Samarium (III) Oxalate, decahydrate 3094 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Samarium (III) Oxalate, decahydrate

PRODUCT NUMBER: 3094

CAS NUMBER: 14175-03-2

SYNONYMS: Samarium oxalate, Oxalic acid, samarium salt.

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Not a dangerous substance according to the GHS.

HMIS CLASSIFICATION: Health: 0 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 0 Flammability: 0 Reactivity Hazard: 0

EYE CONTACT: May cause moderate to sever irritation of the eyes. SKIN CONTACT: May cause moderate to severe irritation of the skin. INHALATION: Dust may be cause vomiting, pain, and violent muscular stimulation INGESTION: Ingestion may cause vomiting, pain violent muscular stimulation, convulsions, collapse, and death.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: Sm2(C2O4)3 Ÿ10H2O

Molecular Weight: 744.93

CHEMICAL NAME CAS# %

Samarium Oxalate 14175-03-2 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim may need assistance in keeping their eyelids open. Get immediate medical attention. SKIN EXPOSURE: Wash affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.

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SECTION 4 FIRST AID MEASURES (Cont.)

INHALATION: Remove to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary. INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention if necessary.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Not available AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Use carbon dioxide, extinguishing powder, or water spray. Fight larger fires with water spray or alcohol resistant foam. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Carbon oxides and samarium oxides.

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Avoid contact with skin and eyes. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts and aerosols. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Keep away from heat and moisture.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Contains no substances with occupational exposure limit values. EYE PROTECTION: Wear chemical safety glasses or goggles and face shield SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: White crystalline powder ODOR: No data available MOLECULAR WEIGHT: 744.93 BOILING POINT: No data available MELTING POINT: No data available SPECIFIC GRAVITY: No data available VAPOR DENSITY: No data available SOLUBILITY: Soluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Moisture INCOMPATIBILITY: Moisture and oxidizing agents DECOMPOSITION PRODUCTS: Carbon oxides and samarium oxides.

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SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No data available.

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good.

SECTION 15 REGULATORY INFORMATION

TSCA: Listed in the TSCA inventory

DSCL (EEC): Listed on the DSCL inventory

SARA 302/304: Not Listed

SARA 311/312: Not Listed

SARA (TITLE 313): Not Listed

CALIFORNIA PROP. 65: Not Listed

WHMIS CANADA: Class D-1B: Toxic material causing immediate and serious toxic effects.

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 08/14

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