Gadolinium (III) Fluoride SDS

SECTION 1 PRODUCT AND COMPANY INFORMATION

PRODUCT NAME: Gadolinium (III) Fluoride

PRODUCT NUMBER: 1828

CAS NUMBER: 13765-26-9

MANUFACTURER:

Prochem, Inc. PHONE: 815-398-1788 826 Roosevelt Road FAX: 815-398-1810 Rockford, IL 61109 TOLL FREE: 800-795-8788

IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION OF SUBSTANCE OR MIXTURE

Pictogram

Signal Word Warning

Hazard Statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.

Precautionary Phrases

P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P280 Wear protective gloves/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse.

HMIS CLASSIFICATION: Health: 2 Fire: 0 Reactivity Hazard: 0 NFPA RATING: Health: 2 Flammability: 0 Reactivity Hazard: 0

EYE CONTACT: May cause irritation of the eyes. SKIN CONTACT: may cause mild irritation and redness. INHALATION: May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath. INGESTION: Toxicity reduced to the extent that this compound is relatively insoluble. In large amounts may cause vomiting, abdominal pain, and diarrhea.

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SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Formula: GdF3

Molecular Weight: 214.25

CHEMICAL NAME CAS# %

Gadolinium (III) Fluoride 13765-26-9 100

SECTION 4 FIRST AID MEASURES

EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5 FIREFIGHTING MEASURES

FLASH POINT: Product is not flammable. AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: This product does not present an explosion hazard. EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Hydrogen fluoride and gadolinium oxide.

SECTION 6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid the formation of dust. Avoid breathing vapors, mist, gas, or dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Mix spills with powdered sodium bicarbonate, lime, or calcium carbonate. Sweep up and place in suitable container for proper disposal.

SECTION 7 HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid formation of dust. CONDITIONS FOR SAFE STORAGE: Store in a cool, dry, and well-ventilated area.

SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

EXPOSURE CONTROLS: Component Exposure Limits Basis Entity Gadolinium (III) Fluoride 2.5 mg/m3 TWA OSHA TWA: Time Weighted Average over 8 hours of work.

EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, apron, or lab coat. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.

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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

COLOR AND FORM: White powder ODOR: None MOLECULAR WEIGHT: 214.25 BOILING POINT: No data available MELTING POINT: 1231° C SPECIFIC GRAVITY: 7.047 gm/ml SOLUBILITY: Insoluble

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None INCOMPATIBILITY: Strong reducing agents DECOMPOSITION PRODUCTS: Hydrogen fluoride and gadolinium oxide

SECTION 11 TOXICOLOGICAL DATA

ACUTE TOXICITY: Not available CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified a carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available RTECS: Not available

To the best of our knowledge the toxicological effects of this compound have not been fully investigated.

SECTION 12 ECOLOGICAL DATA

No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Dispose of in according to local, state, and federal regulations.

SECTION 14 TRANSPORTATION DATA

Not a dangerous good

SECTION 15 REGULATORY INFORMATION

TSCA: Listed in the TSCA inventory

SARA 302/304: Not listed

SARA (TITLE 313): Not listed

SARA 311/312 HAZARD: Acute Health Hazard

PENNSYLVANIA RIGHT TO KNOW: Gadolinium (III) Fluoride

NEW JERSEY RIGHT TO KNOW: Gadolinium (III) Fluoride

CALIFORNIA PROP. 65: Not Listed

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SECTION 16 OTHER INFORMATION

DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 05/15 SDS DEPT.

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