Yttrium (III) Nitrate Hexahydrate 3856 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Yttrium (III) Nitrate Hexahydrate

PRODUCT NUMBER: 3856

CAS NUMBER: 13494-98-9

SYNONYMS: Nitric Acid, yttrium (3+) salt, hexahydrate

MANUFACTURER:

ProChem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Danger

Hazard Statements

H272 May intensify fire; oxidizer. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.

Precautionary Phrases

P210 Keep away from heat. P220 Keep/store away from clothing/combustible materials. P221 Take any precaution to avoid mixing with combustibles. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with waster for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse. P370+P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction P403+P233 Store in a well-ventilated place.

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SECTION 2 HAZARDS IDENTIFICATION (Cont.)

HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 2 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 2 Specific Hazard: OX

EYE CONTACT: Causes slight to mild irritation of the eyes. SKIN CONTACT: Causes slight to mild irritation of the skin. INHALATION: Irritating to the nose, mucous membranes, and respiratory tract. INGESTION: May be harmful if swallowed.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: Y(NO3)3 ! 6H2O

Molecular Weight: 383.01

CHEMICAL NAME CAS# %

Yttrium (III) Nitrate Hexahydrate 13494-98-9 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Not available AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Carbon dioxide, extinguishing powder, or foam. Water may be ineffective but may be used for cooling exposed containers. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Nitrogen oxides and yttrium oxides.

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid dust formation or breathing dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Small spills can be mixed with vermiculite or sodium carbonate and swept up and placed in proper container for disposal.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Use with adequate ventilation. Avoid contact with skin and eyes. Keep way from sources of ignition-No smoking. Keep away from heat. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Hygroscopic. Store away from flammable substances, reducing agents, organic materials, metal powders, water, and moisture. Store under dry inert gas. Protect from humidity and water.

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SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS Component Exposure Limits Basis Entity Yttrium (III) nitrate hexahydrate 1 mg/m3 TLV ACGIH 1 mg/m3 PEL OSHA 1 mg/m3 REL NIOSH TLV: Threshold Limit Value over 8 hours of work. REL: Recommended Exposure Limit PEL: Permissible Exposure Limit

EYE PROTECTION: Wear chemical safety glasses or goggles. SKIN PROTECTION: Wear nitrile or rubber gloves, apron, or lab coat. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: Off-white solid ODOR: None MOLECULAR WEIGHT: 383.01 BOILING POINT: Not available MELTING POINT: Not available SPECIFIC GRAVITY: 2.682 VAPOR DENSITY: No data available SOLUBILITY IN WATER: Soluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high temperatures. INCOMPATIBILITY: Flammable substances, reducing agents, water, moisture, organic materials, metal powders, and strong acids. DECOMPOSITION PRODUCTS: Nitrogen oxides and yttrium oxides

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Subcutaneous (mouse); LDLo: 16600 mg/kg. Subcutaneous (frog); LDLo: 350 mg/kg. CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available RTECS: ZG3750000

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No data available.

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

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SECTION 14 TRANSPORTATION DATA

UN1477 Nitrates, inorganic, n.o.s. (Yttrium (III) Nitrate) CLASS 5.1 PG II

Marine Pollutant: No

SECTION 15 REGULATORY INFORMATION

TSCA: Not listed in the TSCA inventory

SARA 302/304: Not Listed SARA 311/312: Reactivity hazard, acute health hazard.

SARA (TITLE 313): Not Listed CALIFORNIA PROP. 65: Not Listed PENNSYLVANIA RIGHT TO KNOW: Yttrium (III) nitrate hexahydrate NEW JERSEY RIGHT TO KNOW: Yttrium (III) nitrate hexahydrate WHMIS CANADA: Class C: Oxidizing materials. Class D-2B: Toxic materials causing other toxic effects.

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, ProChem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE REVISED: 10/24 SDS DEPT.

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