Yttrium (III) chloride, anhydrous 3844 SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Yttrium (III) chloride, anhydrous

PRODUCT NUMBER: 3844

CAS NUMBER: 10361-92-9

SYNONYMS: Yttrium trichloride

MANUFACTURER:

ProChem, Inc. PHONE: 815-398-1788 826 Roosevelt Road TOLL FREE: 800-795-8788 Rockford, IL 61109

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Warning

Hazard Statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause serious respiratory irritation.

Precautionary Phrases

P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P280 Wear protective gloves/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention

HMIS CLASSIFICATION: Health: 1 Flammability: 0 Reactivity: 0 NFPA RATING: Health: 1 Fire: 0 Reactivity Hazard: 0

EYE CONTACT: Causes serious irritation to the eyes. SKIN CONTACT: Causes slight irritation of the skin.

YTTRIUM (III) CHLORIDE, ANHYDROUS PAGE 1

INHALATION: Inhalation of dust leads to irritation of the respiratory tract. INGESTION: No information available on long-term chronic effects.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: YCl3

Molecular Weight: 195.26

CHEMICAL NAME CAS# %

Yttrium (III) chloride, anhydrous 10361-92-9 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Product is not flammable. AUTO IGNITION TEMPERATURE: Not applicable EXPLOSION LIMITS: Not applicable EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive self-contained breathing apparatus, flame and chemical resistant clothing, hats, boots, and gloves. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen chloride gas and yttrium oxide

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear approved personal protective equipment. Avoid dust formation. Avoid breathing dust, vapors, mist or gas. Ensure adequate ventilation. ENVIRONMENTAL PRECAUTIONS: Do not let product enter drains or allow to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite, or other suitable inert material and swept up.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear personal protective equipment. Avoid contact with skin and eyes. Avoid formation of dust. Ensure adequate ventilation. CONDITIONS FOR SAFE STORAGE: Store solid in a tightly sealed container away from moisture, water, and oxidizing agents. Handle under a dry atmosphere of air or nitrogen. Prolonged exposure to the atmosphere may degrade the product. Hygroscopic.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EYE PROTECTION: Always wear approved safety glasses with side shields, safety goggles, or face shield when handling a chemical substance in the laboratory. SKIN PROTECTION: Chemical resistant gloves. VENTILATION: Handle in an efficient chemical fume hood. RESPIRATOR: If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 19-10.134.

YTTRIUM (III) CHLORIDE, ANHYDROUS PAGE 2

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: White powder MOLECULAR WEIGHT: 195.26 (anhy.) BOILING POINT: 1507°C MELTING POINT: 721°C SPECIFIC GRAVITY: 2.67 VAPOR PRESSURE: No data SOLUBILITY IN WATER: Soluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: No hazardous polymerization CONDITIONS TO AVOID: Contact with moisture INCOMPATIBILITY: Water, moisture, and oxidizing agents. DECOMPOSITION PRODUCTS: Hydrogen chloride gas and yttrium oxide

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Intraperitoneal (rat); LD50: 45 mg/kg. Intraperitoneal (mouse); LD50: 88 mg/kg. Intraperitoneal (guinea pig); LD50: 8 mg/kg. LD50 Oral – Rat – female - >=2,000 mg/kg. LD50 Dermal – Rat – male and female - >2,000 mg/kg CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified as a confirmed carcinogen by IARC, ACGIH, NTP, and OSHA. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: No data available RTECS: ZG3150000

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

TOXICITY: Toxicity to fish: Semi-static test LC50 – Oncorhynchus mykiss (rainbow trout) – 0.62 mg/l – 96h.

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Non-hazardous material

YTTRIUM (III) CHLORIDE, ANHYDROUS PAGE 3

SECTION 15 REGULATORY INFORMATION

TSCA: Listed in the TSCA inventory SARA 313 COMPONENTS: This material does not contain any chemical components with know CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 302 COMPONENTS: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 311/312 HAZARDS: No SARA hazards.

MASSACHUSETTS RIGHT TO KNOW COMPONENTS: No components are subject to the Massachusetts Right To Know Act. CALIFORNIA PROP. 65 COMPONENTS: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, ProChem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE REVISED: 07/26 REVISION SUMMARY: Fax number removed. Updated the following Sections #2- Precautionary Phrases. Section #11 – Added to Acute Toxicity. Section #12 – Added Toxicity statement. All other details in the document about the product remain unchanged. – Revised by EHS 7/26 Reviewed/Approved 6/26 SDS DEPT.

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