Gadolinium(III) fluoride, anhydrous ALFAA41412 SDS

Page 1 / 8 SAFETY DATA SHEET Revision Date 24-Jul-2026 Version 7

ALFAA41412

Gadolinium(III) fluoride, anhydrous

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

产品说明:产品说明:产品说明:产品说明: 氟化钆(III),无水氟化钆(III),无水氟化钆(III),无水氟化钆(III),无水 Product Description: Gadolinium(III) fluoride, anhydrous

Cat No. : 41412 CAS No 13765-26-9 Molecular Formula F3 Gd

Supplier Avocado Research Chemicals Ltd. (Part of Thermo Fisher Scientific) Shore Road, Heysham Lancashire, LA3 2XY, United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608

Emergency Telephone Number For information US call: 001-800-227-6701 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No. US:001-800-424-9300 / Europe:001-703-527-3887

E-mail address begel.sdsdesk@thermofisher.com

Recommended Use Laboratory chemicals. Uses advised against No Information available

SECTION 2. HAZARD IDENTIFICATION

Physical State Appearance Odor Powder Solid White Odorless

Emergency Overview Causes severe skin burns and eye damage. Contact with acids liberates toxic gas.

Classification of the substance or mixture

Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1

Label Elements

Signal Word Danger

Hazard Statements H314 - Causes severe skin burns and eye damage ______________________________________________________________________________________________ Page 1

ALFAA41412 SAFETY DATA SHEET Revision Date 24-Jul-2026Page 2 / 8 Gadolinium(III) fluoride, anhydrous ______________________________________________________________________________________________

Precautionary Statements Prevention P264 - Wash face, hands and any exposed skin thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P362 + P364 - Take off contaminated clothing and wash it before reuse Storage P403 - Store in a well-ventilated place Disposal P501 - Dispose of contents/ container to an approved waste disposal plant

Physical and Chemical Hazards Contact with acids liberates toxic gas. Health Hazards Corrosive. Causes skin and eye burns. Environmental hazards Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Is not likely mobile in the environment due its low water solubility. Spillage unlikely to penetrate soil.

This product does not contain any known or suspected endocrine disruptors.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS No Weight % Gadolinium fluoride (GdF3) 13765-26-9 > 99.9

SECTION 4. FIRST AID MEASURES

Eye Contact Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required.

Inhalation Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration. Immediate medical attention is required.

Ingestion Do NOT induce vomiting. Call a physician immediately.

Most important symptoms and effects Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.

Notes to Physician

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ALFAA41412 SAFETY DATA SHEET Revision Date 24-Jul-2026Page 3 / 8 Gadolinium(III) fluoride, anhydrous ______________________________________________________________________________________________ Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Carbon dioxide (CO 2). Dry chemical. Chemical foam.

Extinguishing media which must not be used for safety reasons No information available.

Specific Hazards Arising from the Chemical Thermal decomposition can lead to release of irritating gases and vapors.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Ensure adequate ventilation.

Environmental Precautions See Section 12 for additional Ecological Information.

Methods for Containment and Clean Up Avoid dust formation. Sweep up and shovel into suitable containers for disposal. Do not let this chemical enter the environment.

Refer to protective measures listed in Sections 8 and 13.

SECTION 7. HANDLING AND STORAGE

Handling Do not breathe dust. Do not get in eyes, on skin, or on clothing. Do not ingest. If swallowed then seek immediate medical assistance. Handle product only in closed system or provide appropriate exhaust ventilation.

Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from acids. Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place.

Specific Use(s) Use in laboratories

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Component China ACGIH TLV OSHA PEL NIOSH Gadolinium fluoride (GdF3) - TWA: 2.5 mg/m3 (Vacated) TWA: 2.5 mg/m3 IDLH: 250 mg/m3

Component Hong Kong Thailand European Union The United Kingdom Gadolinium fluoride (GdF3) - TWA: 2.5 mg/m3 -

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ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration

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ALFAA41412 SAFETY DATA SHEET Revision Date 24-Jul-2026Page 4 / 8 Gadolinium(III) fluoride, anhydrous ______________________________________________________________________________________________ Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust

Exposure Controls

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source.

Personal protective equipment

Eye Protection Goggles (European standard - EN 166)

Hand Protection Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure

Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly

Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143

Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Particle filtering: EN149:2001 When RPE is used a face piece Fit Test should be conducted

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls No information available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance White Physical State Powder Solid

Odor Odorless Odor Threshold No data available pH No information available Melting Point/Range No data available Softening Point No data available ______________________________________________________________________________________________ Page 4

ALFAA41412 SAFETY DATA SHEET Revision Date 24-Jul-2026Page 5 / 8 Gadolinium(III) fluoride, anhydrous ______________________________________________________________________________________________ Boiling Point/Range No information available Flash Point No information available Method - No information available Evaporation Rate Not applicable Solid Flammability (solid,gas) No information available Explosion Limits No data available

Vapor Pressure No information available Vapor Density Not applicable Solid Specific Gravity / Density No data available Bulk Density No data available Water Solubility Insoluble Solubility in other solvents No information available Partition Coefficient (n-octanol/water) Autoignition Temperature No data available Decomposition Temperature No data available Viscosity Not applicable Solid Explosive Properties No information available Oxidizing Properties No information available

Molecular Formula F3 Gd Molecular Weight 214.24

SECTION 10. STABILITY AND REACTIVITY

Stability Stable under normal conditions.

Hazardous Reactions No information available. Hazardous Polymerization No information available.

Conditions to Avoid Avoid dust formation. Incompatible products.

Materials to avoid Acids. Strong oxidizing agents. Strong reducing agents.

Hazardous Decomposition Products Gaseous hydrogen fluoride (HF).

SECTION 11. TOXICOLOGICAL INFORMATION

Product Information No acute toxicity information is available for this product

(a) acute toxicity;

(b) skin corrosion/irritation; Category 1 B

(c) serious eye damage/irritation; No data available

(d) respiratory or skin sensitization; Respiratory No data available Skin No data available

(e) germ cell mutagenicity; No data available

(f) carcinogenicity; No data available

There are no known carcinogenic chemicals in this product

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ALFAA41412 SAFETY DATA SHEET Revision Date 24-Jul-2026Page 6 / 8 Gadolinium(III) fluoride, anhydrous ______________________________________________________________________________________________ (g) reproductive toxicity; No data available

(h) STOT-single exposure; No data available

(i) STOT-repeated exposure; No data available

Target Organs No information available.

(j) aspiration hazard; Not applicable Solid

Other Adverse Effects The toxicological properties have not been fully investigated.

Symptoms / effects,both acute and Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. delayed Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects Do not empty into drains.

Persistence and Degradability Persistence Insoluble in water. Degradability Not relevant for inorganic substances.

Bioaccumulative Potential May have some potential to bioaccumulate

Mobility in soil Spillage unlikely to penetrate soil Is not likely mobile in the environment due its low water solubility

Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors Persistent Organic Pollutant This product does not contain any known or suspected substance Ozone Depletion Potential This product does not contain any known or suspected substance

SECTION 13. DISPOSAL CONSIDERATIONS

Waste from Residues/Unused Waste is classified as hazardous. Dispose of in accordance with the European Directives Products on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of this container to hazardous or special waste collection point.

Other Information Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains. Do not flush to sewer. Large amounts will affect pH and harm aquatic organisms.

SECTION 14. TRANSPORT INFORMATION

Road and Rail Transport

UN-No UN3260 Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s. Hazard Class 8 ______________________________________________________________________________________________ Page 6

ALFAA41412 SAFETY DATA SHEET Revision Date 24-Jul-2026Page 7 / 8 Gadolinium(III) fluoride, anhydrous ______________________________________________________________________________________________ Packing Group III

IMDG/IMO

UN-No UN3260 Proper Shipping Name Corrosive solid, acidic, inorganic, n.o.s. Hazard Class 8 Packing Group III

IATA

UN-No UN3260 Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.* Hazard Class 8 Packing Group III

Special Precautions for User No special precautions required

SECTION 15. REGULATORY INFORMATION

Measures on the Environmental Administration of New Chemical Substances Registration

Registration/Notification number B1A222250991

Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.

International Inventories X = listed, China (IECSC), Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), Korea (KECL).

Component The List of IECSC EINECS TSCA DSL PICCS ENCS ISHL AICS KECL Inventory of dangerous Hazardous goods GB Chemicals 12268 - (2015 2012 Edition) Gadolinium fluoride - - - 237-369-4 X - - X X - KE-17398 (GdF3)

National Regulations

SECTION 16. OTHER INFORMATION

Prepared By Health, Safety and Environmental Department Revision Date 24-Jul-2026 Revision Summary Not applicable.

Training Advice Chemical hazard awareness training, incorporating labelling, Safety Data Sheets (SDS), Personal Protective Equipment (PPE) and hygiene. Use of personal protective equipment, covering appropriate selection, compatibility, breakthrough thresholds, care, maintenance, fit and standards. First aid for chemical exposure, including the use of eye wash and safety showers.

Legend

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ALFAA41412 SAFETY DATA SHEET Revision Date 24-Jul-2026Page 8 / 8 Gadolinium(III) fluoride, anhydrous ______________________________________________________________________________________________ CAS - Chemical Abstracts Service TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances/EU List of Notified Chemical Substances Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japanese Existing and New Chemical Substances IECSC - Chinese Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances NZIoC - New Zealand Inventory of Chemicals

WEL - Workplace Exposure Limit TWA - Time Weighted Average ACGIH - American Conference of Governmental Industrial Hygienists IARC - International Agency for Research on Cancer DNEL - Derived No Effect Level PNEC - Predicted No Effect Concentration RPE - Respiratory Protective Equipment LD50 - Lethal Dose 50% LC50 - Lethal Concentration 50% EC50 - Effective Concentration 50% NOEC - No Observed Effect Concentration POW - Partition coefficient Octanol:Water PBT - Persistent, Bioaccumulative, Toxic vPvB - very Persistent, very Bioaccumulative

ICAO/IATA - International Civil Aviation Organization/International Air IMO/IMDG - International Maritime Organization/International Maritime Transport Association Dangerous Goods Code ADR - European Agreement Concerning the International Carriage of MARPOL - International Convention for the Prevention of Pollution from Dangerous Goods by Road Ships OECD - Organisation for Economic Co-operation and Development ATE - Acute Toxicity Estimate BCF - Bioconcentration factor VOC - (Volatile Organic Compound)

Key literature references and sources for data https://echa.europa.eu/information-on-chemicals Suppliers safety data sheet, Chemadvisor - LOLI, Merck index, RTECS

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

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