Samarium (III) Acetate Hydrate 3074 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Samarium (III) Acetate Hydrate

PRODUCT NUMBER: 3074

CAS NUMBER: 100587-91-5

SYNONYMS: Acetic acid, samarium (+3) salt, hydrate

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Not a dangerous substance according to GHS.

HMIS CLASSIFICATION: Health: 0 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 0 Flammability: 0 Reactivity Hazard: 0

EYE CONTACT: Causes slight to mild irritation of the eyes. SKIN CONTACT: Causes slight to mild irritation of the skin. INHALATION: Irritating to the nose, mucous membranes, and respiratory tract. INGESTION: May be harmful if swallowed

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: Sm(OOCCH3)3 !xH2O

Molecular Weight: 327.49 (anhy.)

CHEMICAL NAME CAS# %

Samarium Acetate Hydrate 100587-91-5 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eyelids open. Get immediate medical attention.

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SECTION 2 HAZARDS IDENTIFICATION (Cont.)

SKIN EXPOSURE: Was the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary. INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention if necessary.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Product is not flammable AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Carbon oxides and samarium oxide.

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts and aerosols. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Keep away from heat and moisture.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: Off-white powder ODOR: None MOLECULAR WEIGHT: 327.53 (anhy.) BOILING POINT: No data available MELTING POINT: No data available SPECIFIC GRAVITY: 1.94 gm/ml VAPOR DENSITY: No data available SOLUBILITY: Soluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Excess heat

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SECTION 10 STABILITY AND REACTIVITY (Cont.)

INCOMPATIBILITY: Strong oxidizing agents, bases, and active metals. DECOMPOSITION PRODUCTS: Carbon oxides and samarium oxides.

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No data available.

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good.

SECTION 15 REGULATORY INFORMATION

TSCA: Listed in the TSCA inventory DSCL (EEC): Listed on the DSCL inventory SARA 302/304: Not Listed SARA 311/312: No SARA Hazards. SARA (TITLE 313): Not Listed

CALIFORNIA PROP. 65: Not Listed WHMIS CANADA: Not Listed NEW JERSEY RIGHT TO KNOW COMPONENTS: Samarium (III) acetate hydrate PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Samarium (III) acetate hydrate

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 08/14

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