard: Not applicable.

Specific target organ toxicity - single exposure The substance or mixture is not classified as specific target organ toxicant, single exposure. Specific target organ toxicity - repeated exposure The substance or mixture is not classified as specific target organ toxicant, repeated exposure.

Additional toxicological information: We have no description of any toxic symptoms.

Further information: To the best of our knowledge, the toxicological properties have not been thoroughly investigated. Hazardous properties cannot be excluded. The product should be handled with the care usual when dealing with chemicals.

12 Ecological information

12.1 Toxicity

Aquatic toxicity: Quantitative data on the ecological effect of this product are not available.

12.2 Persistence and degradability No further relevant information available.

12.3 Bioaccumulative potential No further relevant information available.

12.4 Mobility in soil No further relevant information available. (Contd. on page 7)

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Printing date 05.02.2014 Version number 1 Revision: 05.02.2014

Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

(Contd. of page 6)

Ecotoxical effects:

Remark: Do not allow to enter waters, waste water, or soil!

12.5 Results of PBT and vPvB assessment

PBT: Not applicable. vPvB: Not applicable.

12.6 Other adverse effects

No further relevant information available.

13 Disposal considerations

Waste treatment methods

Recommendation The disposal is regionally differently regulated, therefore the kind of disposal is to be inquired at the responsible authorities.

Uncleaned packaging:

Recommendation: Disposal according to official regulations.

14 Transport information

14.1 UN-Number

ADR, ADN, IMDG, IATA Void

14.2 UN proper shipping name

ADR, ADN, IMDG, IATA Void

14.3 Transport hazard class(es)

ADR, ADN, IMDG, IATA Class Void

14.4 Packing group

ADR, IMDG, IATA Void

14.5 Environmental hazards:

Marine pollutant: No

14.6 Special precautions for user Not applicable.

14.7 Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code Not applicable.

UN "Model Regulation": -

(Contd. on page 8)

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Trade name: GADOLINIUM (III)-CARBONATE HYDRATE ROTI® REMETIC 99,99%

(Contd. of page 7)

15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations:

Breakdown regulations: -

Waterhazard class: Water hazard class 3 (Self-assessment): extremely hazardous for water.

15.2 Chemical safety assessment A Chemical Safety Assessment has not been carried out.

16 Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

Department issuing MSDS: Department: Health, Safety and Environment

Contact: Frau Weckemann Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent LD50*: Lethal Dose, 50 percent (Not relevant for classification) LD50*: Lethal Concentration, 50 percent (Not relevant for classification) * Data compared to the previous version altered.

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