Samarium, powder 3070 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Samarium, powder

PRODUCT NUMBER: 3070

CAS NUMBER: 7400-19-9

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Danger

Hazard Statements

H228 Flammable solid H260 In contact with water releases flammable gases which may ignite spontaneously H373 May cause damage to organs through prolonged or repeated exposure

Precautionary Phrases

P210 Keep away from heat/sparks/open flames/hot surfaces P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231+P232 Handle under inert gas. Protect from moisture. P240 Ground/bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting equipment P260 Do not breathe dust or mist. P280 Wear protective gloves/protective clothing/eye protection/face protection P314 Get medical advice/attention if you feel unwell P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages P370+P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction

HMIS CLASSIFICATION: Health: 1 Fire: 3 Reactivity Hazard: 2 NFPA RATING: Health: 0 Flammability: 2 Reactivity Hazard: 2 Specific Hazard: W

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SECTION 2 HAZARDS IDENTIFICATION (Cont.)

EYE CONTACT: May cause slight to mild irritation of the eyes. SKIN CONTACT: May cause slight to mild irritation of the skin. INHALATION: Inhalation of fine dust may be irritating to the nasal cavity, mucous membranes, and respiratory tract. INGESTION: May be harmful if swallowed.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: Sm

Molecular Weight: 150.40

CHEMICAL NAME CAS# %

Samarium 7440-19-9 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Was affected area with water. Remove contaminated clothes if necessary. Seek medical assistance ir irritation persists. INHALATION: Remove to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary. INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention if necessary.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Not available AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Carbon dioxide or dry powder. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Samarium Oxide

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released to the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Fine powder should be covered with sodium carbonate or dolomite in order to reduce the formation of dust. Sweep up and place in suitable container for disposal.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts and aerosols. Keep away from sources of ignition – No smoking. Take measures to prevent the build up of electrostatic charge. Handle in argon. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area under argon. Keep away from incompatible materials. Air and moisture sensitive. Store under dry inert gas. Store away from oxidizing agents, halogens, and acid chlorides.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator.

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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: Gray to silver powder ODOR: None MOLECULAR WEIGHT: 150.40 BOILING POINT: 1794° C MELTING POINT: 1072° C SPECIFIC GRAVITY: 7.4 gm/ml VAPOR DENSITY: No data available SOLUBILITY: Reacts with water

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Reacts violently with water. CONDITIONS TO AVOID: Heat, flames, and sparks. Extremes of temperature and direct sunlight. Exposure to moisture. INCOMPATIBILITY: Halogens, strong acids, strong oxidizing agents, water, oxygen, and halocarbons. DECOMPOSITION PRODUCTS: Samarium oxides

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available CHRONIC TOXICITY: Rare earth compounds may cause delayed blood clotting leading to hemorrhages. Inhalations of rare earths may cause sensitivity to heat, itching, and increased awareness of odor and taste. Abdominal pain, nausea, vomiting, salivation, fatigue, dizziness, confusion. Palpitation, ataxia.

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No data available.

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

DOT: UN3089 IATA: UN3089

Metal powders, flammable, n.o.s. Metal powder, flammable, n.o.s.

(Samarium powder) (Samarium powder)

Class 4.1 Class 4.1

PG III PG III

SECTION 15 REGULATORY INFORMATION

TSCA: Listed in the TSCA inventory

DSCL (EEC): Listed on the DSCL inventory

SARA 302/304: Not Listed

SARA 311/312: Fire Hazard, Chronic Health Hazard

SARA (TITLE 313): Not Listed

CALIFORNIA PROP. 65: Not Listed

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SECTION 15 REGULATORY INFORMATION (Cont.)

WHMIS CANADA: Not Listed

NEW JERSEY RIGHT TO KNOW COMPONENTS: Samarium

PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Samarium

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 08/14

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