Thulium powder ALFAA44168 SDS

Page 1 / 8 SAFETY DATA SHEET Revision Date 22-Jul-2026 Version 5

ALFAA44168

Thulium powder

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 铥粉铥粉铥粉铥粉 Product Description: Thulium powder

Cat No. : 44168 CAS No 7440-30-4 Molecular Formula Tm

Supplier Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

Recommended Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Powder Solid Grey Odorless

Emergency Overview Flammable solid. Moisture sensitive. Air sensitive. May form combustible dust concentrations in air.

Classification of the substance or mixture

Flammable solids. Category 2

Label Elements

Signal Word Warning

Hazard Statements H228 - Flammable solid

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Precautionary Statements Prevention P280 - Wear protective gloves/protective clothing/eye protection/face protection P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment Response P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Combustible material. May form combustible dust concentrations in air. Health Hazards The product contains no substances which at their given concentration are considered to be hazardous to health. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Is not likely mobile in the environment due its low water solubility. Spillage unlikely to penetrate soil.

May form explosible dust-air mixture if dispersed. This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Thulium 7440-30-4 99.9

SECTION 4. FIRST AID MEASURES

General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Most important symptoms and effects None reasonably foreseeable.

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

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ALFAA44168 SAFETY DATA SHEET Revision Date 22-Jul-2026Page 3 / 8 Thulium powder ______________________________________________________________________________________________ Dry chemical.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Dust can form an explosive mixture with air. Combustible material. Fine dust dispersed in air may ignite.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation.

Environmental Precautions Should not be released into the environment. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system.

Methods for Containment and Clean Up Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed containers for disposal.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat, sparks and flame. Keep under nitrogen.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment ______________________________________________________________________________________________ Page 3

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Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Long sleeved clothing

Respiratory Protection No protective equipment is needed under normal use conditions.

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced

Small scale/Laboratory use Maintain adequate ventilation

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Grey Physical State Powder Solid

Odor Odorless Odor Threshold No data available pH No information available Melting Point/Range 1545 °C / 2813 °F Softening Point No data available Boiling Point/Range 1727 °C / 3140.6 °F Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No data available Vapor Density Not applicable Solid Specific Gravity / Density 9.332 Bulk Density No data available Water Solubility Insoluble Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature Not applicable Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

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ALFAA44168 SAFETY DATA SHEET Revision Date 22-Jul-2026Page 5 / 8 Thulium powder ______________________________________________________________________________________________

Molecular Formula Tm Molecular Weight 168.93

SECTION 10. STABILITY AND REACTIVITY

Stability Moisture sensitive. Air sensitive.

Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur.

Conditions to Avoid Incompatible products.

Materials to avoid Strong acids. Halogens.

Hazardous Decomposition Products Thulium oxide.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information No acute toxicity information is available for this product

(a) acute toxicity;

(b) skin corrosion/irritation; No data available

(c) serious eye damage/irritation; No data available

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs No information available.

(j) aspiration hazard; Not applicable Solid

Symptoms / effects,both acute and No information available delayed

SECTION 12. ECOLOGICAL INFORMATION

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Ecotoxicity effects May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.

Persistence and Degradability Product contains heavy metals. Discharge into the environment must be avoided. Special pre-treatment is necessary Persistence Insoluble in water, May persist. Degradability Not relevant for inorganic substances. Degradation in sewage Contains substances known to be hazardous to the environment or not degradable in waste treatment plant water treatment plants.

Bioaccumulative Potential May have some potential to bioaccumulate; Product has a high potential to bioconcentrate

Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water solubility

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep product and empty container away from heat and sources of ignition.

Other Information Waste codes should be assigned by the user based on the application for which the product was used. Do not flush to sewer. Can be landfilled or incinerated, when in compliance with local regulations.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN3089 Proper Shipping Name Metal powder, flammable, n.o.s. Hazard Class 4.1 Packing Group III

IMDG/IMO

UN-No UN3089 Proper Shipping Name Metal powder, flammable, n.o.s. Hazard Class 4.1 Packing Group III

IATA

UN-No UN3089 Proper Shipping Name Metal powder, flammable, n.o.s. Hazard Class 4.1

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Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

International Inventories X = listed, China (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Thulium - - - 231-140-2 X X - X - -

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Revision Date 22-Jul-2026 Revision Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers.

Legend

CAS - Chemical Abstracts Service TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japanese Existing and New Chemical Substances IECSC - Chinese Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic Compound)

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ALFAA44168 SAFETY DATA SHEET Revision Date 22-Jul-2026Page 8 / 8 Thulium powder ______________________________________________________________________________________________ Key literature references and sources for data https://echa.europa.eu/information-on-chemicals Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

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