Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum(III) 2177 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum(III)

PRODUCT NUMBER: 2177

CAS NUMBER: 14319-13-2

SYNONYMS: Dipivaloylmethane, lanthanum complex, Lanthanum (III) 2,2,6,6-tetramethyl-3,5- heptanedionato

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Not classified as a hazardous substance according to the GHS.

HMIS CLASSIFICATION: Health: 0 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 0 Flammability: 0 Reactivity Hazard: 0

EYE CONTACT: Causes slight to mild irritation of the eyes. SKIN CONTACT: Causes slight to mild irritation of the skin. INHALATION: May cause irritation to the nose, mucous membranes, and respiratory tract. INGESTION: No information available on the effects of ingestion.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: La(C11H19O2)3

Molecular Weight: 688.72

CHEMICAL NAME CAS# %

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum(III) 14319-13-2 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention.

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SECTION 4 FIRST AID MEASURES (Cont.)

SKIN EXPOSURE: Wash affected area with plenty of water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Not available AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Carbon dioxide, extinguishing powder, or water spray. Fight large fires with water spray or alcohol resistant foam. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Carbon oxides and lanthanum oxides

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Keep unprotected persons away. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Mix spills with vermiculite, sodium carbonate, or other suitable non-combustible absorbent. Sweep up and place in suitable container.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Ensure adequate ventilation. Keep container tightly sealed. CONDITIONS FOR SAFE STORAGE: Store in cool, dry well ventilated area. Store away from oxidizing agents, water, and moisture. Store under dry inert gas. Protect from humidity and water.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: White solid ODOR: None MOLECULAR WEIGHT: 688.72 BOILING POINT: 370° C (dec.) MELTING POINT: Decomposes SPECIFIC GRAVITY: 4.13 gm/ml VAPOR DENSITY: No data available SOLUBILITY: Insoluble

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SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Air, moisture, and incompatible materials INCOMPATIBILITY: Strong oxidizers DECOMPOSITION PRODUCTS: Carbon oxides and lanthanum oxides

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No component of this product present at levels greater than or equal to 0.1% is considered a carcinogen to humans. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available CHRONIC TOXICITY: Not available RTECS: No data

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No information available

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good

SECTION 15 REGULATORY INFORMATION

SARA 302/304: Not Listed

SARA 311/312: No SARA Hazards

SARA (TITLE 313): Not listed

CALIFORNIA PROP. 65: Not Listed

MASSACHUSETTS RIGHT TO KNOW COMPONENTS: No components are subject to the Massachusetts Right to Know Act.

NEW JERSEY RIGHT TO KNOW COMPONENTS: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum(III), 99%

PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum(III), 99%

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 02/15 SDS DEPT.

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