Titanium-50 SDS

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 1/9

Section 1: Identification of the Substance/Mixture and of the Company/Undertaking

Product Identifier: Identification as on the label/Trade name: Titanium, Enriched Titanium. Molecular weight: 47.87 Chemical formula: Ti Synonyms: None. Details of the supplier of the Safety Data Sheet: Neonest AB Storgatan 70C, Solna SE-17152 Sweden Contact details: +46-76-219-9731 24-hour Emergency Contact: Swedish Poisons Centre Phone: 112 - Ask for Poisons Information, 112 – begär Giftinformation . Other International Contacts: CHEMTREC 24-hour: +1-703-741-5500 (US + Worldwide) NHS: 111 (UK) Charite: +49 30 450 531 000 (Netherlands) INTCF: +34 917689800 (Spain) CapTv: +33 1 40 05 48 48 (France)

Section 2: Hazards Identification

Classification of the substances or mixture: The mixture is classified according to: Regulation EC 1272/2008 [EU-GHS/CLP] Hazard classes/Hazard categories: Hazard statement: Pyrophoric Solid (Category 1) H250 Label elements: Hazard pictograms: Signal Words: Danger. Hazard Statements: H250 Catches fire spontaneously if exposed to air.

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 2/9 Precautionary Statements: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P222 Do not allow contact with air. P231 + P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P280 Wear protective gloves/protective clothing. P302 + P334 IF ON SKIN: Immerse in cool water or wrap in wet bandages. Other hazards: None known.

Section 3: Composition/Information on Ingredients

Substance/Mixture: Substance. Ingredients: Substance name (IUPAC/EC) CAS - No. Molecular weight Concentration % by weight Classification EC1272/2008 EC - No. Titanium 7440-32-6 47.87 >99% Pyr. Sol. 1 H250 231-142-3 For explanation of abbreviations see Section 16.

Section 4: First - Aid Measures

Description of first aid measures: In case of inhalation: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact: Wash off with soap and plenty of water. Consult a physician. In case of eye contact: Flush eyes with water as a precaution. In case of ingestion: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed: Inhalation: May be harmful if inhaled; may cause respiratory tract irritation. Eyes: May cause eye irritation. Skin contact: May be harmful if absorbed through skin; may cause skin irritation. Ingestion: May be harmful if swallowed. Indication of any immediate medical attention and special treatment needed: Treat symptomatically. Show this safety data sheet to a physician or emergency room.

Section 5: Fire - Fighting Measures

Extinguisher media: Suitable extinguisher media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media: None known. Special hazards arising from the mixture: Hazardous decomposition products formed under fire conditions: Titanium/titanium oxides.

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 3/9 Advice for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Further information: Use water spray to cool unopened containers.

Section 6: Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Personal precautions: Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Local authorities should be advised if significant spillages cannot be contained. Methods for containment and cleaning up: Methods for cleaning up: Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see Section 13). Keep in suitable closed containers for disposal. Reference to other sections: Treat recovered material as described in the section "Disposal considerations".

Section 7: Handling and Storage

Precautions for safe handling: Advice on safe handling: Provide appropriate exhaust ventilation at places where dust is formed. Keep away from sources of ignition. NO SMOKING. Hygiene measures: Do not eat, drink or smoke when using this product. Conditions for safe storage, including incompatibilities: Requirements for storage areas and containers: Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. Air- and moisture-sensitive. Keep in a dry place.

Section 8: Exposure Controls/ Personal Protection

Control parameters: Occupational exposure limits: Contains no substances with occupational exposure limit values. Exposure controls: Appropriate engineering controls: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Individual protection measures, such as personal protective equipment: Eye/face protection: Face shield and safety glasses: Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 4/9 use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Use protective gloves against thermal risks. Body protection: Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Section 9: Physical and Chemical Properties

Information on basic physical and chemical properties Appearance (form): Solid (powder). Colour: No data available. Odour: No data available. Odour threshold: No data available. Molecular Weight: 47.87 pH (concentration): No data available. Melting point/range (° C): 1660 °C Boiling point/range (° C): 3287 °C Freezing point (°C): No data available. Flash point (° C): No data available. Evaporation rate: No data available. Flammability (solid, gas): The substance is a flammable solid. Ignition temperature (° C): No data available. Upper/lower flammability/explosive limits: No data available. Vapour pressure (20 ° C): No data available Vapour density: No data available. Relative densi ty (25 ° C): 4.5 g/mL at 25 °C Water solubility (g/L ) at 20 ° C: Insoluble. n-Octanol/Water partition coefficient : No data available. Auto-ignition temperature: Pyrophoric / subcategory 1. Decomposition temperature: No data available. Viscosity, dynamic (mPa s): No data available. Explosive properties: The substance or mixture is not classified as explosive. Oxidising properties: The substance or mixture is not classified as oxidizing.

Section 10: Stability and Reactivity

Reactivity: No dangerous reaction known under conditions of normal use. Chemical stability: Stable under normal conditions. Possibility of hazardous reactions: Reacts violently with water. Conditions to avoid: None known . Incompatible materials: Oxygen, aluminium, carbon dioxide (CO 2 ), halogens, chlorinated solvents, strong acids, strong oxidizing agents. Hazardous decomposition products: Hazardous decomposition products formed under fire conditions: Titanium/titanium oxides.

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 5/9

Section 11: Toxicological Information

Information on toxicological effects: Not classified based on available information. Classification according to GHS (1272/2008/EG, CLP) Skin corrosion/irritation: Not classified based on available information. Serious eye damage/eye irritation: Not classified based on available information. Respiratory or skin sensitisation: Not classified based on available information. Germ cell mutagenicity: Not classified based on available information. Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as a probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Reproductive toxicity: Not classified based on available information. Specific target organ toxicity – single exposure (STOT): Not classified based on available information. Specific target organ toxicity (STOT) – repeated exposure: Not classified based on available information. Aspiration toxicity: Not classified based on available information.

Section 12: Ecological Information

Toxicity: No data available. Persistence and degradability: No data available. Bioaccumulative potential: No data available. Mobility in soil: No data available. Results of PBT& vPvB assessment: Not relevant. Other adverse effects: No data available.

Section 13: Disposal Considerations

Waste treatment methods: Burn in a chemical incinerator equipped with an afterburner and scrubber, but exert extra care in igniting, as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 6/9

Section 14: Transport Information

DOT: Proper Shipping Name: TITANIUM POWDER, DRY. Hazard Class : 4.2 UN Number: 2546 Packing Group: II Hazard Label: IMDG: Proper Shipping Name: TITANIUM POWDER, DRY. Hazard Class : 4.2 UN Number: 2546 Packing Group: II Marine Pollutant: No IATA: Proper Shipping Name: TITANIUM POWDER, DRY. Hazard Class : 4.2 UN Number: 2546 Packing Group: II

Section 15: Regulatory Information

EU regulations: Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed. Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed. Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed.

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 7/9 Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Not listed. Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed. Authorisations: Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed. Restrictions on use: Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Not listed. Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding. Not regulated. Other EU regulations: Directive 2012/18/EU on major accident hazards involving dangerous substances Not listed. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Always applicable. Directive 94/33/EC on the protection of young people at work Not listed. Other regulations: The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended. OSHA Hazards: Flammable solid. SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components : This material does not contain any chemical components with known CAS numbers that exceed the threshold (de minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards: Fire Hazard. Massachusetts Right to Know Components: No components are subject to the Massachusetts Right to Know Act. Pennsylvania Right to Know Components: Titanium / CAS No. 7440-32-6 / Revision Date 2007-03-01 New Jersey Right to Know Components: Titanium / CAS No. 7440-32-6 / Revision Date 2007-03-01 California Prop. 65 Components: This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm. National regulations: Follow national regulation for work with chemical agents. Chemical safety assessment: No Chemical Safety Assessment has been carried out.

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 8/9

Section 16: Other Information

List of abbreviations: ACGIH American Conference of Governmental Industrial Hygienists ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road ALARA As Low As Is Reasonably Achievable AMU Atomic Mass Unit ANSI American National Standards Institute BLS Basic Life Support CAM Continuous Air Monitor CAS Chemical Abstracts Service (division of the American Chemical Society) CEN European Committee for Standardization CERCLA Comprehensive Environmental Response Compensation and Liability Act CLP Classification, Labelling and Packaging (European Union) CPR Controlled Products Regulations (Canada) CWA Clean Water Act (USA) DAC Derived Air Concentration (USA) DOE United States Department of Energy (USA) DOT United States Department of Transportation (USA) DSL Domestic Substances List (Canada) EC50 Half Maximal Effective Concentration EINECS European Inventory of Existing Commercial Chemical Substances EHS Environmentally Hazardous Substance ELINCS European List of Notified Chemical Substances EMS Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency (USA) EPCRA Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 GHS Globally Harmonized System HMIS Hazardous Materials Identification System (USA) IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Containers ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life or Health IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent LDLO Lethal Dose Low LOEC Lowest-Observed-Effective Concentration MARPOL International Convention for the Prevention of Pollution from Ships MSHA Mine Safety and Health Administration (USA) NCRP National Council on Radiation Protection & Measurements (USA) NDSL Non-Domestic Substances List (Canada) NFPA National Fire Protection Association (USA) NIOSH National Institute for Occupational Safety and Health (USA) NOEC No Observed Effect Concentration N.O.S. Not Otherwise Specified

Safety Data Sheet for Titanium Metal Powder, Enriched Titanium Metal Powder According to ISO 11014:2010 First Print Date: 5-Mar-2015 Revision Date: 24-Aug-2019 Version: 1.1.1. Safety Data Sheet (SDS) for Titanium, Enriched Titanium https://www.buyisotope.com Page 9/9 NRC Nuclear Regulatory Commission (USA) NTP National Toxicology Program (USA) OSHA Occupational Safety and Health Administration (USA) PBT Persistent Bioaccumulative and Toxic Chemical PEL Permissible Exposure Limit PIH Poisonous by Inhalation Hazard RCRA Resource Conservation and Recovery Act (USA) RCT Radiation Control Technician REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (Europe) RID Regulations Concerning the International Transport of Dangerous Goods by Rail RTECS Registry of Toxic Effects of Chemical Substances SARA Superfund Amendments and Reauthorization Act (USA) TDG Transportation of Dangerous Goods (Canada) TIH Toxic by Inhalation Hazard TLV Threshold Limit Value TPQ Threshold Planning Quantity TSCA Toxic Substances Control Act TWA Time Weighted Average UN United Nations (Number) VOC Volatile Organic Compound vPvB Very Persistent Very Bioaccumulative Chemical WGK Wassergefährdungsklassen (Germany: Water Hazard Classes) WHMIS Workplace Hazardous Materials Information System References: Not available. Full text of any H-statements not written out in full under Sections 2 to 15: H250 Catches fire spontaneously if exposed to air. Revision information: None. Training information: Follow training instructions when handling this material. Further Information: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.