Thulium (III) Bromide Anhydrous 3594 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Thulium (III) Bromide Anhydrous

PRODUCT NUMBER: 3594

CAS NUMBER: 14456-51-0

MANUFACTURER:

ProChem, Inc. PHONE: 815-398-1788 826 Roosevelt Road TOLL FREE: 800-795-8788 Rockford, IL 61109

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Warning

Hazard Statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.

Precautionary Phrases

P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352+P362 IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. P304+P340+P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 1 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 1

THULIUM (III) BROMIDE ANHYDROUS PAGE 1

SECTION 2 HAZARDS IDENTIFICATION (Cont.)

EYE CONTACT: Causes serious eye irritation. SKIN CONTACT: Causes skin irritation. INHALATION: May cause respiratory tract irritation. INGESTION: May be harmful if swallowed.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: TmBr3

Molecular Weight: 408.66

CHEMICAL NAME CAS# %

Thulium (III) bromide 14456-51-0 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Get medical attention. SKIN EXPOSURE: Wash affected area with water for at least 15 minutes. If skin irritation persists, call a physician. INHALATION: Remove victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. Get medical attention if symptoms occur. INGESTION: Clean mouth with water and drink afterward plenty of water. Get medical attention if symptoms occur.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Not applicable AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: No data available SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen bromide and metal oxides.

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the formation of dust. Avoid breathing vapors, mist, gas, or dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Sweep up and place in suitable container for proper disposal.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Avoid formation of dusts. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated. Keep away from incompatible materials. Store under inert gas. Protect from moisture.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield.

THULIUM (III) BROMIDE ANHYDROUS PAGE 2

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION (Cont.)

SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: White solid ODOR: No data available MOLECULAR WEIGHT: 408.66 BOILING POINT: 1440° C MELTING POINT: 952° C SPECIFIC GRAVITY: No data available SOLUBILITY IN WATER: No data available

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Hygroscopic HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Exposure to moist air and water. INCOMPATIBILITY: Oxidizing agents DECOMPOSITION PRODUCTS: Hydrogen bromide and metal oxides

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available CHRONIC TOXICITY: Not available RTECS: No data

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No information available

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good.

SECTION 15 REGULATORY INFORMATION

SARA (TITLE 313): Not Listed CALIFORNIA PROP. 65: Not Listed

THULIUM (III) BROMIDE ANHYDROUS PAGE 3

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, ProChem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 10/24 SDS DEPT.

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