Gadolinium ingot ALFAA45529 SDS

Page 1 / 7 SAFETY DATA SHEET Creation Date 09-Apr-2018 Revision Date 31-Jul-2026 Version 6

ALFAA45529

Gadolinium ingot

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 钆锭钆锭钆锭钆锭 Product Description: Gadolinium ingot

Cat No. : 45529 CAS No 7440-54-2

Supplier Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

Recommended Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Solid Silver Grey Odorless

Emergency Overview Moisture sensitive. Air sensitive.

Classification of the substance or mixture Based on available data, the classification criteria are not met

Label Elements

None required

Physical and Chemical Hazards None identified. Health Hazards The product contains no substances which at their given concentration are considered to be hazardous to health. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Is not likely mobile in the environment due its low water solubility. Spillage unlikely to penetrate soil.

This product does not contain any known or suspected endocrine disruptors.

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ALFAA45529 SAFETY DATA SHEET Revision Date 31-Jul-2026Page 2 / 7 Gadolinium ingot ______________________________________________________________________________________________

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Gadolinium 7440-54-2 <=100

SECTION 4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.

Most important symptoms and effects None reasonably foreseeable.

Self-Protection of the First Aider No special precautions required.

Notes to Physician Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media approved class D extinguishers. Do not use water or foam.

Extinguishing media which must not be used for safety reasons Water may be ineffective.

Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. No special precautions required.

Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological Information. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system.

Methods for Containment and Clean Up ______________________________________________________________________________________________ Page 2

ALFAA45529 SAFETY DATA SHEET Revision Date 31-Jul-2026Page 3 / 7 Gadolinium ingot ______________________________________________________________________________________________ Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Pick up and transfer to properly labelled containers.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation. Avoid dust formation.

Storage Keep in a dry place. Keep away from acids.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust MDHS 91 Metals and metalloids in workplace air by X-ray fluorescence spectrometry MDHS 99 Metals in air by ICP-AES

Exposure Controls

Engineering Measures None under normal use conditions. .

Personal protective equipment

Eye Protection Wear safety glasses with side shields (or goggles) (European standard - EN 166)

Hand Protection No special protective equipment required

Glove material Breakthrough time Glove thickness EU standard Glove comments Disposable gloves See manufacturers - EN 374 (minimum requirement) recommendations

Skin and body protection Long sleeved clothing

Respiratory Protection No protective equipment is needed under normal use conditions.

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particle filter

Small scale/Laboratory use Maintain adequate ventilation

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Silver Grey Physical State Solid

Odor Odorless Odor Threshold No data available pH No information available Melting Point/Range 1312 °C / 2393.6 °F Softening Point No data available Boiling Point/Range 3000 °C / 5432 °F Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure 23 hPa @ 20 °C Vapor Density Not applicable Solid Specific Gravity / Density 7.89 g/cm3 @ 20 °C Bulk Density No data available Water Solubility Insoluble in water Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

SECTION 10. STABILITY AND REACTIVITY

Stability Air sensitive. Moisture sensitive.

Hazardous Reactions None under normal processing. Hazardous Polymerization No information available.

Conditions to Avoid None known.

Materials to avoid Acids. Strong bases.

Hazardous Decomposition Products Gadolinium oxide.

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information

(a) acute toxicity;

(b) skin corrosion/irritation; No data available

(c) serious eye damage/irritation; No data available

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available ______________________________________________________________________________________________ Page 4

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(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

(g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs No information available.

(j) aspiration hazard; Not applicable Solid

Symptoms / effects,both acute and No information available delayed

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system.

Persistence and Degradability Product contains heavy metals. Discharge into the environment must be avoided. Special pre-treatment is necessary Persistence Insoluble in water, May persist. Degradability Not relevant for inorganic substances. Degradation in sewage Contains substances known to be hazardous to the environment or not degradable in waste treatment plant water treatment plants.

Bioaccumulative Potential May have some potential to bioaccumulate; Product has a high potential to bioconcentrate

Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water solubility

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Chemical waste generators must determine whether a discarded chemical is classified as a Products hazardous waste. Consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

Contaminated Packaging Empty remaining contents. Dispose of in accordance with local regulations. Do not re-use empty containers.

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ALFAA45529 SAFETY DATA SHEET Revision Date 31-Jul-2026Page 6 / 7 Gadolinium ingot ______________________________________________________________________________________________ Other Information Waste codes should be assigned by the user based on the application for which the product was used.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

IMDG/IMO Not regulated

IATA Not regulated

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

Measures on the Environmental Administration of New Chemical Substances Registration

Registration/Notification number B1A222252544

Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.

International Inventories X = listed, China (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Gadolinium - - - 231-162-2 X - - X - KE-05-0661

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Creation Date 09-Apr-2018 Revision Date 31-Jul-2026 Revision Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and hygiene.

Legend

CAS - Chemical Abstracts Service TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japanese Existing and New Chemical Substances ______________________________________________________________________________________________ Page 6

ALFAA45529 SAFETY DATA SHEET Revision Date 31-Jul-2026Page 7 / 7 Gadolinium ingot ______________________________________________________________________________________________ IECSC - Chinese Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic Compound)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

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